非贵金属催化剂用于丙烷脱氢的研究进展

doi:10.19964/j.issn.1006-4990.2023-0274

摘要/Abstract

摘要：

丙烯是一种重要的工业原料，主要用于生产聚丙烯、丙烯腈、异丙醇、丙酮和环氧丙烷等。随着对丙烯需求的日益增长，丙烷脱氢技术已被广泛应用于丙烯工业生产中。铂基、铬基催化剂虽然在丙烷脱氢反应中的活性很高，却容易中毒失活。金属氧化物作为可替代型非贵金属催化剂被人们广泛关注。首先，介绍金属氧化物催化丙烷脱氢的反应路径及失活机理，指出增强C—H活化能力、缓解活性组分重构及还原是提高金属氧化物丙烷脱氢性能的关键。然后，对几种代表性的金属氧化物催化剂进行了详细的综述，总结归纳各类催化剂的作用机制及活性物种，并分析讨论相应催化剂存在的问题。最后提出未来丙烷脱氢催化剂的重点研究方向，有望为低碳烷烃活化直接制取化学品提供新的思路。

关键词: 丙烷脱氢, 金属氧化物, 活性位点, 反应路径, 稳定性, 非贵金属催化剂

Abstract:

Propylene is an important industrial raw material mainly used in the production of polypropylene，acrylonitrile，isopropyl alcohol，acetone and propylene oxide.With the increasing demand for propylene，the technology of propane dehydrogenation has been widely used in the industrial production of propylene.Although platinum-based and chromium-based catalysts have high activity in propane dehydrogenation，they are also prone to poisoning and deactivation.Metal oxides have attracted widespread attention as alternative non-precious metal catalysts.Firstly，the reaction pathway and deactivation mechanism of propane dehydrogenation catalyzed by metal oxides were introduced.It was pointed out that enhancing the C—H activation ability，alleviating the reconstruction and reduction of active components were the key to improving the propane dehydrogenation performance of metal oxide catalysts.Then，several representative metal oxide catalysts were reviewed in detail，the mechanism of action and active species of various catalysts were summarized，and the existing problems of corresponding catalysts were analyzed and discussed.Finally，key research directions for future propane dehydrogenation catalysts were proposed，which was expected to provide new ideas for the direct production of chemicals through the activation of low-carbon alkanes.

Key words: propane dehydrogenation, metal oxides, active site, reaction pathway, stability, non-precious metal catalysts

中图分类号:

TQ138

王延苏, 刘国柱, 于海斌. 非贵金属催化剂用于丙烷脱氢的研究进展[J]. 无机盐工业, 2023, 55(12): 1-11.

WANG Yansu, LIU Guozhu, YU Haibin. Research progress of non-precious metal catalysts for propane dehydrogenation[J]. Inorganic Chemicals Industry, 2023, 55(12): 1-11.

