磷酸银光催化材料的微观形貌及晶面效应研究进展

doi:10.19964/j.issn.1006-4990.2023-0024

Abstract

Abstract:

The morphology and crystal surface control of semiconductor photocatalysts are research focus in the photocatalysis area.Ag₃PO₄ as a new visible light photocatalyst is possessed of high photoquantum efficiency and strong photooxidation ability.The current status，research progress and existing problems in the microstructure construction and crystal surface effect of Ag₃PO₄ photocatalysts were reviewed.In terms of microstructure construction，Ag₃PO₄ materials with nano-size，hollow structure，porous structure，two-dimensional dendritic structure，one-dimensional hollow porous structure and other microstructure were synthesized，which greatly improved the photocatalytic activity.It was necessary to further optimize the relationship between microstructure and particle size，as well as develop new microstructure to obtain better photocatalytic materials.In terms of crystal surface regulation，Ag₃PO₄ materials exposed to different exponential crystal surfaces were synthesized，which required optimization design in terms of theoretical research，synthesis method，and synergistic effect of different crystal surfaces to obtain higher performance.The structure-activity relationship between microscopic morphology and photocatalytic performance was explored，which provided certain theoretical basis and research ideas for the design and construction of efficient and stable Ag₃PO₄ photocatalysts.

Key words: photocatalysis, Ag₃PO₄, microstructure, crystal surface effect

CLC Number:

TQ426

YU Hongchao, ZHANG Mengmeng, JIN Tianxiang. Research progress of microstructure and crystal surface effect of Ag₃PO₄ photocatalysts[J]. Inorganic Chemicals Industry, 2023, 55(8): 13-20.

