多种晶型纳米碳酸钙制备及生长机理的研究进展

doi:10.19964/j.issn.1006-4990.2023-0478

Abstract

Abstract:

As a general material，nano calcium carbonate has a wide range of application prospects and market demand，and has attracted much attention in recent years.However，due to the diversity of crystal forms of nano-calcium carbonate，it has different application potential in different fields.Therefore，the preparation methods，growth influencing factors and formation mechanism of nano-calcium carbonate with different crystal forms have been studied in depth，and the targeted preparation of specific crystal products has become the focus of current research.In this paper，the structure of nano-calcium carbonate was summarized firstly，and the advantages，disadvantages and mechanisms of two common preparation methods were summarized.Secondly，the research progress of crystal form control agent and preparation process on the regulation of nano-calcium carbonate crystal form was emphasized.It was also described that the two reactors were able to enhance the microscopic mixing effect between solutions，thus significantly improving the overall reaction efficiency.Finally，it was reviewed that the crystallization process of nano-calcium carbonate was controlled by both crystal nucleation and growth.By studying these two crystallization processes，the regulation mechanism could be better understood，and finally the precise regulation of crystal form and morphology could be achieved.

Key words: nano calcium carbonate, crystal controlling, synthesis mechanism, crystallization guiding agent

CLC Number:

TQ132.32

LI Yuxing, ZHANG Jincai, CHENG Fangqin. Research progress of preparation and growth mechanism of various crystalline nano-calcium carbonate[J]. Inorganic Chemicals Industry, 2024, 56(5): 1-10.

Figures/Tables 17

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项目	晶系	溶度积常数（log Ksp）	晶胞参数			密度/ （g·m^-³）
项目	晶系	溶度积常数（log Ksp）	a	b	c	密度/ （g·m^-³）
方解石	三方	-8.48	4.99	4.99	17.061	2.71
文石	六方	-7.91	4.13	4.13	8.484	2.66
球霰石	正交	-8.34	4.959 8	7.964 1	3.373	2.93

主要因素	次要因素
过饱和度	反应溶剂
温度	晶型控制剂
搅拌速率	两相界面
反应物溶液的混合速率	pH

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Research progress of preparation and growth mechanism of various crystalline nano-calcium carbonate

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