羰基镍粉焙烧制备高纯度微米氧化亚镍粉体的研究

doi:10.19964/j.issn.1006-4990.2021-0392

Abstract

Abstract:

Nickel oxide was prepared from carbonyl nickel powder by roasting,and micron powders were obtained after ball milling.The thermogravimetry-differential scanning calorimeter（TG-DSC） was used to study the thermal behavior of carbonyl nickel powder in air atmosphere.Laser particle size analyzer,plasma spectrometer,X-ray diffraction analysis（XRD） and scanning electron microscopy（SEM） were used to analyze structure,composition and morphology of the prepared samples.The results showed that the effect of compressed air and compressed oxygen atmosphere on product purity was not obvious.Under the two carrier gas conditions,the carbonyl nickel powder could be directly roasted to prepare face-centered cubic nickel oxide with 100% purity and high crystallinity by optimizing the roasting temperature and roasting time（roasting temperature 700 ℃,roasting time 2 h,carrier gas flow 1.5 L/min）.After ball milling,spherical microns nickel oxide powder with particle size of 4~19 μm was obtained.The preparation process had the characteristics of simple technology and environmentally friendly.

Key words: carbonyl nicke, roasting method, nickel oxide powder

CLC Number:

TQ138.13

DING Yong,FENG Xiaorui,LU Xiangjie,GAO Xiaoqin,FENG Yan,HE Yan. Study on preparation of high purity micron nickel oxide powder by roasting carbonyl nickel powder[J]. Inorganic Chemicals Industry, 2022, 54(4): 119-122.

Figures/Tables 9

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References 13

[1]	LI G J, HUANG X X, GUO J K. Preparation and characteristics of nanocrystalline NiO by organic solvent method[J]. Materials Letters, 2001, 51(4):325-330. doi: 10.1016/S0167-577X(01)00312-3
[2]	何焕华, 蔡乔方. 中国镍钴冶金[M].2版. 北京: 冶金工业出版社, 2009:641-642.
[3]	SATHISHA D, NAIK K G. Synjournal and characterization of nickel oxide nanostructures by hydrothermal method[J]. Advanced Science Letters, 2018, 24(8):5691-5694. doi: 10.1166/asl.2018.12178
[4]	PRADEEP K V, MATHWE S, ANAND V R, et al. Defect level dependent visible emission of nickel oxide nanoparticles through controlled calcination temperature[J]. Optik, 2021, 231.Doi: 10.1016/j.ijleo.2021.166388. doi: 10.1016/j.ijleo.2021.166388
[5]	GUPTA P, MAURYA S, PANDEY N K, et al. Structural,electrical and humidity sensing properties of nano-structured nickel oxide prepared by sol-gel method[J]. Journal of Materials Science:Materials in Electronics, 2021, 32(3):3529-3542. doi: 10.1007/s10854-020-05099-4
[6]	SUNANDA K K, KARAN S, BHASKAR B. Electrodeposited MnO₂NiO composites as a Pt free counter electrode for dye-sensitized solar cells[J]. Journal of Electronic Materials, 2020, 49(3):2197-2202. doi: 10.1007/s11664-019-07925-w
[7]	KUMAR P R, PRASAD N, VEILLON F, et al. Raman spectroscopic and magnetic properties of europium doped nickel oxide nanoparticles prepared by microwave-assisted hydrothermal method[J]. Journal of Alloys and Compounds, 2021, 858.Doi: 10.1016/j.jallcom.2020.157639. doi: 10.1016/j.jallcom.2020.157639
[8]	汪芳, 黄寅生, 赵宇. 固相法合成纳米MgO和NiO的实验探究[J]. 材料导报, 2013, 27(1):17-20.
[9]	张新涛, 张科翠, 张娟, 等. 喷雾热解氧化亚镍制备微细镍粉工艺研究[J]. 有色金属:冶炼部分, 2019(3):64-67.
[10]	郭秋松, 郭学益, 田庆华. 溶液雾化焙烧法制备氧化亚镍超细粉体[J]. 材料科学与工艺, 2011, 19(2):47-51.
[11]	NOBUYUKI G, SHOHEI N, TSUYOSHI H, et al. Steam reforming of methane using double-walled reformer tubes containing hightemperature thermal storage Na₂CO₃/MgO composites for solar fuel production[J]. Energy, 2014, 68(4):773-782. doi: 10.1016/j.energy.2014.01.107
[12]	张荣良, 嵇立磊, 居殿春, 等. 碱式碳酸镍热解法制备氧化亚镍粉末的研究[J]. 无机盐工业, 2018, 50(5):33-35,39.
[13]	郭学益, 黄凯, 张多默, 等. 尿素均相沉淀法制备均分散氧化亚镍粉末(Ⅱ)——前驱体的热分解研究[J]. 中南工业大学学报, 1999, 30(4):378-381.

颗粒粒径/μm			w（Ni）/ %	w（Co）/ %	w（Cu）/ %
D₁₀	D₅₀	D₉₀	w（Ni）/ %	w（Co）/ %	w（Cu）/ %
3.79	10.2	28.3	97.66	0.008	<0.002
w（Fe）/ %	w（Zn）/ %	w（Ca+Mg+ Na）/%	w（Cd）/ %	w（S）/ %	w（盐酸不溶物）/%
0.082	<0.001	<0.012	0.008	0.011	3.37

牌号	颗粒粒径/μm			w（Ni）/ %	w（Co）/ %	w（Cu）/ %	w（Fe）/ %	w（Zn）/ %	w（Ca+Mg+ Na）/%	w（Cd）/ %	w（S）/ %	w（盐酸不溶物）/%
牌号	D₁₀	D₅₀	D₉₀	w（Ni）/ %	w（Co）/ %	w（Cu）/ %	w（Fe）/ %	w（Zn）/ %	w（Ca+Mg+ Na）/%	w（Cd）/ %	w（S）/ %	w（盐酸不溶物）/%
空气气氛中焙烧后实测值	3.53	9.18	16.8	78.56	0.014	<0.000 1	0.007	0.000 4	0.015 2	<0.000 1	0.008	0.003
氧气气氛中焙烧后实测值	3.51	9.63	18.7	78.14	0.0099	<0.000 1	0.038	<0.000 1	0.007 5	<0.000 1	<0.000 1	0.005
YS/T 277—2016标准中NiO770指标	<150			≥77.0	≤0.05	≤0.01	≤0.05	≤0.005	≤0.5	≤0.000 5	≤0.01	≤0.10

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Study on preparation of high purity micron nickel oxide powder by roasting carbonyl nickel powder

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