水淬渣-粉煤灰基4A沸石的制备及性能表征

doi:10.19964/j.issn.1006-4990.2021-0399

摘要/Abstract

摘要：

粉煤灰因其主要成分为二氧化硅、三氧化二铝常被用来当作合成沸石的原材料,合成的沸石类型主要有X型、Y型、A型、ZSM-5型等,相关合成技术也已非常成熟。水淬渣是高炉炼铁水淬急冷产生的高炉渣,对其主要利用方式是作为水泥、路基材料,均属低附加值利用。通过碱熔水热法利用水淬渣、粉煤灰混合原料合成4A型沸石。初步探究硅铝物质的量比（简称硅铝比）、熔融温度、熔融时间、晶化时间对制备的沸石样品品质造成的影响,得到最佳制备条件：硅铝比为1.0、碱灰质量比为1.5、碱熔时间为1 h、碱熔温度为600 ℃、老化时间为12 h、灰水质量比为1∶5、晶化温度为90 ℃、晶化时间为16 h。对合成的沸石进行X射线衍射（XRD）、X射线荧光光谱（XRF）、扫描电镜（SEM）、红外光谱（FT-IR）等表征,结果表明利用水淬渣、粉煤灰合成的4A型沸石各方面性能良好,具有超高的工业化生产价值。

关键词: 粉煤灰, 水淬渣, 4A沸石, 性能表征

Abstract:

Fly ash is often used as the raw material for synthetic zeolite because of its main components are SiO₂ and Al₂O₃.The main types of synthetic zeolite are X-type,Y-type,A-type,ZSM-5,etc.The related synthesis technology is also very mature.Water quenching slag is the blast furnace slag produced by quenching of blast furnace ironmaking water.Its main utilization method is as cement and roadbed materials,all of which are low value-added utilization.4A zeolite was synthesized by the alkali melting hydrothermal method using water quenching slag and fly ash mixed raw materials.The influence of silicon-toaluminum ratio,melting temperature,melting time,and crystallization time on the quality of the prepared zeolite samples was explored preliminarily,and the obtained best preparation conditions were：silicon-to-aluminum ratio of 1.0,alkali-to-ash ratio of 1.5,alkali melting time of 1 h,alkali melting temperature of 600 ℃,aging time of 12 h,gray-water ratio of 1∶5,crystallization temperature of 90 ℃,crystallization time of 16 h.The synthesized zeolite was characterized by XRD,XRF,SEM,FT-IR,etc.The results showed that the 4A zeolite synthesized by water quenching slag and fly ash had good performance in all aspects and had ultra-high industrial production value.

Key words: fly ash, water quenching slag, 4A zeolite, performance characterization

中图分类号:

O643.36

崔家新,王连勇,李尧,何艳,王睿,韩建丽. 水淬渣-粉煤灰基4A沸石的制备及性能表征[J]. 无机盐工业, 2022, 54(4): 135-140.

CUI Jiaxin,WANG Lianyong,LI Yao,HE Yan,WANG Rui,HAN Jianli. Preparation and properties characterization of water quenching slag-fly ash based 4A zeolite[J]. Inorganic Chemicals Industry, 2022, 54(4): 135-140.

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参考文献 15

[1]	TRIPATHY S K, DASU J, MURTHY Y, et al. Utilisation perspective on water quenched and air-cooled blast furnace slags[J]. Journal of Cleaner Production, 2020, 262.Doi: 10.1016/j.jclepro.2020.121354.
[2]	孙红燕, 孔馨, 张瑾勋, 等. 铅冶炼水淬渣球磨工艺研究[J]. 湿法冶金, 2019, 38(5):412-415.
[3]	李峰, 马国军, 张翔, 等. 微波强化冰乙酸浸出高炉渣中钙的行为[C]// 中国金属学会.第十一届中国钢铁年会论文集-S15.能源与环保, 2017.
[4]	罗雪梅, 唐朝培, 韦星华, 等. 水淬矿渣的综合利用[J]. 中国资源综合利用, 2006(4):18-21.
[5]	LUO Y, WU Y H, MA S H, et al. Utilization of coal fiy ash in China:A mini-review on challenges and future directions[J]. Environmental Science and Pollution Research, 2021, 15(18):18727-18740.
[6]	张祥成, 孟永彪. 浅析中国粉煤灰的综合利用现状[J]. 无机盐工业, 2020, 52(2):1-5.
[7]	冯文丽, 吕学斌, 熊健, 等. 粉煤灰高附加值利用研究进展[J]. 无机盐工业, 2021, 53(4):25-31.
[8]	ZHOU Q, TANG Y G. Utilization of coal ash in China[J]. Advanced Materials Research, 2013, 2115:2386-2390.
[9]	CHEN X J, GUO Y X, CHENG F Q, et al. Application of modified coal fly ash as an absorbent for ammonia-nitrogen wastewater treatment[J]. Advanced Materials Research, 2012, 1793:2380-2384.
[10]	WANG Z, FAN Y, LI Y W, et al. Synjournal of zeolite/hydrous lanthanum oxide composite from coal fly ash for efficient phosphate removal from lake water[J]. Microporous and Mesoporous Materials, 2016, 222:226-234.
[11]	MAHSHID A, SYED S B, HOSSEIN K, et al. A low-cost adsorbent from coal fly ash for mercury removal from industrial wastewater[J]. Journal of Environmental Chemical Engineering, 2017, 1(5):391-399.
[12]	GABRIELE V, LORENZO C, BENEDETTA D C, et al. Study of the parameters of zeolites synjournal from coal fly ash in order to optimize their CO₂ adsorption[J]. Fuel, 2020, 276.Doi: 10.1016/j.fuel.2020.118041.
[13]	RAJAKRISHNAMOORTHY P, KARTHIKEYAN D, SARAVANAN C G. Emission reduction technique applied in SI engines exhaust by using zsm5 zeolite as catalysts synthesized from coal fly ash[J]. Materials Today:Proceedings, 2020, 3(22):499-506.
[14]	李勃. 粉煤灰合成A型沸石处理制革废水试验研究[D]. 兰州:兰州大学, 2009.
[15]	廉先进, 葛宝勋, 李凯琦. 用煤矸石作原料合成A型沸石分子筛工艺条件的探讨[J]. 郑州大学学报:理学版, 1998(2):36-41.

项目	w （SiO₂）	w （Al₂O₃）	w （CaO）	w （Fe₂O₃）	w （C）	w （其他）
预处理前	61.88	19.56	6.28	3.69	2.64	5.95
预处理后	70.13	17.82	2.48	1.58	0.00	7.99

样品名称	w（SiO₂）	w（Al₂O₃）	w（Fe₂O₃）	w（CaO）	w（Na₂O）
商用沸石	55.29	36.26	1.31	2.22	1.97
自制沸石	53.19	35.56	2.98	3.98	2.06

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