图/表 11

图1

图2

图3

表1

图4

图 5

图6

图7

图8

图9

图10

参考文献 65

1	SUN Minglei， HU Zhongpan， WANG Haoyu， et al. Design strategies of stable catalysts for propane dehydrogenation to propylene［J］. ACS Catalysis， 2023， 13（7）：4719-4741. doi: 10.1021/acscatal.3c00103
2	QI Wei， YAN Pengqiang， SU Dang sheng. Oxidative dehydrogenation on nanocarbon：Insights into the reaction mechanism and kinetics via in situ experimental methods［J］. Accounts of Chemical Research， 2018， 51（3）：640-648. doi: 10.1021/acs.accounts.7b00475 pmid: 29446621
3	CARRERO C A， SCHLOEGL R， WACHS I E， et al. Critical literature review of the kinetics for the oxidative dehydrogenation of propane over well-defined supported vanadium oxide catalysts［J］. ACS Catalysis， 2014， 4（10）：3357-3380. doi: 10.1021/cs5003417
4	张雨宸，张耀远，吴芹，等. 丙烷脱氢用高稳定性Pt基催化剂研究进展［J］. 化工进展， 2022， 41（9）：4733-4753. doi: 10.16085/j.issn.1000-6613.2021-2449
	ZHANG Yuchen， ZHANG Yaoyuan， WU Qin， et al. Advances in high stable Pt based catalysts for propane dehydrogenation［J］. Chemical Industry and Engineering Progress， 2022， 41（9）：4733-4753. doi: 10.16085/j.issn.1000-6613.2021-2449
5	WANG Yang， CHEN Sai， SUN Jiachen， et al. Roles of V-O sites for non-oxidative propane dehydrogenation over supported vanadium oxides［J］. Science China Materials， 2023， 66（3）：1062-1070. doi: 10.1007/s40843-022-2214-8
6	SATTLER J J H B， RUIZ-MARTINEZ J， SANTILLAN-JIMENEZ E， et al. Catalytic dehydrogenation of light alkanes on metals and metal oxides［J］. Chemical Reviews， 2014， 114（20）：10613- 10653. doi: 10.1021/cr5002436 pmid: 25163050
7	CAMACHO-BUNQUIN J， AICH P， FERRANDON M， et al. Single-site zinc on silica catalysts for propylene hydrogenation and propane dehydrogenation：Synthesis and reactivity evaluation using an integrated atomic layer deposition-catalysis instrument［J］. Journal of Catalysis， 2017， 345：170-182. doi: 10.1016/j.jcat.2016.10.017
8	HU Bo， “BEAN” GETSOIAN A， SCHWEITZER N M， et al. Selective propane dehydrogenation with single-site Co^II on SiO₂ by a non-redox mechanism［J］. Journal of Catalysis， 2015， 322：24-37. doi: 10.1016/j.jcat.2014.10.018
9	HU Bo， SCHWEITZER N M， ZHANG Guanghui， et al. Isolated Fe^II on silica as a selective propane dehydrogenation catalyst［J］. ACS Catalysis， 2015， 5（6）：3494-3503. doi: 10.1021/acscatal.5b00248
10	ZHAO Zhijian， WU Tengfang， XIONG Chuanye， et al. Hydroxyl-mediated non-oxidative propane dehydrogenation over VO _x /γ-Al₂O₃ catalysts with improved stability［J］. Angewandte Chemie International Edition， 2018， 57（23）：6791-6795. doi: 10.1002/anie.v57.23
11	ZHANG Yiwei， ZHOU Yuming， HUANG Li， et al. Structure and catalytic properties of the Zn-modified ZSM-5 supported platinum catalyst for propane dehydrogenation［J］. Chemical Engineering Journal， 2015， 270：352-361. doi: 10.1016/j.cej.2015.01.008
12	ERSOY B， GUNAY V. Effects of La₂O₃ addition on the thermal stability of γ-Al₂O₃ gels［J］. Ceramics International， 2004， 30（2）：163-170. doi: 10.1016/S0272-8842(03)00084-1
13	XIE Yufei， LUO Ran， SUN Guodong， et al. Facilitating the reduction of V—O bonds on VO _x /ZrO₂ catalysts for non-oxidative propane dehydrogenation［J］. Chemical Science， 2020， 11（15）：3845-3851. doi: 10.1039/d0sc00690d pmid: 34122852
14	LIU Gang， ZHAO Zhijian， WU Tengfang， et al. Nature of the active sites of VO _x /Al₂O₃ catalysts for propane dehydrogenation［J］. ACS Catalysis， 2016， 6（8）：5207-5214. doi: 10.1021/acscatal.6b00893
15	CHEN Sai， ZENG Liang， MU Rentao， et al. Modulating lattice oxygen in dual-functional Mo—V—O mixed oxides for chemical looping oxidative dehydrogenation［J］. Journal of the American Chemical Society， 2019， 141（47）：18653-18657. doi: 10.1021/jacs.9b09235
16	CHEN Miao， XU Jie， SU Fangzheng， et al. Dehydrogenation of propane over spinel-type gallia-alumina solid solution catalysts［J］. Journal of Catalysis， 2008， 256（2）：293-300. doi: 10.1016/j.jcat.2008.03.021
