碳酸钠溶液结晶抑制剂的制备与应用

doi:10.11962/1006-4990.2019-0482

Abstract

Abstract:

A sodium carbonate crystal inhibitor ELYZ-09 was synthesized with ethylenediamine,hydroxyacetonitrile and isopropanol as raw materials.The effects of temperature and stirring rate on the crystal inhibition were studied.The effect of inhibitor was best when the synthesis temperature was 70 ℃ and the stirring rate was 420 r/min. Applied experiment was made with crystalline inhibitor,when the dosage of sodium carbonate inhibitor ELYZ-09 not less than 0.12%,less crystals were precipitated when the 20%（mass fraction） sodium carbonate solution cooled to 10 ℃,inhibiting crystallization rate to 100 %,at the same time,solution pH and carbonate ions content did not change significantly.

Key words: sodium carbonate solution, crystallization, inhibitor

CLC Number:

TQ127.13

Ma Yuming. Synthesis and application of sodium carbonate solution crystallization inhibitor[J]. Inorganic Chemicals Industry, 2020, 52(8): 63-65.

抑制剂型号	质量分数/%	晶体析出质量/g	抑制析出率/%
空白	—	7.12	—
ELYZ-02	0.12	3.13	56.04
ELYZ-06	0.12	0.35	95.08
ELYZ-09	0.12	0.00	100.00
ELYZ-14	0.12	1.45	79.63
ELYZ-15	0.12	0.83	88.34

抑制剂型号	质量分数/%	晶体析出质量/g	抑制析出率/%	备注
空白	—	7.89	—	小颗粒白色晶体
ELYZ-09	0.09	1.87	76.30	大粒透明结晶
ELYZ-09	0.12	0.00	100.00	pH=11.82
ELYZ-09	0.15	0.00	100.00	pH=11.82
ELYZ-09	0.18	0.00	100.00	pH=11.84
ELYZ-09	0.21	0.00	100.00	pH=11.84

	温度/ ℃	pH	ρ（碳酸根）/ （mg·L^-1）	晶体析出程度	备注
未加抑制剂	30	11.95	128 475.95	无晶体析出	完全溶解
加抑制剂ELYZ-09	30	11.98	128 475.64	溶液澄清,无晶体析出
	25	11.90	128 577.32	溶液澄清,无晶体析出
	20	11.81	128 457.80	溶液澄清,无晶体析出
	15	11.80	128 464.34	溶液澄清,无晶体析出
	10	11.82	128 462.63	溶液澄清,无晶体析出

[1]	王继琼, 颜廷燕, 李梦然, 等. 工业碳酸钠的纯化技术概述[J]. 天津化工, 2018,32(1):196-198.
[2]	孙雨丽, 李珺, 石晨. 碳酸钠的制备与含量测定实验的改进[J]. 实验技术与管理, 2016,33(10):6-8.
[3]	王书平. 碳酸钠在高压溶出过程中的析出机理及应对措施[J]. 轻金属, 2012,(4):13-16.
[4]	陈洁, 陈侠. 制备碳酸锂结晶的工艺优化[J]. 无机盐工业, 2019,51(8):29-32.
[5]	李志强, 杨立斌, 沙作良, 等. 氯化钾间歇冷却结晶生长规律及粒度控制实验研究[J]. 无机盐工业, 2019,51(8):33-36.

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Inorganic Acid-Base-Salt Committee of CIESC

Synthesis and application of sodium carbonate solution crystallization inhibitor

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