层状硅酸镍纳米管催化剂的可控制备及其催化性能研究

doi:10.19964/j.issn.1006-4990.2022-0501

Abstract

Abstract:

Nickel phyllosilicate nanotubes（Ni-PSNTs） materials with tubular structure were synthesized by hydrothermal method.The effects of hydrothermal reaction temperature，time，pressure，and sodium hydroxide content on the morphology and structure of the materials were investigated.The results showed that the amount of sodium hydroxide，hydrothermal reaction temperature，and reaction time were key factors affecting the formation of Ni-PSNTs，while the hydrothermal reaction pressure had no significant impact on the formation of Ni-PSNTs.The optimal hydrothermal reaction conditions for the synthesis of Ni-PSNTs materials were determined as hydrothermal reaction temperature of 200 ℃，hydrothermal reaction pressure of 2 MPa，n（Ni）∶n（NaOH）=1∶（54~72），and hydrothermal reaction time of 12 h.In addition，the catalytic performance of the Ni-PSNTs catalyst for the methanation of carbon dioxide was investigated.The results showed that the Ni-PSNTs catalyst exhibited excellent catalytic performance and reaction stability for the methanation of carbon dioxide.After 72 h of reaction testing，the catalyst performance did not significantly decrease，nor did nickel nanoparticles agglomerate and sinter.

Key words: nickel phyllosilicate nanotubes, nickel catalysts, controllable synthesis, methanation, sintering

CLC Number:

O643.3

LI Tong, YIN Hongfeng. Study on controllable preparation of nickel phyllosilicate nanotubes catalysts and their catalytic performance[J]. Inorganic Chemicals Industry, 2023, 55(5): 128-136.