17	YUN J H， LOBO R F. Catalytic dehydrogenation of propane over iron-silicate zeolites［J］. Journal of Catalysis， 2014， 312：263- 270. doi: 10.1016/j.jcat.2014.02.007
18	WANG Guowei， ZHANG Huanling， ZHU Qingqing， et al. Sn-containing hexagonal mesoporous silica（HMS） for catalytic dehydrogenation of propane：An efficient strategy to enhance stabili- ty［J］. Journal of Catalysis， 2017， 351：90-94. doi: 10.1016/j.jcat.2017.04.018
19	WANG Haoren， HUANG Huiwen， BASHIR K， et al. Isolated Sn on mesoporous silica as a highly stable and selective catalyst for the propane dehydrogenation［J］. Applied Catalysis A：General， 2020， 590：117291.
20	DAI Yihu， GU Jingjing， TIAN Suyang， et al. γ-Al₂O₃ sheet-stabilized isolate Co²⁺ for catalytic propane dehydrogenation［J］. Journal of Catalysis， 2020， 381：482-492. doi: 10.1016/j.jcat.2019.11.026
21	BAI Peng， MA Zhipeng， LI Tingting， et al. Relationship between surface chemistry and catalytic performance of mesoporous γ-Al₂O₃ supported VO _x catalyst in catalytic dehydrogenation of propane［J］. ACS Applied Materials & Interfaces， 2016， 8（39）：25979-25990.
22	SEARLES K， SIDDIQI G， SAFONOVA O V， et al. Silica-supported isolated gallium sites as highly active，selective and stable propane dehydrogenation catalysts［J］. Chemical Science， 2017， 8（4）：2661-2666. doi: 10.1039/C6SC05178B
23	ESTES D P， SIDDIQI G， ALLOUCHE F， et al. C—H activation on Co，O sites：Isolated surface sites versus molecular analogs［J］. Journal of the American Chemical Society， 2016， 138（45）：14987-14997. doi: 10.1021/jacs.6b08705
24	ZHAO Yiqing， SOHN H， HU Bo， et al. Zirconium modification promotes catalytic activity of a single-site cobalt heterogeneous catalyst for propane dehydrogenation［J］. ACS Omega， 2018， 3（9）：11117-11127. doi: 10.1021/acsomega.8b00862 pmid: 31459220
25	CHEN Chong， ZHANG Shoumin， WANG Zheng， et al. Ultrasmall Co confined in the silanols of dealuminated beta zeolite：A highly active and selective catalyst for direct dehydrogenation of propane to propylene［J］. Journal of Catalysis， 2020， 383：77-87. doi: 10.1016/j.jcat.2019.12.037
26	CHEN Chong， HU Zhongpan， REN Jintao， et al. ZnO nanoclusters supported on dealuminated zeolite β as a novel catalyst for direct dehydrogenation of propane to propylene［J］. ChemCat- Chem， 2019， 11（2）：868-877.
27	HU Zhongpan， QIN Gangqiang， HAN Jingfeng， et al. Atomic insight into the local structure and microenvironment of isolated co-motifs in MFI zeolite frameworks for propane dehydrogenation［J］. Journal of the American Chemical Society， 2022， 144（27）：12127-12137. doi: 10.1021/jacs.2c02636
28	仇新玲，柴瑞栋，仲富，等. 响应面法研究非贵金属Co基催化剂于丙烷脱氢制丙烯的最佳工艺条件［J］. 燃料化学学报， 2022， 50（11）：1498-1510.
	QIU Xinling， CHAI Ruidong， ZHONG Fu， et al. Investigate of the optimum process conditions for Co/HZSM-5 catalyzed propane dehydrogenation by a response surface method［J］. Journal of Fuel Chemistry and Technology， 2022， 50（11）：1498-1510. doi: 10.1016/S1872-5813(22)60027-6
29	FANG Xuejin， LIU Bing， CAO Kun， et al. Particle-size-dependent methane selectivity evolution in cobalt-based fischer-tropsch synthesis［J］. ACS Catalysis， 2020， 10（4）：2799-2816. doi: 10.1021/acscatal.9b05371
30	宋卫余，罗磊，王志霞，等. 用于丙烷脱氢的Co基催化剂及其制备方法：中国， 115155591B［P］. 2023-08-18.
31	SUN Yanan， WU Yimin， SHAN Honghong， et al. Studies on the nature of active cobalt species for the production of methane and propylene in catalytic dehydrogenation of propane［J］. Catalysis Letters， 2015， 145（7）：1413-1419. doi: 10.1007/s10562-015-1533-4
32	LIU Yiwei， LI Zhi， YU Qiuying， et al. A general strategy for fabricating isolated single metal atomic site catalysts in Y zeolite［J］. Journal of the American Chemical Society， 2019， 141（23）：9305-9311. doi: 10.1021/jacs.9b02936 pmid: 31117651
