含硝酸盐水盐体系降温过程研究

Abstract

Abstract: The study on the change of liquid composition and crystallization regularity has been carried out for the Na+∥Cl-，SO42-，NO3--H2O system with different concentration characteristics in natural cooling process，which was involved in development of nitrate mine in Xinjiang，China.Results showed that，as the temperature decreased，crystallization field of Na2SO4·10H2O expanded but ones of Na2SO4·NaNO3·H2O and Na2SO4 became small，and disappeared，and ones of NaCl and NaNO3 changed a little.Crystallization pathways of solution saturated with different salts were different in cooling process. For the brine saturated with NaCl，NaNO3，and Na2SO4·NaNO3·H2O，as the temperature decreased，three salts were always saturated and precipitated，however，the liquid composition was determined by the crystallization rate of three salts.

Key words: nitrate, low temperature, crystallization, phase diagram

CLC Number:

TQ126.25

ZHANG Xia, HUANG Xue-Li, HUANG Wen-Ting, REN Xiao-Jing. Study on cooling process of salt-water system with nitrate[J]. INORGANICCHEMICALSINDUSTRY, 2014, 46(4): 18-.

[1]	Cao Weiwen,Li Jun,Chen Ming,Yu Yinrong,Liao Xiaoting. Study on agglomeration process during crystallization of calcium hydrogen phosphate and its main affecting impurity thereof [J]. Inorganic Chemicals Industry, 2021, 53(1): 50-53.
[2]	Liu Juexin,Zheng Chenggang,Ye Shichao. Determination and application of thermodynamic data of potassium dihydrogen phosphate crystal [J]. Inorganic Chemicals Industry, 2021, 53(1): 62-64.
[3]	Gan Yonghai,Wu Bingdang,Li Haojie,Li Jingbiao,Li Runsheng,Zhang Shujuan. Preparation and application evaluation of a novel titanium coagulant [J]. Inorganic Chemicals Industry, 2020, 52(9): 1-5.
[4]	Ma Yuming. Synthesis and application of sodium carbonate solution crystallization inhibitor [J]. Inorganic Chemicals Industry, 2020, 52(8): 63-65.
[5]	Shi Xingxing,Hu Kaibao,Wang Zhanhe,Pan Jingzhong,Cui Jingui,Luo Ruiyin,Du Wei,Tang Na. Study on salt crystallization law of brine frozen mirabilite and frozen mirabilite mother liquor evaporation in Jilantai Salt Lake [J]. Inorganic Chemicals Industry, 2020, 52(6): 54-58.
[6]	Wang Yanxia,Cheng Wenting,Fang Li,Cheng Fangqin. Study on preparation and growth mechanism of MgCO₃·3H₂O whiskers [J]. Inorganic Chemicals Industry, 2020, 52(5): 22-26.
[7]	Wang Jukui,Dong Xingfeng,Zhao Dong,Wang Shiqiang,Guo Yafei,Deng Tianlong. Solid-liquid phase equilibria in quaternary system lithium borate-potassium borate-magnesium borate-water at 308.15 K [J]. Inorganic Chemicals Industry, 2020, 52(5): 27-30.
[8]	Su Lei,Zhang Haijun,Wang Jin,Yu Xuefeng,Dong Changji,Sun Ze,Song Xingfu,Yu Jianguo. Study on preparation of molten salt grade potassium nitrate by reactive extraction method [J]. Inorganic Chemicals Industry, 2020, 52(5): 35-39.
[9]	Wang Haohao,Da Tao,Ye Shichao. Experimental study on crystallization process of ammonium chloride [J]. Inorganic Chemicals Industry, 2020, 52(4): 49-52.
[10]	Liao Xiaoting,Li Jun,Chen Ming. Process study on preparation of industrial grade ammonium dihydrogen phosphate from urea phosphate mother liquor [J]. Inorganic Chemicals Industry, 2020, 52(4): 79-83.
[11]	Yin Haijiao,Xia Junjun,Quan Xiaoyu,Peng Tao,Tang Hao. Study on operation characteristics of mechanical flash cooling crystallization technology for titanium solution in summer [J]. Inorganic Chemicals Industry, 2020, 52(4): 93-95.
[12]	Han Tao,He Yanbin,Huang Shuaipeng. Instruction of production process and equipment for continuous freezing crystallization denitrification of lithium hydroxide [J]. Inorganic Chemicals Industry, 2020, 52(3): 98-100.
[13]	Chao Xiaoguang,Wang Hongbin,Cao Kun,Dai Yin,Song Litao,Zou Ping,Jia Min,Gao Guimei. Study on technology of recovering aluminum chloride from evaporation mother liquor in extraction of alumina from fly ash by hydrochloric acid method [J]. Inorganic Chemicals Industry, 2020, 52(12): 64-68.
[14]	Liu Yanrui,Song Congcong,Shi Guizhen,Wang Kun. The study of double oxalate lithium borate preparation technology by aqueous phase method [J]. Inorganic Chemicals Industry, 2020, 52(10): 100-105.
[15]	Xiong Xiaoyun,Wei Zhaocheng,Wang Jiujiang,Gao Xionghou,Zhao Hongjuan,Hu Qingxun. Effect of synthesizing conditions on NaY zeolite prepared by in-situ crystallization from kaolin microspheres [J]. Inorganic Chemicals Industry, 2020, 52(1): 99-102.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Study on cooling process of salt-water system with nitrate

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 10