锆钇废料制备氧化钇和磷酸锆吸附剂及其性能评价

doi:10.19964/j.issn.1006-4990.2023-0305

Abstract

Abstract:

Yttrium-Stabilized Zirconia（YSZ） is a material with excellent performance，which generates a large amount of solid waste such as cutting edges during its production and use，and its recycling helps to protect the environment and the effective use of resources.However，due to the stable nature of the waste material，how to recycle and convert it into valuable products has become the key to the effective utilization of resources.It was proposed a route to convert zirconium-yttrium waste into zirconium hydroxide and yttrium oxalate intermediates and further into zirconium hydrogen phosphate and yttrium oxide adsorbents to increase the added value of zirconium-yttrium resource products in this paper.This synthetic route employed ethanol as a dispersing agent.Zirconium hydroxide，oxalic acid，and disodium hydrogen phosphate were mixed in the ratio of 1∶2∶2 by mole，and reacted at 373 K for 6 h to produce layered zirconium phosphate.The adsorption capacity of layered zirconium phosphate for potassium ions was 151.6 mg/g，which could reduce the potassium concentration in simulated hyperkalemic serum to the normal human level of 4.51 mmol/L without excessive loss of sodium ions，using ethanol as a dispersion aid and reacting at 373 K for 6 h.Yttrium oxide，obtained by calcination of yttrium oxalate ammonia hydrate，was used as an efficient adsorbent for sulfate.The results showed that the yttrium oxide obtained by calcination of yttrium oxalate ammonia hydrate at 1 073 K maintained 98.6% of sulfate removal when added at 10 g/L in a strongly acidic solution.The process of sulfate adsorption by yttrium oxide followed the Langmuir isothermal adsorption model and belonged to monomolecular layer adsorption.Its quasi-secondary kinetic constant was 2.03×10^-3 g/（min·mg），which was chemisorption.

Key words: zirconium-yttrium waste, zirconium phosphate, yttrium oxide, adsorption

CLC Number:

TQ134.12

XU Mengyao, ZHANG Xin, HE Kunpeng, HE Jian, JIANG Wei. Preparation of yttrium oxide and zirconium phosphate adsorbents from zirconium-yttrium waste and evaluation of their performance[J]. Inorganic Chemicals Industry, 2024, 56(3): 116-124.

Figures/Tables 18

Table 1

Fig.1

Fig.2

Table 2

Fig.3

Fig.4

Table 3

Fig.5

Table 4

Kinetic model fitting results of adsorption ofpotassium ions by zirconium phosphate"

拟合模型	拟合方程	R²
颗粒内扩散模型	$Q t = 4.408 t 0.5 + 84.43$	0.846 7
准一级动力学模型	$l g (66.99 - Q t) = 1.826 - 0.002 3 t$	0.924 1
准二级动力学模型	t/ $Q t$ $= 0.153 3 + (1 / 171.53) t$	0.999 7