33	LI Zhi， JI Shufang， LIU Yiwei， et al. Well-defined materials for heterogeneous catalysis：From nanoparticles to isolated single-atom sites［J］. Chemical Reviews， 2020， 120（2）：623-682. doi: 10.1021/acs.chemrev.9b00311 pmid: 31868347
34	GROMMET A B， FELLER M， KLAJN R. Chemical reactivity under nanoconfinement［J］. Nature Nanotechnology， 2020， 15（4）：256-271. doi: 10.1038/s41565-020-0652-2 pmid: 32303705
35	LI Zhanyong， PETERS A W， BERNALES V， et al. Metal-organic framework supported cobalt catalysts for the oxidative dehydrogenation of propane at low temperature［J］. ACS Central Science， 2017， 3（1）：31-38. doi: 10.1021/acscentsci.6b00290 pmid: 28149950
36	LI Zhanyong， PETERS A W， PLATERO-PRATS A E， et al. Fine-tuning the activity of metal-organic framework-supported cobalt catalysts for the oxidative dehydrogenation of propane［J］. Journal of the American Chemical Society， 2017， 139（42）：15251-15258. doi: 10.1021/jacs.7b09365 pmid: 28976757
37	BERNALES V， ORTUÑO M A， TRUHLAR D G， et al. Computational design of functionalized metal-organic framework nodes for catalysis［J］. ACS Central Science， 2018， 4（1）：5-19. doi: 10.1021/acscentsci.7b00500 pmid: 29392172
38	ZHAI Quanguo， BU Xianhui， ZHAO Xiang， et al. Pore space partition in metal-organic frameworks［J］. Accounts of Chemical Research， 2017， 50（2）：407-417. doi: 10.1021/acs.accounts.6b00526 pmid: 28106984
39	YANG Zhengkun， CHEN Bingxu， CHEN Wenxing， et al. Directly transforming copper（I） oxide bulk into isolated single-atom copper sites catalyst through gas-transport approach［J］. Nature Communications， 2019， 10：3734. doi: 10.1038/s41467-019-11796-4 pmid: 31427572
40	SUN Xiaohui， SUAREZ A I O， MEIJERINK M， et al. Manufacture of highly loaded silica-supported cobalt Fischer-Tropsch catalysts from a metal organic framework［J］. Nature Communications， 2017， 8：1680. doi: 10.1038/s41467-017-01910-9 pmid: 29162823
41	YIN Peiqun， YAO Tao， WU Yuen， et al. Single cobalt atoms with precise N-coordination as superior oxygen reduction reaction catalysts［J］. Angewandte Chemie（International Ed.in English）， 2016， 55（36）：10800-10805.
42	LUO Shijian， LI Xiaoman， ZHANG Baohai， et al. MOF-derived Co₃O₄@NC with core-shell structures for N₂ electrochemical reduction under ambient conditions［J］. ACS Applied Materials & Interfaces， 2019， 11（30）：26891-26897.
43	HAN Xiaopeng， LING Xiaofei， WANG Ying， et al. Generation of nanoparticle，atomic-cluster，and single-atom cobalt catalysts from zeolitic imidazole frameworks by spatial isolation and their use in zinc-air batteries［J］. Angewandte Chemie International Edition， 2019， 58（16）：5359-5364. doi: 10.1002/anie.v58.16
44	WANG Yansu， SUO Yujun， REN Jintao， et al. Spatially isolated cobalt oxide sites derived from MOFs for direct propane dehydrogenation［J］. Journal of Colloid and Interface Science， 2021， 594：113-121. doi: 10.1016/j.jcis.2021.03.023 pmid: 33756359
45	HUANG Zijun， HE Dedong， DENG Weihua， et al. Illustrating new understanding of adsorbed water on silica for inducing tetrahedral cobalt（Ⅱ） for propane dehydrogenation［J］. Nature Communications， 2023， 14：100. doi: 10.1038/s41467-022-35698-0 pmid: 36609564
46	SCHWEITZER N M， HU Bo， DAS U， et al. Propylene hydrogenation and propane dehydrogenation by a single-site Zn²⁺ on silica catalyst［J］. ACS Catalysis， 2014， 4（4）：1091-1098. doi: 10.1021/cs401116p
47	SONG Shaojia， YANG Kun， ZHANG Peng， et al. Silicalite-1 stabilizes Zn-hydride species for efficient propane dehydrogenati- on［J］. ACS Catalysis， 2022， 12（10）：5997-6006. doi: 10.1021/acscatal.2c00928
48	ZHAO Dan， TIAN Xinxin， DORONKIN D E， et al. in situ formation of ZnO _x species for efficient propane dehydrogenation［J］. Nature， 2021， 599（7884）：234-238. doi: 10.1038/s41586-021-03923-3
49	QU Yingmin， LI Ganggang， ZHAO Ting， et al. Low-temperature direct dehydrogenation of propane over binary oxide catalysts：Insights into geometric effects and active sites［J］. ACS Sustainable Chemistry & Engineering， 2021， 9（38）：12755-12765.