Figures/Tables 10

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References 28

1	WEI Jian， YAO Ruwei， HAN Yu，et al.Towards the development of the emerging process of CO₂ heterogenous hydrogenation into high-value unsaturated heavy hydrocarbons[J].Chemical Society Reviews，2021，50（19）∶10764-10805.
2	YU Yisong， ZHANG Xianwei， LIU Jianwu，et al.Natural gas hydrate resources and hydrate technologies：A review and analysis of the associated energy and global warming challenges[J].Energy & Environmental Science，2021，14（11）：5611-5668.
3	TEBALDI C， RANASINGHE R， VOUSDOUKAS M，et al.Extreme sea levels at different global warming levels[J].Nature Climate Change，2021，11（9）：746-751.
4	胡旭，董灵玉，李文翠，等.光化学法制备过渡金属-氮共掺杂多孔炭基CO₂电还原催化剂[J].无机盐工业，2021，53（6）：8-13.
	HU Xu， DONG Lingyu， LI Wencui，et al.Preparation of transition metal-nitrogen co-doped porous carbon-based CO₂ electro-reduction catalyst through photochemical method[J].Inorganic Chemicals Industry，2021，53（6）：8-13.
5	RAHMAN F A， AZIZ M M A， SAIDUR R，et al.Pollution to solution：Capture and sequestration of carbon dioxide（CO₂） and its utilization as a renewable energy source for a sustainable future[J].Renewable and Sustainable Energy Reviews，2017，71：112- 126.
6	WANG Fei， HE Shan， CHEN Hao，et al.Active site dependent reaction mechanism over Ru/CeO₂ catalyst toward CO₂ methanati-on[J].Journal of the American Chemical Society，2016，138（19）：6298-6305.
7	QUINDIMIL A， ONRUBIA-CALVO J A， DAVÓ-QUIÑONERO A，et al.Intrinsic kinetics of CO₂ methanation on low-loaded Ni/Al₂O₃ catalyst：Mechanism，model discrimination and parameter estimation[J].Journal of CO₂ Utilization，2022，57：101888.
8	WU Hungchi， CHEN T C， WU Jiahuang，et al.Influence of sodium-modified Ni/SiO₂ catalysts on the tunable selectivity of CO₂ hydrogenation：Effect of the CH₄ selectivity，reaction pathway and mech-anism on the catalytic reaction[J].Journal of Colloid and Interface Science，2021，586：514-527.
9	ASHOK J， PATI S， HONGMANOROM P，et al.A review of recent catalyst advances in CO₂ methanation processes[J].Catalysis Today，2020，356：471-489.
10	鲁杰，吴华东，马尚，等.镍系催化剂的制备、表征及其甲烷化性能的研究[J].无机盐工业，2019，51（5）：78-81，96.
	LU Jie， WU Huadong， MA Shang，et al.Preparation and characterization of nickel-based catalyst and its methanation performance[J].Inorganic Chemicals Industry，2019，51（5）：78-81， 96.
11	TSIOTSIAS A I， CHARISIOU N D， YENTEKAKIS I V，et al.Bimetallic Ni-based catalysts for CO₂ methanation：A review[J].Nanomaterials，2020，11（1）：28.
12	ABE T， TANIZAWA M， WATANABE K，et al.CO₂ methanation property of Ru nanoparticle-loaded TiO₂ prepared by a polygonal barrel-sputtering method[J].Energy & Environmental Science，2009，2（3）：315-321.
13	GAC W， ZAWADZKI W， ROTKO M，et al.Effects of support composition on the performance of nickel catalysts in CO₂ methanation reaction[J].Catalysis Today，2020，357：468-482.
14	STRUCKS P， FAILING L， KALUZA S.A short review on Ni-catalyzed methanation of CO₂：Reaction mechanism，catalyst deactivation，dynamic operation[J].Chemie Ingenieur Technik，2021，93（10）：1526-1536.
15	WANG Yongzhao， WU Ruifang， ZHAO Yongxiang.Effect of ZrO₂ promoter on structure and catalytic activity of the Ni/SiO₂ catalyst for CO methanation in hydrogen-rich gases[J].Catalysis Today，2010，158（3/4）：470-474.
16	YAN Yong， DAI Yihu， YANG Yanhui.Improved stability of Y₂O₃ supported Ni catalysts for CO₂ methanation by precursor-determined metal-support interaction[J].Applied Catalysis B：Environmental，2018，237：504-512.
17	LIU Qing， TIAN Yuanyu.One-pot synthesis of NiO/SBA-15 mo-nolith catalyst with a three-dimensional framework for CO₂ meth-anation[J].International Journal of Hydrogen Energy，2017，42（17）：12295-12300.
18	ROMERO-SÁEZ M， DONGIL A B， BENITO N，et al.CO₂ methanation over nickel-ZrO₂ catalyst supported on carbon nanotubes：A comparison between two impregnation strategies[J].Applied Catalysis B：Environmental，2018，237：817-825.
19	IGLESIAS I， QUINDIMIL A， MARINO F，et al.Journal of Hydrogen Energy，2019，44（3）：1710-1719.
20	XU Leilei， LIAN Xinbo， CHEN Mindong，et al.CO₂ methanation over CoNi bimetal-doped ordered mesoporous Al₂O₃ catalysts with enhanced low-temperature activities[J].International Journal of Hydrogen Energy，2018，43（36）：17172-17184.
21	YUE Hairong， ZHAO Yujun， ZHAO Shuo，et al.A copper-phyllosilicate core-sheath nanoreactor for carbon-oxygen hydrogenolysis reactions[J].Nature Communications，2013，4：2339.
22	ZHANG Chengxi， ZHU Wancheng， LI Shuirong，et al.Sintering-resistant Ni-based reforming catalysts obtained via the nanoconfinement effect[J].Chemical Communications，2013，49（82）：9383-9385.
23	BIAN Zhoufeng， SURYAWINATA I Y， KAWI S.Highly carbon resistant multicore-shell catalyst derived from Ni-Mg phyllosilicate nanotubes@silica for dry reforming of methane[J].Applied Catalysis B：Environmental，2016，195：1-8.
24	MCDONALD A， SCOTT B， VILLEMURE G.Hydrothermal preparation of nanotubular particles of a 1∶1 nickel phyllosilicate[J].Microporous and Mesoporous Materials，2009，120（3）：263- 266.
25	WANG Hui， ZHAO Wenru， REHMAN M U，et al.Copper phyllosilicate nanotube catalysts for the chemosynthesis of cyclohexane via hydrodeoxygenation of phenol[J].ACS Catalysis，2022，12（8）：4724-4736.
26	KORYTKOVA E N， PIVOVAROVA L N， DROZDOVA I A，et al.Synthesis of nanotubular nickel hydrosilicates and nickel-magnesium hydrosilicates under hydrothermal conditions[J].Glass Phy- sics and Chemistry，2005，31（6）：797-802.
27	KORYTKOVA E N， MASLOV A V， PIVOVAROVA L N，et al.Synthesis of nanotubular Mg₃Si₂O₅（OH）₄-Ni₃Si₂O₅（OH）₄ silicat-es at elevated temperatures and pressures[J].Inorganic Materials，2005，41（7）：743-749.
28	PERBOST R， AMOURIC M， OLIVES J.Influence of cation size on the curvature of serpentine minerals：HRTEM-AEM study and elastic theory[J].Clays and Clay Minerals，2003，51（4）：430- 438.

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Study on controllable preparation of nickel phyllosilicate nanotubes catalysts and their catalytic performance

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