Table 4

Fig.6

Fig.7

Fig.8

Fig.9

Fig.10

Fig.11

Table 5

Fig.12

Fig.13

References 15

1	林振汉.锆及其化合物的应用［J］.世界有色金属，2011（7）：68-69.
	LIN Zhenhan.Application of zirconium and its compounds［J］.World Nonferrous Metals，2011（7）：68-69.
2	吴先锋.氧化锆磨削废料的回收工艺研究［D］.青岛：山东科技大学，2014.
	WU Xianfeng.Study on recovery technology of zirconia grinding waste［D］.Qingdao：Shandong University of Science and Technology，2014.
3	喻杰.锆的核应用与我国锆材加工技术［J］.机械制造，2009，47（5）：48-50.
	YU Jie.Nuclear application of zirconium and processing technology of zirconium in China［J］.Machinery，2009，47（5）：48-50.
4	陈鹏辉.钇稳定氧化锆（YSZ）透明陶瓷的制备与性能研究［D］.镇江：江苏大学，2020.
	CHEN Penghui.Fabrication and properties of yttria-stabilized ZrO₂（YSZ）transparent ceramics［D］.Zhenjiang：Jiangsu University，2020.
5	焦子豪.磷酸锆吸附剂的制备及其对锶离子的吸附性能和机理研究［D］.南宁：广西大学，2021.
	JIAO Zihao.Preparation of zirconium phosphate adsorbent and study on adsorption properties and mechanism of strontium［D］.Nanning：Guangxi University，2021.
6	武越，周慧晴，史雍何，等.磷酸锆/介孔密胺树脂复合吸附材料的制备及性能研究［J］.化工新型材料，2022，50（2）：124-128.
	WU Yue， ZHOU Huiqing， SHI Yonghe，et al.Study on preparation and property of Zr（HOP₄）₂ and mesoporous melamine resin as composite sorbent［J］.New Chemical Materials，2022，50（2）：124- 128.
7	刘志立.氧化钇纳米粉体的可控制备与表征［D］.上海：上海第二工业大学，2021.
	LIU Zhili.Controllable preparation and characterization of Y₂O₃ nanopowders［D］.Shanghai：Shanghai Polytechnic University，2021.
8	于佳欣，白杨.2021年4季度稀土价格走势分析［J］.稀土信息，2022（1）：37-39.
	YU Jiaxin， BAI Yang.Analysis of rare earth price trend in the fo-urth quarter of 2021［J］.Rare Earth Information，2022（1）：37-39.
9	王彦.2021年美国钇统计分析［J］.稀土信息，2022（2）：24-25.
	WANG Yan.Statistical analysis of yttrium in the United States in 2021［J］.Rare Earth Information，2022（2）：24-25.
10	钟竞德.超细粒度氧化钇生产的新工艺分析［J］.科技创新与应用，2016（6）：116.
	ZHONG Jingde.Analysis of new technology for ultra-fine grained yttrium oxide production［J］.Technology Innovation and Application，2016（6）：116.
11	CLEARFIELD A， STYNES J A.The preparation of crystalline zirconium phosphate and some observations on its ion exchange behaviour［J］.Journal of Inorganic and Nuclear Chemistry，1964，26（1）：117-129.
12	CHENG Yu， CHUAH G K.The synthesis and applications of α-zirconium phosphate［J］.Chinese Chemical Letters，2020， 31（2）：307-310.
13	陆运涛.磷酸锆纳米载银抗菌剂及其抗菌中心静脉导管的体内外抗菌效果和安全性研究［D］.上海：复旦大学，2010.
	LU Yuntao.Study on the antibacterial effect and safety of silver-containing zirconium phosphate antibacterial agents of nanometer level and the made-up central venous catheter in vitro and in vivo［D］.Shanghai：Fudan University，2010.
14	曾仁权，傅相锴.磷酸锆及其衍生物的离子交换性能［J］.化学进展，2009，21（12）：2536-2541.
	ZENG Renquan， FU Xiangkai.Ion-exchange properties of zirconium phosphate and its derivatives［J］.Progress in Chemistry，2009，21（12）：2536-2541.
15	邱磊.蛋壳和桔皮对重金属的吸附性能及不同吸附工艺研究［D］.天津：河北工业大学，2020.
	QIU Lei.Studies on the adsorption properties of heavy metals by eggshell and orange peel and different adsorption processes［D］.Tianjin：Hebei University of Technology，2020.

元素	曲线方程	拟合度（R²）
Na	y=9 121x	0.999 99
K	y=925.3x	0.999 71

吸附温度/K	Langmuir			Freundlich
吸附温度/K	Q_max/ （mg·g^-1）	K_L/ （L·mg^-1）	R²	n	K_F/（mg^1-1/ⁿ ·L^1/ⁿ ·g^-1）	R²
283	183.22	0.003 2	0.929 7	13.99	2.09	0.975 6
293	182.51	0.003 1	0.915 0	9.17	1.81	0.977 8
303	168.33	0.002 9	0.979 2	15.48	2.25	0.991 1

温度/ K	Langmuir			Freundlich
温度/ K	Q_max/ （mg·g^-1）	K_L/ （L·mg^-1）	R²	n	K_F/（mg^1-1/ⁿ · L^1/ⁿ ·g^-1）	R²
283	121.49	0.142 5	0.992 6	1.266	2.707	0.948 9
293	126.91	0.173 6	0.998 2	1.235	2.786	0.947 1
303	131.18	0.207 8	0.996 5	1.338	4.191	0.911 2
313	133.46	0.220 9	0.995 2	1.367	5.348	0.914 3
323	141.55	0.241 3	0.998 7	1.476	7.871	0.924 5

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Preparation of yttrium oxide and zirconium phosphate adsorbents from zirconium-yttrium waste and evaluation of their performance

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