无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2013, Vol. 45 ›› Issue (5): 24-.

• 论文 • 上一篇    下一篇

硫酸酸解攀西钛精矿技术研究

马维平   

  1. 攀钢集团研究院有限公司,钒钛资源综合利用国家重点实验室,四川攀枝花  617000
  • 发布日期:2013-05-03

Research on acidolysis of Panxi titanium concentrate with sulfuric acid

 MA  Wei-Ping   

  1. State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization,Pangang Group
    Research Institute Co.,Ltd.,Panzhihua 617000,China
  • Online:2013-05-03

摘要: 为提高攀西钛精矿中钛资源的利用率,系统探讨了硫酸酸解攀西钛精矿的工艺原理、技术参数及热力学。研究结果表明,通过优化反应硫酸浓度、酸矿比、熟化时间等因素可使硫酸酸解攀西钛精矿的酸解率达95%以上。此外钛精矿酸解反应若用98%(质量分数,下同)硫酸与钛精矿预混后,稀释至反应酸浓度引发反应总放热量为 1 397.5 kJ/kg,反应剧烈、危险系数大。改用92%硫酸与钛精矿预混引发反应总热量为1 267.4 kJ/kg,能够将反应产物加热到271 ℃,反应较温和,且其总热量完全满足酸解反应的需求。

关键词: 钛精矿, 硫酸, 熟化时间, 酸解温度, 酸解率

Abstract: In order to improve the utilization of titanium resources in Panxi titanium concentrate,the process principle,technical parameters,and thermodynamics of acidolysis of Panxi titanium concentrate with sulfuric acid have been studied.Research results showed that,acidolysis ratio could reach more than 95% by optimizing the reaction factors,such as sulfuric acid concentration,acid/ore ratio,and curing time.In addition,if use 98%(mass fraction,same below) sulfuric acid to pre-mix with titanium concentrate,total heat release,aroused by dilution to the reaction concentration,was 1 397.5 kJ/kg,and the reaction was violent and dangerous.However,if use 92% sulfuric acid,the total heat release was 1 267.4 kJ/kg,which could heat the product to 271 ℃,the reaction was mild and total heat could totally meet the requirements of acidolysis reaction.

Key words: titanium concentrate, sulfuric acid, curing time, acidolysis temperature, acidolysis ratio

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