b轴取向MFI分子筛膜的制备及应用研究进展

doi:10.19964/j.issn.1006-4990.2021-0390

Abstract

Abstract:

Zeolite membrane is a new type of inorganic membrane,which has the advantages of regular pore structure,good chemical and thermal stability,high mechanical strength,good pollution resistance and easy modification.b-axis oriented MFI zeolite membrane has wide application prospect in membrane separation and membrane reactor,because it can shorten the mass transfer path,reduce the mass transfer resistance and improve the diffusion efficiency,which has been widely con-cerned by scholars at home and abroad.In this paper,the preparation and application of b-axis oriented zeolite membranes were reviewed.The in-situ hydrothermal synthesis,secondary growth,microwave-assisted synthesis,gel-free method,powder conversion method and nanosheet method were introduced in detail.The secondary growth method could control the micro-structure of zeolite membrane,which was less affected by the surface properties of support.Microwave-assisted method could shorten crystallization time and reduce energy consumption,which was of great significance for industrial production.The gel-free method had the advantages of simple preparation process and environmental friendliness.On the basis of the above meth-ods,the membrane thickness could be reduced by using nanosheets as crystal seeds.Finally,the development prospect of b-axis oriented MFI zeolite membrane was prospected.There were still many challenges in the preparation of b-axis oriented continuous and defect-free MFI zeolite membranes.It included improving the mechanical strength and long-term stability of membranes and achieving the preparation of oriented membranes on the roughness or bending and large-scale support surface.

Key words: b-axis, MFI zeolite membranes, preparation, separation, catalysis

CLC Number:

YUAN Biao,WU Wei,LUO Chao,SHEN Peng,CHEN Zan. Research progress on preparation and application of b-axis oriented MFI zeolite membranes[J]. Inorganic Chemicals Industry, 2021, 53(12): 54-60.

Figures/Tables 5

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Table 1

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样品	特殊处理	合成时间/h	取向	完整性	厚度/ μm
S1	—	17	b轴	不连续	8
S2	无TPAOH	17	随机	不连续	9
S3	0.32 g TPAOH溶液浸渍	17	a轴,b轴	连续	8
S4	0.08 g TPAOH溶液浸渍	17	a轴,b轴	连续	8
S5	—	24	随机	连续	15
S6	—	5	a轴	连续	3
S7	浸渍后真空处理	17	随机	连续	250
S8	—	17（旋转）	随机	不连续	5
S9	TPAOH溶液1∶3稀释, 垂直位置	17	b轴	不连续	9
S10	TPAOH溶液1∶3稀释,水平位置	17	b轴	连续	10
S11	TPAOH溶液1∶3稀释,垂直位置	48	a轴,b轴	连续	8
S12	TPAOH溶液1∶3稀释,水平位置	48	a轴,b轴	连续	30

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