50	WANG Guowei， ZHANG Huanling， WANG Haoren， et al. The role of metallic Sn species in catalytic dehydrogenation of propane：Active component rather than only promoter［J］. Journal of Catalysis， 2016， 344：606-608. doi: 10.1016/j.jcat.2016.11.003
51	WANG Haoren， HUANG Huiwen， BASHIR K， et al. Isolated Sn on mesoporous silica as a highly stable and selective catalyst for the propane dehydrogenation［J］. Applied Catalysis A：General， 2020， 590：117291.
52	YUE Yuanyuan， FU Jing， WANG Chuanming， et al. Propane dehydrogenation catalyzed by single Lewis acid site in Sn-Beta zeolite［J］. Journal of Catalysis， 2021， 395：155-167. doi: 10.1016/j.jcat.2020.12.019
53	SOKOLOV S， STOYANOVA M， RODEMERCK U， et al. Effect of support on selectivity and on-stream stability of surface VO _x species in non-oxidative propane dehydrogenation［J］. Catalysis Science & Technology， 2014， 4（5）：1323-1332.
54	CHEN Chong， SUN Minglei， HU Zhongpan， et al. Nature of active phase of VO _x catalysts supported on Si-Beta for direct dehydrogenation of propane to propylene［J］. Chinese Journal of Catalysis， 2020， 41（2）：276-285. doi: 10.1016/S1872-2067(19)63444-3
55	WU Tengfang， LIU Gang， ZENG Liang， et al. Structure and catalytic consequence of Mg-modified VO _x /Al₂O₃ catalysts for propane dehydrogenation［J］. AIChE Journal， 2017， 63（11）：4911-4919. doi: 10.1002/aic.v63.11
56	GU Yu， LIU Haijun， YANG Miaomiao， et al. Highly stable phosphine modified VO _x /Al₂O₃ catalyst in propane dehydrogenation［J］. Applied Catalysis B：Environmental， 2020， 274：119089.
57	RODEMERCK U， STOYANOVA M， KONDRATENKO E V， et al. Influence of the kind of VO _x structures in VO _x /MCM-41 on activity，selectivity and stability in dehydrogenation of propane and isobutane［J］. Journal of Catalysis， 2017， 352：256-263. doi: 10.1016/j.jcat.2017.05.022
58	XIE Zean， YU Tingting， SONG Weiyu， et al. Highly active nanosized anatase TiO_2– _x oxide catalysts in situ formed through reduction and Ostwald ripening processes for propane dehydrogenati- on［J］. ACS Catalysis， 2020， 10（24）：14678-14693. doi: 10.1021/acscatal.0c02825
59	SCHREIBER M W， PLAISANCE C P， BAUMGÄRTL M， et al. Lewis-Brønsted acid pairs in Ga/H-ZSM-5 to catalyze dehydrogenation of light alkanes［J］. Journal of the American Chemical Society， 2018， 140（14）：4849-4859. doi: 10.1021/jacs.7b12901 pmid: 29488757
60	PHADKE N M， MANSOOR E， BONDIL M， et al. Mechanism and kinetics of propane dehydrogenation and cracking over Ga/H-MFI prepared via vapor-phase exchange of H-MFI with GaCl₃ ［J］. Journal of the American Chemical Society， 2019， 141（4）：1614-1627. doi: 10.1021/jacs.8b11443 pmid: 30586991
61	YUAN Yong， LEE J S， LOBO R F. Ga⁺-chabazite zeolite：A highlhly selective catalyst for nonoxidative propane dehydrogenation［J］. Journal of the American Chemical Society， 2022， 144（33）：15079-15092. doi: 10.1021/jacs.2c03941 pmid: 35793461
62	NI Lingli， KHARE R， BERMEJO-DEVAL R， et al. Highly active and selective sites for propane dehydrogenation in zeolite Ga-BEA［J］. Journal of the American Chemical Society， 2022， 144（27）：12347-12356. doi: 10.1021/jacs.2c03810
63	YUAN Yong， LOBO R F. Propane dehydrogenation over extra-fra-mework In（i） in chabazite zeolites［J］. Chemical Science， 2022， 13（10）：2954-2964. doi: 10.1039/d1sc05866e pmid: 35382476
64	HAN Jingtan， XUE Zhonghua， ZHANG Ke， et al. Atomically dispersed Ni-based anti-coking catalysts for methanol dehydrogenation in a fixed-bed reactor［J］. ACS Catalysis， 2020， 10（21）：12569-12574. doi: 10.1021/acscatal.0c03328
65	MA Rui， GAO Junxian， KOU Jiajing， et al. Insights into the nature of selective nickel sites on Ni/Al₂O₃ catalysts for propane dehydrogenation［J］. ACS Catalysis， 2022， 12（20）：12607-12616. doi: 10.1021/acscatal.2c03240

