碳化法制备球霰石碳酸钙微球及形成机理

doi:10.11962/1006-4990.2020-0230

Abstract

Abstract:

The monodispersed pure vaterite microspheres were synthesized by disperse bubbling carbonization using the reaction system of CaCl₂-NH₃-H₂O and characterized by SEM,FE-SEM,TEM and XRD.The effects of several factors such as the initial pH,final pH,initial reaction temperature and flow rate of CO₂ gas on the morphology and particle size of products were investigated.The formation mechanism of vaterite microspheres was also discussed.The experiment results demonstrate that much more CO₂ bubbles with uniform size are produced by dispersed bubbling carbonization which can increase the supersaturation of CO₂ in solution compared with the direct bubbling carbonization.It is helpful to prepare monodisperse vaterite microspheres with high purity.Low initial temperature and high flow rate of CO₂ gas also improve the produce of vaterite.The optimum conditions are as follows: initial pH of 10.0,final pH of 7.0,flow rate of CO₂ gas of 1 L/min.

Key words: dispersed bubble carbonization, vaterite, synthesis, formation mechanism

CLC Number:

TQ132.32

Zhao Li,Zhuo Minquan,Gong Fuzhong,Wang Jun,Ruan Heng,Li Kaicheng,Li Yanlin. Synthesis of vaterite CaCO₃ microspheres by carbonization method and its formation mechanism[J]. Inorganic Chemicals Industry, 2021, 53(3): 38-43.

