CuAl2O4和CuAl2O4：Cr荧光粉的合成及发光机理研究

doi:10.19964/j.issn.1006-4990.2021-0162

Abstract

Abstract:

CuAl₂O₄ and CuAl₂O₄：Cr phosphors were prepared by a mild sol-gel method with tartaric acid as chelating agent.The X-ray powder diffraction results showed that the CuAl₂O₄ xerogel sintered at 800 ℃ exhibited a pure cubic CuAl₂O₄ phase with high crystallinity,CuAl₂O₄：Cr phosphor after sintering of xerogels was a mixed phase of CuAl₂O₄ and Cr₂O₃.The analysis of elemental composition and charge state showed that the CuAl₂O₄ and CuAl₂O₄：Cr phosphors did not contain other impurity elements,and there was a small amount of adsorbed oxygen in the two samples.Scanning electron microscope analysis showed that the particles of CuAl₂O₄ and CuAl₂O₄：Cr phosphors were approximately spherical,and each large particle was composed of many fine grains.The agglomeration phenomenon among CuAl₂O₄：Cr phosphor particles was obvious than that of CuAl₂O₄.The optical properties analysis found that the agglomeration of CuAl₂O₄：Cr phosphor particles resulted in a smaller optical band gap than that of CuAl₂O₄.CuAl₂O₄：Cr phosphor stimulated at 255 nm,and a strong fluorescence emission peak was obtained at 690 nm,which was mainly attributed to the transition between²E_g and⁴A_2g in Cr³⁺.

Key words: sol-gel method, chelating agent, CuAl₂O₄, phosphor

CLC Number:

TQ131.21

BAN Liping,MA Min. Study on synthesis and photoluminescence mechanism of CuAl₂O₄ and CuAl₂O₄：Cr phosphors[J]. Inorganic Chemicals Industry, 2022, 54(1): 56-61.

Figures/Tables 9

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References 14

[1]	赵文卿, 关荣锋, 王杏. 稀土荧光粉的制备技术研究与展望[J]. 无机盐工业, 2008, 40(10):8-11.
[2]	杨晓红. MgAl₂O₄:Ce荧光粉辐照合成及发光机理研究[J]. 无机盐工业, 2019, 51(9):30-35.
[3]	RYU H, BARTWAL K S. Investigations on luminescence character-istics of Eu and Cr codoped BaAl₂O₄[J]. Materials Chemistry and Physics, 2008, 111:186-189. doi: 10.1016/j.matchemphys.2008.04.007
[4]	葛东来, 范迎菊, 尹龙, 等. 连续在线原位ATR-FTIR技术测定介孔CuAl₂O₄对黄药的吸附[J]. 物理化学学报, 2013(2):149-154.
[5]	LV W, LIU B, QIU Q, et al. Synjournal,characterization and photoca-talytic properties of spinel CuAl₂O₄ nanoparticles by a sonochemical method[J]. Journal of Alloys and Compounds, 2009, 479:480-483. doi: 10.1016/j.jallcom.2008.12.111
[6]	TANGCHAROEN T, THIENPRASERT J T, KONGMARK C. Effect of calcination temperature on structural and optical properties of MAl₂O₄ (M=Ni,Cu,Zn)aluminate spinel nanoparticles[J]. Advan-ced Ceramics, 2019, 3:352-366.
[7]	HA L H, LANH P T, LONG N N, et al. Some physical properties of ZnAl₂O₄:Cr³⁺(Co²⁺) powders prepared by hydrothermal method[J]. Journal of Physics:Conference Series, 2009, 187.Doi: 10.1088/1742-6596/187/1/012053. doi: 10.1088/1742-6596/187/1/012053
[8]	MENON S G, HEBBAR D N, KULKARNI S D, et al. Facile synthe-sis and luminescence studies of nanocrystalline red emitting Cr:ZnAl₂O₄ phosphor[J]. Materials Research Bulletin, 2017, 86:63-71. doi: 10.1016/j.materresbull.2016.10.009
[9]	朱金剑, 张景成, 南军, 等. EDTA/CA对加氢处理催化剂性能的影响[J]. 无机盐工业, 2019, 51(7):85-88.
[10]	TENG Y, ZHOU J, KHISRO S N, et al. Persistent luminescence of SrAl₂O₄:Eu²⁺,Dy³⁺,Cr³⁺ phosphors in the tissue transparency win-dow[J]. Materials Chemistry and Physics, 2014, 147:772-776. doi: 10.1016/j.matchemphys.2014.06.018
[11]	PONMUDI S, SIVAKUMAR R, SANJEEVIRAJA C, et al. Facile fabrication of spinel structured n-type CuAl₂O₄ thin film with nano-grass like morphology by sputtering technique[J]. Applied Surfa-ce Science, 2019, 483:601-615.
[12]	KOCHUR A G, KOZAKOV A T, GOOGLEV K A, et al. Valence state of transition metal ions in Co₁-_xFe_xCr₂O₄(x=0.1,0.2,0.5) ce-ramics from X-ray photoelectron and Mössbauer spectroscopy data[J]. Journal of Alloys and Compounds, 2015, 636:241-248. doi: 10.1016/j.jallcom.2015.02.150
[13]	周元, 刘素芹, 梁英. 稳定的高可见光活性Ag₃PO₄/WO₃复合光催化剂[J]. 应用化学, 2013, 30(6):673-676.
[14]	LOU F H, BALLEXTYNE D W G. Visible and ultra-violet emission and absorption spectra of MgAl₂O₄:Cr[J]. Journal of Physics C:So-lid State Physics, 1968, 2(1):608-613.

2θ/（°）	FWHM/rad	d/nm	（hkl）	D/nm
31.470	0.669	0.284 04	（220）	12.20
37.051	0.695	0.242 43	（311）	11.92
45.155	0.498	0.200 63	（400）	17.08
55.903	0.332	0.164 34	（422）	26.79
59.747	0.620	0.154 65	（511）	14.61
65.879	0.727	0.141 66	（440）	12.88

2θ/（°）	FWHM/rad	d/nm	（hkl）	D/nm
31.022	0.648	0.285 69	（220）	12.58
36.685	0.663	0.244 77	（311）	12.48
45.041	0.492	0.201 11	（400）	17.29
55.569	0.316	0.165 46	（422）	28.10
59.363	0.643	0.155 56	（511）	14.06
65.531	0.723	0.144 23	（440）	12.92

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Study on synthesis and photoluminescence mechanism of CuAl₂O₄ and CuAl₂O₄：Cr phosphors

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Study on synthesis and photoluminescence mechanism of CuAl2O4 and CuAl2O4：Cr phosphors