催化剂	反应温度/℃	反应原料比	丙烷初始转化率/%	丙烯选择性/%	失活速率K_d/h^-1
VO _x /ZrO₂^［13］	550	φ（C₃H₈）∶φ（H₂）∶φ（N₂）=7∶36∶7	25	85	0.549
VO _x /Al₂O₃^［14］	600	φ（C₃H₈）∶φ（H₂）∶φ（N₂）=7∶7∶11	32	约94	0.245
Mo－V－O^［15］	550	φ（C₃H₈）∶φ（N₂）=19∶81	36	89
Ga₈Al₂O₁₅^［16］	500	φ（C₃H₈）∶φ（N₂）=1∶39	49.7	91.7	0.086
［Fe］ZSM-5（MFI）^［17］	530		约7.2	约78
Sn-HMS^［18］	600	φ（C₃H₈）∶φ（N₂）=5∶95	约40	约90
SnO₂/SiO₂^［19］	600	φ（C₃H₈）∶φ（N₂）=5∶95	约30	约85
Fe_Ⅱ/SiO₂^［9］	650	φ（C₃H₈）∶φ（Ar）=3∶97	4.9	>99
Co-Al₂O₃-HT^［20］	590	φ（C₃H₈）∶φ（H₂）∶φ（N₂）=1∶0.8∶3.2	23	约97	0.06
VO _x /meso-Al₂O₃^［21］	510	φ（C₃H₈）∶φ（N₂）=4∶1	70	约85	0.169
GaO _x /SiO₂^［22］	580	φ（C₃H₈）∶φ（N₂）=1∶10	65	约90	0.136
Co–Al₂O₃–IMP^［20］	590	φ（C₃H₈）∶φ（H₂）∶φ（N₂）=1：0.8：3.2	21.2	94.6	0.16
Co（II）/SiO₂^［23］	550	φ（C₃H₈）∶φ（Ar）=20∶80	710	72	0.07
Co/SiO₂^［24］	550	φ（C₃H₈）∶φ（He）=3∶97	3.5	92	0.008 5
0.5CoSiBeta^［25］	600	φ（C₃H₈）∶φ（N₂）=5∶95	19	98.2	0.04
Co-Zr/SiO₂^［24］	550	φ（C₃H₈）∶φ（He）=3∶97	8.7	96	0.011 5
ZnO/Beta^［26］	600	φ（C₃H₈）∶φ（N₂）=5∶95	52	约93	0.095