Figures/Tables 9

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References 44

1	BYRNE C， SUBRAMANIAN G， PILLAI S C.Recent advances in photocatalysis for environmental applications［J］.Journal of Environmental Chemical Engineering，2018，6（3）：3531-3555.
2	LIU Hongshuai， WANG Zeyan， LI Huiliang，et al.Photocatalytic degradation of ethylene by Ga₂O₃ polymorphs［J］.RSC Advances，2018，8（26）：14328-14334.
3	PHOON B L， LAI C W， JUAN J C，et al.Recent developments of strontium titanate for photocatalytic water splitting application［J］.International Journal of Hydrogen Energy，2019，44（28）：14316-14340.
4	XIONG Hailong， DONG Yueyue， LIU Dong，et al.Recent advances in porous materials for photocatalytic CO₂ reduction［J］.The Journal of Physical Chemistry Letters，2022，13（5）：1272-1282.
5	GAO Linjie， LI Yaguang， REN Jiabin，et al.Passivation of defect states in anatase TiO₂ hollow spheres with Mg doping：Realizing efficient photocatalytic overall water splitting［J］.Applied Catalysis B：Environmental，2017，202：127-133.
6	LEE K M， LAI C W， NGAI K S，et al.Recent developments of zinc oxide based photocatalyst in water treatment technology：A revi- ew［J］.Water Research，2016，88：428-448.
7	YI Zhiguo， YE Jinhua， KIKUGAWA N，et al.An orthophosphate semiconductor with photooxidation properties under visible-light irradiation［J］.Nature Materials，2010，9（7）：559-564.
8	MARTIN D J， LIU Guigao， MONIZ S J A，et al.Efficient visible driven photocatalyst，silver phosphate：Performance，understanding and perspective［J］.Chemical Society Reviews，2015，44（21）：7808-7828.
9	CAI Tao， WANG Longlu， LIU Yutang，et al.Ag₃PO₄/Ti₃C₂ MXene interface materials as a Schottky catalyst with enhanced photocatalytic activities and anti-photocorrosion performance［J］.Applied Catalysis B：Environmental，2018，239：545-554.
10	DUAN Yi， DENG Lin， SHI Zhou，et al.Assembly of graphene on Ag₃PO₄/AgI for effective degradation of carbamazepine under Visi-
	ble-light irradiation：Mechanism and degradation pathways［J］.Chemical Engineering Journal，2019，359：1379-1390.
11	LIU Wei， SHEN Jun， YANG Xiaofei，et al.Dual Z-scheme g-C₃N₄/Ag₃PO₄/Ag₂MoO₄ ternary composite photocatalyst for solar oxygen evolution from water splitting［J］.Applied Surface Science，2018，456：369-378.
12	XIE Yingpeng， WANG Guosheng.Visible light responsive porous Lanthanum-doped Ag₃PO₄ photocatalyst with high photocatalytic water oxidation activity［J］.Journal of Colloid and Interface Science，2014，430：1-5.
13	CHEN Xiaojuan， DAI Youzhi， GUO Jing，et al.Novel magnetically separable reduced graphene oxide（RGO）/ZnFe₂O₄/Ag₃PO₄ nanocomposites for enhanced photocatalytic performance toward 2，4-dichlorophenol under visible light［J］.Industrial & Engineering Chemistry Research，2016，55（3）：568-578.
14	汲畅，王国胜.Ag₃PO₄/g-C₃N₄异质结催化剂可见光降解黄连素［J］.无机盐工业，2022，54（4）：175-180.
	JI Chang， WANG Guosheng.Degradation of berberine by visible light over Ag₃PO₄/g-C₃N₄ heterojunction catalyst［J］.Inorganic Chemicals Industry，2022，54（4）：175-180.
15	覃利琴，陶萍芳，王荣芳，等.一步溶剂热法合成溴化银/磷酸银复合催化剂及其可见光催化性能［J］.无机盐工业，2018，50（6）：86-90.
	QIN Liqin， TAO Pingfang， WANG Rongfang，et al.Synthesis and photocatalytic properties of AgBr/Ag₃PO₄ hybrids by one-step solvothermal method［J］.Inorganic Chemicals Industry，2018，50（6）：86-90.
16	陶萍芳，覃利琴，欧小梅，等.水热合成锰离子掺杂磷酸银及其光催化性能［J］.无机盐工业，2017，49（6）：90-93.
	TAO Pingfang， QIN Liqin， Xiaomei OU，et al.Hydrothermal synthesis and photocatalytic activity of Mn²⁺-doped Ag₃PO₄ ［J］.Inorganic Chemicals Industry，2017，49（6）：90-93.
17	MASSE R， TORDJMAN I， DURIF A.Affinement de la structure cristalline du monophosphate d'argent Ag₃PO₄：Existence d'une forme haute témperature［J］.Zeitschrift Für Kristallographie，1976，144（1/2/3/4/5/6）：76-81.
18	LIU J J， FU X L， CHEN S F，et al.Electronic structure and optical properties of Ag₃PO₄ photocatalyst calculated by hybrid density functional method［J］.Applied Physics Letters，2011，99（19）：191903.
19	MA Xinguo， LU Bin， LI Di，et al.Origin of photocatalytic activation of silver orthophosphate from first-principles［J］.The Journal of Physical Chemistry C，2011，115（11）：4680-4687.
20	UMEZAWA N， SHUXIN O， YE Jinhua.Theoretical study of high photocatalytic performance of Ag₃PO₄ ［J］.Physical Review B，2011，83（3）：035202.
21	DINH C T， NGUYEN T D， KLEITZ F，et al.Large-scale synthesis of uniform silver orthophosphate colloidal nanocrystals exhibiting high visible light photocatalytic activity［J］.Chemical Communications，2011，47（27）：7797-7799.
22	LIANG Qinghua， MA Wangjing， SHI Yao，et al.Hierarchical Ag₃PO₄ porous microcubes with enhanced photocatalytic properties synthesized with the assistance of trisodium citrate［J］.CrystEngComm，2012，14（8）：2966-2973.
