高镍三元正极材料镍钴铝的掺杂改性研究进展

doi:10.19964/j.issn.1006-4990.2021-0533

Abstract

Abstract:

Due to the high energy density，high working voltage，low cost and environmental friendliness，high nickel ternary nickel-cobalt-aluminum（NCA） cathode material is likely to become one of the next generation widely used cathode materials for lithium ion batteries.However，increasing of nickel content，resulting in more unstable material structure，reduced cycle performance，and rate capability，limits its further development.The modification mechanism of ion doping at different positions from four aspects: lithium site，transition metal site，oxygen site doping and composite co-doping were summarized.A large number of research results showed that modification by composite co-doping could effectively improve the electrochemical performance of nickel-cobalt-aluminum cathode materials by combining the advantages of single ion doping.

Key words: NCA cathode material, ion doping modification, capacity decay mechanism, electrochemical performance

CLC Number:

TQ138.13

HOU Shunli,ZHAO Duan,ZHOU Geng,WEI Shishi,LI Jian,WANG Jiatai. Research progress on doping modification of high nickel ternary nickel-cobalt-aluminum cathode material[J]. Inorganic Chemicals Industry, 2022, 54(8): 40-46.

Figures/Tables 7

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掺杂分类	取代位置	掺杂离子	化合价	离子半径/nm	放电速率	循环次数	容量保持率/%
单离子掺杂	Li位	Na^+［16］	+1	0.102	1.0C	200	90.71
	Li位	K^+［17］	+1	0.138	1.0C	150	87.4
	M位	Ti^4+［20］	+4	0.060 5	0.1C	100	86.9
	M位	Mg^2+［21］	+3	0.072	0.5C	100	84.9
	O位	Br^-［28］	-1	0.196	0.5C	100	73.7
	O位	S^2-［30］	-2	0.184	1.0C	1 100	70.4
复合共掺杂	Li位 O位	Na^+［33］ Nb^5+［33］	+1 +5	0.102 0.069	0.5C	100	94.3
复合共掺杂	Li位 O位	Na^+［34］ Br^-［34］	+1 -1	0.102 0.196	2.0C	100	91.5

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Research progress on doping modification of high nickel ternary nickel-cobalt-aluminum cathode material

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