[1]	占思进, 刘仕轲, 刘飞, 姚梦琴, 曹建新. ZnO-CeO₂制备及催化性能研究[J]. 无机盐工业, 2024, 56(3): 137-143.
[2]	刘杰, 石雪茹, 魏树兵, 曹鑫鑫. P2型层状氧化物正极的人工界面层构筑及储钠性能[J]. 无机盐工业, 2024, 56(3): 39-44.
[3]	陈俊雪, 莫建欣, 周治宇, 李中林, 王丁, 李玉平, 胡拥军, 将学先, 李义兵. NaFe _x Cr _y （SO₄）₂（OH）₆的合成及电化学性能研究[J]. 无机盐工业, 2023, 55(8): 71-76.
[4]	王延苏, 刘国柱, 于海斌. 铂基丙烷脱氢催化剂研究进展[J]. 无机盐工业, 2023, 55(7): 1-9.
[5]	韩红静, 张竞择, 拉毛卓玛, 韩吉者, 吴勇民, 汤卫平. 铝钴共掺杂锂锰氧化物的制备及吸附提锂性能[J]. 无机盐工业, 2023, 55(7): 38-44.
[6]	田玉玲, 程阳, 韩融, 周梅, 王成杰, 葛强茹. 氧化钙对污泥炭重金属稳定性及其吸附性能的影响[J]. 无机盐工业, 2023, 55(6): 124-129.
[7]	罗志波, 王怀有, 王敏, 杜宝强. 纯度对60%NaNO₃-40%KNO₃二元熔盐热物性的影响[J]. 无机盐工业, 2023, 55(6): 43-49.
[8]	许春辉, 王峰, 凌长见, 王子睿, 唐忠锋. 熔盐改性的金属氧化物捕获二氧化碳研究进展[J]. 无机盐工业, 2023, 55(5): 1-7.
[9]	贾育红, 胡忠攀, 王坤院, 韩晶峰, 魏迎旭, 刘中民. S-1分子筛羟基窝锚定钴用于丙烷脱氢制丙烯[J]. 无机盐工业, 2023, 55(5): 121-127.
[10]	李海涛,赵银峰. 氮化SBA-15负载高分散过渡金属用于丙烷高效直接脱氢[J]. 无机盐工业, 2023, 55(2): 141-148.
[11]	胡月, 莫恒亮, 李天玉, 彭文娟, 孙广东, 肖宏康, 陈亦力, 李锁定, 唐阳. 钛系锂离子筛粉体与PVDF树脂纺丝成型及性能研究[J]. 无机盐工业, 2023, 55(11): 58-63.
[12]	冀颖, 张颖, 侯雪超, 朱晓峰, 姜润, 彭文娟, 孙广东, 吕龙. 钛系吸附剂在西藏碳酸盐型盐湖中的应用研究[J]. 无机盐工业, 2023, 55(11): 70-77.
[13]	彭晨熹, 刘军. 钠离子电池层状过渡金属氧化物正极材料的研究进展[J]. 无机盐工业, 2023, 55(10): 1-12.
[14]	杨庭龙,王富中,刘飞. 锆基双金属氧化物催化剂硫中毒的研究[J]. 无机盐工业, 2023, 55(1): 151-158.
[15]	韩红静,吴勇民,曹永生,韩婷婷,汤卫平. 纳米片多面体锰基锂离子筛的制备及锂离子吸脱附特性[J]. 无机盐工业, 2022, 54(8): 59-65.

首页

全国无机盐信息中心

中国化工学会

无机酸碱盐专业委员会