Figures/Tables 10

References 36

[1]	Jimoh O A, Ariffin K S, Hussin H B, et al. Synjournal of precipitated calcium carbonate:a review[J]. Carbonates and Evaporites, 2018,33(2):331-346.
[2]	Trushina D B, Bukreeva T V, Kovalchuk M V, et al. CaCO₃ vaterite microparticles for biomedical and personal care application[J]. Materials Science & Engineering:C, 2014,45(12):644-658.
[3]	Konopacka-Łyskawa D. Synjournal methods and favorable conditions for spherical vaterite precipitation:a review[J]. Crystals, 2019,9(4):2-16.
[4]	蒋久信, 吴月, 何瑶, 等. 亚稳态球霰石相碳酸钙的调控制备进展[J]. 无机材料学报, 2017,32(7):681-690.
[5]	Huang S C, Naka K, Chujo Y. A carbonate controlled-addition method for amorphous calcium carbonate spheres stabilized by poly (acrylic acid)s[J]. Langmuir, 2007,23(24):12086-12095. pmid: 17963412
[6]	Lai Y H, Chen L S, Bao W C, et al. Glycine-mediated,selective preparation of monodisperse spherical vaterite calcium carbonate in various reaction systems[J]. Crystal Growth & Design, 2015,15(3):1194-1200.
[7]	Daria B T, Tatiana V B, Maria N A. Size-controlled synjournal of vaterite calcium carbonate by the mixing method:Aiming for nanosized particles[J]. Crystal Growth & Design, 2016,16(3):1311-1319.
[8]	Pérez-Villarejo L, Takabait F, Mahtout L, et al. Synjournal of vaterite CaCO₃ as submicron and nanosized particles using inorganic precursors and sucrose in aqueous medium[J]. Ceramics International, 2018,44(5):5291-5296.
[9]	赵丽娜, 孔治国, 王继库. 碳酸钙中空微球的制备及机理[J]. 化工学报, 2012,43(6):1976-1980.
[10]	郑天文, 陈雪梅. 球霰石碳酸钙微球的合成及其机理[J]. 材料科学与工程学报, 2018,36(3):258-264.
[11]	王耀宣, 袁爱群, 周泽广, 等. 球霰石型纳米碳酸钙椭球形颗粒的合成[J]. 无机盐工业, 2020,52(1):54-58.
[12]	谭婷婷, 仲剑初. 球形碳酸钙的控制合成研究[J]. 无机盐工业, 2019,51(12):30-34.
[13]	陈银霞, 纪献兵, 景长勇. 花状球霰石碳酸钙微球的简易合成与表征[J]. 无机盐工业, 2018,50(3):28-30.
[14]	张晓蕾, 邱勇波. 球霰石碳酸钙的制备及其稳定性研究[J]. 无机盐工业, 2018,50(2):46-49.
[15]	丁杨, 任洋洋, 王丹, 等. 微乳液体系中形貌可控合成碳酸钙的研究[J]. 无机盐工业, 2017,49(6):33-36.
[16]	黄文艺, 马蓝宇, 程昊, 等. 球霰石型碳酸钙微球的制备及在不同溶液中转变过程的研究[J]. 无机盐工业, 2017,49(5):18-21.
[17]	Udrea I, Capat C, Olaru E A, et al. Vaterite synjournal via gas-liquid route under controlled pH conditions[J]. Industrial & Engineering Chemistry Research, 2012,51(24):8185-8193.
[18]	Hadiko G, Han Y S, Fuji M, et al. Synjournal of hollow calcium carbonate particles by the bubble templating method[J]. Materials Letters, 2005,59(19/20):2519-2522.
[19]	Boyjoo Y, Pareek V K, Liu J. Synjournal of micro and nano-sized calcium carbonate particles and their applications[J]. Materials Chemistry A, 2014,2(35):14270-14288.
[20]	Konopacka-Łyskawa D, Koscielska B, Karczewski J, et al. The influence of ammonia and selected amines on the characteristics of calcium carbonate precipitated from calcium chloride solutions via carbonation[J]. Materials Chemistry and Physics, 2017,1931(6):13-18.
[21]	王芬, 余军霞, 肖春桥, 等. CO₂ 碳化法制备微米级球霰石型食品碳酸钙的研究[J]. 硅酸盐通报, 2017,36(1):43-50.
[22]	Svenskaya Y I, Fattah H, Inozemtseva O A, et al. Key parameters for size and shape-controlled synjournal of vaterite particle[J]. Crystal Growth & Design, 2018,18(1):331-337.
[23]	Oral C M, Ercan B. Influence of pH on morphology,size and polymorph of room temperature synthesized calcium carbonate particles[J]. Powder Technology, 2018,339(11):781-788.
[24]	Watanabe H, Yoshiaki M, Takeshi E, et al. Effect of initial pH on formation of hollow calcium carbonate particles by continuous CO₂ gas bubbling into CaCl₂ aqueous solution[J]. Advanced Powder Technology, 2009,20(1):89-93.
[25]	Han Y S, Hadiko G, Fuji M, et al. Effect of flow rate and CO₂ content on the phase and morphology of CaCO₃ prepared by bubbling method[J]. Crystal Growth, 2005,276(3/4):541-548.
[26]	Han Y S, Fuji M, Shehukin D, et al. A new model for the synjournal of hollow particles via the bubble templating method[J]. Crystal Growth & Design, 2009,9(8):3771-3775.
[27]	Radek S, Pérez-Estébanez M, Viani A, et al. Characterization of vaterite synthesized at sized at various temperatures and stirring velocities without use of additives[J]. Powder Technology, 2015,284(11):265-271.
[28]	向乐凯, 李枫, 赵宁, 等. 二氧化碳鼓泡碳化法制备碳酸钙的研究[J]. 无机盐工业, 2016,48(8):46-51.
[29]	Rodriguez-Blanco J D, Shaw S, Bots P, et al. The role of pH and Mg on the stability and crystallization of amorphous calcium carbonate[J]. Journal of Alloys & Compounds, 2012,536(supp_S1), S477-S479.
[30]	Sun J, Wang L S, Zhao D F. Polymorph and morphology of CaCO₃ in relation to precipitation conditions in a bubbling system[J]. Chinese Journal of Chemical Engineering, 2017,25(9):1335-1342.
[31]	Takeshi O, Toshio S, Kiyoshi S. The formation and transformation mechanism of calcium carbonate in water[J]. Geochimica et Cosmochimica Acta, 1987,51(10):2757-2767.
[32]	Zeng Y P, Cao J, Wang Z, et al. The formation of amorphous calcium carbonate and its transformation mechanism to crystalline CaCO₃ in laminar microfluidics[J]. Crystal Growth & Design, 2018,18(3):1710-1721.
[33]	Ding Y, Liu Y Y, Ren Y Y, et al. Controllable synjournal of all the anhydrous CaCO₃ Polymorphs with various morphologies in CaCl₂NH₃-CO₂ aqueous system[J]. Powder Technology, 2018,333(6):410-420.
[34]	Wang Y S, Moo Y X, Chen C P, et al. Fast precipitation of uniform CaCO₃ nanospheres and their transformation to hollow hydroxyap-atite nanospheres[J]. Colloid and Interface Science, 2010,352(2):393-400.
[35]	Vagenas N V, Gatsouli A, Kontoyannis C G. Quantitative analysis of synthetic calcium carbonate polymorphs using FT-IR spectro-scopy[J]. Talanta, 2003,59(4):831-836. doi: 10.1016/S0039-9140(02)00638-0 pmid: 18968970
[36]	Han Y S, Hadiko G, Fuji M, et al. Crystallization and transforma-tion of vaterite at controlled pH[J]. Journal of Crystal Growth, 2006,289(1):269-274.

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Inorganic Acid-Base-Salt Committee of CIESC

Synthesis of vaterite CaCO₃ microspheres by carbonization method and its formation mechanism

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Synthesis of vaterite CaCO3 microspheres by carbonization method and its formation mechanism