无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2025, Vol. 57 ›› Issue (11): 65-73.doi: 10.19964/j.issn.1006-4990.2024-0575

• 环境·健康·安全 • 上一篇    下一篇

高炉矿渣优化配比泡沫混凝土制备与性能研究

杨旭荣1(), 郭智云1, 李灿华1(), 都刚1, 马孟臣1, 李家茂2   

  1. 1.安徽工业大学冶金工程学院,安徽 马鞍山 243002
    2.安徽工业大学材料科学与工程学院,安徽 马鞍山 243002
  • 收稿日期:2024-10-31 出版日期:2025-11-10 发布日期:2025-07-17
  • 通讯作者: 李灿华(1979— ),男,博士,教授,主要研究方向为新污染物检测及控制技术研究,绿色冶金与增值冶金研究;E-mail:licanhua1979@163.com
  • 作者简介:杨旭荣(1999— ),女,硕士研究生,主要研究方向为绿色低碳型泡沫混凝土的制备与研究;E-mail:1723269168@qq.com
  • 基金资助:
    安徽省中央引导地方科技发展专项(202107d06050012);安徽高校研究生科学研究项目(YJS202110333)

Study on peparation and performance of foam concrete by optimization of blast furnace slag proportioning

YANG Xurong1(), GUO Zhiyun1, LI Canhua1(), DU Gang1, MA Mengchen1, LI Jiamao2   

  1. 1. School of Metallurgical Engineering,Anhui University of Technology,Ma′anshan 243002,China
    2. School of Materials Science and Engineering,Anhui University of Technology,Ma′anshan 243002,China
  • Received:2024-10-31 Published:2025-11-10 Online:2025-07-17

摘要:

高炉矿渣(BFS)作为工业固体废物,被认为是制备绿色低碳泡沫混凝土的理想原材料。采用BFS高效替代水泥制备泡沫混凝土,结合动物蛋白发泡剂提高材料性能。通过优化BFS替代率和调整发泡剂掺量改善孔隙结构。探究BFS和发泡剂掺量对泡沫混凝土抗压强度、干密度及导热系数等性能的影响,并利用图像分析法获取孔结构参数。研究结果表明:适量掺入BFS可提高泡沫混凝土抗压强度并降低干密度,当BFS替代率达80%时,其28 d抗压强度为5.1 MPa,干密度为1 057.06 kg/m3;泡沫混凝土的干密度和导热系数随着发泡剂掺量的增加而减小,最大降幅分别为17.1%和37.0%;发泡剂最佳掺量为3%,孔径尺寸分布趋于均匀,孔形状因子为1.182,孔隙形状接近球形,粘连现象较少;所制备的泡沫混凝土导热系数为0.094 2~0.059 3 W/(m·K),展现出优异保温性能。研究结果为建筑材料碳减排提供技术支撑,实现高效保温与绿色低碳发展的融合。

关键词: 泡沫混凝土, 高炉矿渣, 孔隙结构, 导热系数, 力学性能

Abstract:

Blast furnace slag(BFS),as an industrial solid waste,is considered as an ideal raw material for the preparation of green and low-carbon foam concrete.In this paper,BFS was used to prepare foam concrete by efficiently replacing cement and combing it with an animal protein blowing agent to enhance the material properties.The pore structure was optimized by adjusting the replacement rate of BFS and the blowing agent dosage.The effects of BFS and blowing agent admixture on the properties of foam concrete,such as compressive strength,dry density,and thermal conductivity,were investigated.Additionally,pore structure parameters were obtained through image analysis.The results of the study showed that the appropriate amount of BFS could improve compressive strength and reduce dry density.When the substitution rate reached 80%,the 28 d compressive strength was 5.1 MPa,and the dry density was 1 057.06 kg/m3.The dry density and thermal conductivity of foam concrete were decreased with an increase in amount of the blowing agent,with the maximum reduction reaching 17.1% and 37.0% respectively.The optimal dosage of foaming agent was 3%,the pore size distribution was the most uniform,the pore shape factor was 1.182,the pores were close to spherical,and the adhesion phenomenon was minimized.The thermal conductivity of the prepared foam concrete was ranged from 0.094 2~0.059 3 W/(m·K),which showed the excellent thermal insulation performance.This study provided technical support for carbon emission reduction in building materials and enabled the integration of efficient thermal insulation and green low-carbon development.

Key words: foam concrete, blast furnace slag, pore structure, thermal conductivity, mechanical properties

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