23	MANDAL S， ANANTHAKRISHNAN R.Sustainable design of hierarchically porous Ag₃PO₄ microspheres through a novel natural template and their superior photooxidative capacity［J］.ACS Sustainable Chemistry & Engineering，2018，6（1）：1091-1104.
24	TANG Hua， WANG Yuqi， ZHANG Du，et al.Shape-controllable synthesis and morphology-dependent photocatalytic properties of AgBr photocatalysts［J］.Journal of Materials Science：Materials in Electronics，2016，27（7）：6955-6963.
25	BI Yingpu， HU Hongyan， JIAO Zhengbo，et al.Two-dimensional dendritic Ag₃PO₄nanostructures and their photocatalytic properties［J］.Physical Chemistry Chemical Physics，2012，14（42）：14486-14488.
26	YU Hongchao， JIAO Zhengbo， JIN Bingjun，et al.Facile synthesis of porous Ag₃PO₄ photocatalysts with high self-stability and activity［J］.RSC Advances，2016，6（61）：56166-56169.
27	WANG Zhong lin， SONG Jinhui.Piezoelectric nanogenerators based on zinc oxide nanowire arrays［J］.Science，2006，312（5771）：242-246.
28	XIE Xiaowei， LI Yong， LIU Zhiquan，et al.Low-temperature oxidation of CO catalysed by Co₃O₄ nanorods［J］.Nature，2009，458（7239）：746-749.
29	BI Yingpu， HU Hongyan， OUYANG Shuxin，et al.Photocatalytic and photoelectric properties of cubic Ag₃PO₄ sub-microcrystals with sharp corners and edges［J］.Chemical Communications，2012，48（31）：3748-3750.
30	GUO Xingyuan， CHEN Changfeng， YIN Shengyan，et al.Controlled synthesis and photocatalytic properties of Ag₃PO₄ microcrystals［J］.Journal of Alloys and Compounds，2015，619：293- 297.
31	BI Yingpu， OUYANG Shuxin， UMEZAWA N，et al.Facet effect of single-crystalline Ag₃PO₄ sub-microcrystals on photocatalytic properties［J］.Journal of the American Chemical Society，2011，133（17）：6490-6492.
32	WANG Jun， TENG Fei， CHEN Mindong，et al.Facile synthesis of novel Ag₃PO₄ tetrapods and the｛110｝facets-dominated photocatalytic activity［J］.CrystEngComm，2013，15（1）：39-42.
33	XIE Yao， HUANG Zhaohui， ZHANG Zhijie，et al.Controlled synthesis and photocatalytic properties of rhombic dodecahedral Ag₃PO₄ with high surface energy［J］.Applied Surface Science，2016，389：56-66.
34	HU Hongyan， JIAO Zhengbo， YU Hongchao，et al.Facile synthesis of tetrahedral Ag₃PO₄ submicro-crystals with enhanced photocatalytic properties［J］.Journal of Materials Chemistry A，2013，1（7）：2387-2390.
35	ZHENG Binjie， WANG Xue， LIU Chang，et al.High-efficiently visible light-responsive photocatalysts：Ag₃PO₄ tetrahedral microcrystals with exposed｛111｝facets of high surface energy［J］.Journal of Materials Chemistry A，2013，1（40）：12635-12640.
36	MARTIN D J， UMEZAWA N， CHEN Xiaowei，et al.Facet engineered Ag₃PO₄ for efficient water photooxidation［J］.Energy & Environmental Science，2013，6（11）：3380-3386.
37	MIYASATO R， FUJIWARA M， SATO H，et al.Particle size effects of tetrahedron-shaped Ag₃PO₄ photocatalyst on water-oxidation activity and carrier recombination dynamics［J］.Chemical Physics Letters，2019，737：100023.
38	HSIEH M S， SU H J， HSIEH P L，et al.Synthesis of Ag₃PO₄ crystals with tunable shapes for facet-dependent optical property，pho-
	tocatalytic activity，and electrical conductivity examinations［J］.ACS Applied Materials & Interfaces，2017，9（44）：39086-39093.
39	TACHIKAWA T， YAMASHITA S， MAJIMA T.Evidence for crystal-face-dependent TiO₂ photocatalysis from single-molecule imaging and kinetic analysis［J］.Journal of the American Chemical Society，2011，133（18）：7197-7204.
40	KIM S， WANG Yue， ZHU Mingshan，et al.Facet effects of Ag₃PO₄ on charge-carrier dynamics：Trade-off between photocatalytic activity and charge-carrier lifetime［J］.Chemistry-A European Journal，2018，24（56）：14928-14932.
41	JIAO Zhengbo， ZHANG Yan， YU Hongchao，et al.Concave trisoctahedral Ag₃PO₄ microcrystals with high-index facets and enhanced photocatalytic properties［J］.Chemical Communications，2013，49（6）：636-638.
42	YU Jiaguo，LOW J， XIAO Wei，et al.Enhanced photocatalytic CO₂-reduction activity of anatase TiO₂ by coexposed｛001｝and｛101｝facets［J］.Journal of the American Chemical Society，2014，136（25）：8839-8842.
43	ZHENG Zhaoke， HUANG Baibiao， LU Jibao，et al.Hierarchical TiO₂ microspheres：Synergetic effect of｛001｝and｛101｝facets for enhanced photocatalytic activity［J］.Chemistry-A European Journal，2011，17（52）：15032-15038.
44	于红超，杜俊杰，张梦萌，等.Ag₃PO₄光催化剂的合成与再生［J］.兵器材料科学与工程，2020，43（5）：71-76.
	YU Hongchao， DU Junjie， ZHANG Mengmeng，et al.Synthesis and regeneration of Ag₃PO₄ photocatalyst［J］.Ordnance Material Science and Engineering，2020，43（5）：71-76.

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Research progress of microstructure and crystal surface effect of Ag₃PO₄ photocatalysts

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