无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (7): 73-.

• 论文 • 上一篇    下一篇

天然矿物负载纳米二氧化钛复合材料的制备与表征

樊雪敏1,张汉超2,李光辉1,白春华1,徐志勇1,范雯阳1   

  1. 1.内蒙古科技大学矿业研究院,内蒙古包头 014010;2. 北京中矿环保科技股份有限公司
  • 出版日期:2016-07-10 发布日期:2016-07-25

Preparation and characterization of natural mineral loaded nano-sized TiO2 composites

Fan Xuemin1,Zhang Hanchao2,Li Guanghui1,Bai Chunhua1,Xu Zhiyong1,Fan Wenyang1   

  1. 1. Mining Research Institute,Inner Mongolia University of Science and Technology,Baotou 014010,China;
    2.Beijing Zhongkuang Environmental Protection Technologies Inc.
  • Published:2016-07-10 Online:2016-07-25

摘要: 采用水解沉淀法制备了白炭黑、硅藻土和蛋白土负载纳米二氧化钛复合材料。通过SEM和XRD等手段对复合材料分别进行了表征,并用罗丹明B溶液的光催化脱色率来评价复合材料的光催化性能。结果表明,在复合材料表面负载了大量的二氧化钛且主要以锐钛型为主,白炭黑、硅藻土、蛋白土复合材料表面负载的二氧化钛的平均粒径分别为14.6、25.7、22.9 nm。二氧化钛/白炭黑、二氧化钛/硅藻土、二氧化钛/蛋白土3种复合材料的最佳制备条件分别为:700 ℃煅烧2 h,二氧化钛负载量为30%;700 ℃煅烧2 h,二氧化钛负载量为20%;600 ℃煅烧2 h,二氧化钛负载量为20%。3种复合材料对罗丹明B溶液15 min的降解率分别达到98.6%、97.4%和87.7%。

关键词: 纳米二氧化钛, 复合材料, 光催化, 降解

Abstract: Silica,diatomite,and opal loaded nano-sized TiO2 composites were prepared by hydrolysis precipitation method.The composite materials were characterized by means of SEM and XRD,and photocatalytic properties thereof were evaluated by the photocatalytic decolorization rate of Rhodamine B solution.Results showed:a large amount of TiO2 was loaded on the surface of the composite material,and the main type was anatase;and the average particle sizes of TiO2 were 14.6 nm,25.7 nm,and 22.9 nm on the surfaces of silica,diatomite,and opal respectively.The best preparation conditions of the three kinds of composites of TiO2/silica,TiO2/diatomite,and TiO2/opal were respectively:700 ℃ calcined for 2 h,and the loading of TiO2 was 30%;700 ℃ calcined for 2 h,and the loading of TiO2 was 20%;600 ℃ calcined for 2 h,and the loading of TiO2 was 20%.The degradation rates of three kinds of composite materials on the degradation of Rhodamine B for 15 min were 98.6%,97.4%,and 87.7%,respectively.

Key words: nano-sized TiO2, compound material, photocatalysis, degradation

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