镍基磷化物复合材料在催化电解水析氢性能提升方面的研究进展

doi:10.19964/j.issn.1006-4990.2023-0399

Abstract

Abstract:

Nickel-based phosphorus compounds have been shown to have good hydrogen evolution ability in electrolytic water because of their hydrogen-like electronic structure and excellent stability.Because its intrinsic activity is insufficient，the conductivity is not high and the stability is poor，so practical application of monometallic phosphide is limited.The preparation methods of nickel-based phosphide composites with novel structure，excellent performance and high stability were reviewed.The research results of regulating the electronic structure and microstructure of electrode materials，promoting long-term electrolytic stability，increasing specific surface area and improving electrical conductivity through heteroatom doping，morphology regulation，combination of self-supporting materials and new composite materials（carbon nanotubes，graphene，graphyne，MXene） were summarized and analyzed.It provided the research direction for exploring new nickel-based phosphide composite materials with high catalytic activity and stable structure.

Key words: electrocatalysis, hydrogen evolution performance, nickel-phosphorus compounds, composite materials, non-precious metal

CLC Number:

O643.3

ZHOU Xuan, LI Mengrui, CHEN Yichen, FAN Huiqiang, WANG Bin, YUAN Gang. Research progress of nickel-based phosphide composites in improving of catalytic water electrolysis for hydrogen evolution performance[J]. Inorganic Chemicals Industry, 2024, 56(4): 8-15.

References 53

1	LIU Ping， RODRIGUEZ J A. Catalysts for hydrogen evolution from the［NiFe］hydrogenase to the Ni2P（001） surface：The importance of ensemble effect［J］. Journal of the American Chemical Society， 2005， 127（42）：14871-14878. pmid: 16231942
2	POPCZUN E J， MCKONE J R， READ C G， et al. Nanostructured nickel phosphide as an electrocatalyst for the hydrogen evolution reaction［J］. Journal of the American Chemical Society， 2013， 135（25）：9267-9270. doi: 10.1021/ja403440e pmid: 23763295
3	JAKŠIĆ M M. Advances in electrocatalysis for hydrogen evolution in the light of the Brewer-Engel valence-bond theory［J］. Journal of Molecular Catalysis， 1986， 38（1/2）：161-202. doi: 10.1016/0304-5102(86)87056-0
4	马洁，刘顺诚，江琳才，等. 纳米晶Ni-Mo合金复合镀层中钼含量对析氢反应的影响［J］. 化学学报， 1997， 55（4）：363-369.
	MA Jie， LIU Shuncheng， JIANG Lincai， et al. Effects of molybdenum content of nanocrystalline Ni-Mo alloy composite coating on hydrogen evolution reaction［J］. Acta Chimica Sinica， 1997， 55（4）：363-369.
5	TRASATTI S. Work function，electronegativity，and electrochemical behaviour of metals［J］. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry， 1972， 39（1）：163-184. doi: 10.1016/S0022-0728(72)80485-6
6	LI Yang， DONG Zihao， JIAO Lifang. Multifunctional transition metal-based phosphides in energy-related electrocatalysis［J］. Advanced Energy Materials， 2020， 10（11）：1902104. doi: 10.1002/aenm.v10.11
7	ZHANG Bing， YANG Fan， LIU Xiaodong， et al. Phosphorus doped nickel-molybdenum aerogel for efficient overall water splitting［J］. Applied Catalysis B：Environmental， 2021， 298：120494.
8	戴凌杰. 多组分过渡金属磷化物复合材料的制备及其水分解性能研究［D］. 长春：吉林大学， 2022.
	DAI Lingjie. Preparation of multicomponent transition metal phosphate composite and study on its hydrolysis performance［D］. Changchun： Jilin University， 2022.
9	GUO Baoyu， WANG Yiwei， DONG Bin. Controllable leaching of Ag₂WO₄ template for production of Ni-Co-P nanosheets as electrocatalyst for hydrogen evolution［J］. International Journal of Electrochemical Science， 2022， 17（9）：22091. doi: 10.20964/2022.09.03
10	WU Konglin， SUN Kaian， LIU Shoujie， et al. Atomically dispersed Ni-Ru-P interface sites for high-efficiency pH-universal electrocatalysis of hydrogen evolution［J］. Nano Energy， 2021， 80：105467. doi: 10.1016/j.nanoen.2020.105467
11	WANG Yue， CHEN Zhi， LI Qichang， et al. Porous needle-like Fe-Ni-P doped with Ru as efficient electrocatalyst for hydrogen generation powered by sustainable energies［J］. Nano Research， 2023， 16（2）：2428-2435. doi: 10.1007/s12274-022-4980-4
12	瞿国兴. 非金属元素掺杂型电催化剂的制备及其催化电解水性能研究［D］. 成都：电子科技大学， 2020.
	QU Guoxing. The study of nonmetal-doped electrocatalyst synthesis and their performances in catalyzing water electrolysis［D］. Chengdu： University of Electronic Science and Technology of China， 2020.
13	ZHANG Xiangrui， SHI Xuerong， WANG Peijie， et al. Bio-inspired design of NiFeP nanoparticles embedded in（N，P） co-doped carbon for boosting overall water splitting［J］. Dalton Transactions， 2023， 52（20）：6860-6869. doi: 10.1039/D3DT00583F
14	SONG D， HONG D， KWON Y， et al. Highly porous Ni-P electrode synthesized by an ultrafast electrodeposition process for efficient overall water electrolysis［J］. Journal of Materials Chemistry A， 2020， 8（24）：12069-12079. doi: 10.1039/D0TA03739G
15	WANG Yuan， ARANDIYAN H， CHEN Xianjue， et al. Microwave-induced plasma synthesis of defect-rich，highly ordered porous phosphorus-doped cobalt oxides for overall water electrolysis［J］. The Journal of Physical Chemistry C， 2020， 124（18）：9971-9978. doi: 10.1021/acs.jpcc.0c01135
16	KHALID M， BHARDWAJ P A， HONORATO A M B， et al. Metallic single-atoms confined in carbon nanomaterials for the electrocatalysis of oxygen reduction，oxygen evolution，and hydrogen evolution reactions［J］. Catalysis Science & Technology， 2020， 10（19）：6420-6448.
17	NIU Shanshan， YANG Ji， QI Haifeng， et al. Single-atom Pt promoted Mo₂C for electrochemical hydrogen evolution reaction［J］. Journal of Energy Chemistry， 2021， 57：371-377. doi: 10.1016/j.jechem.2020.08.028
18	段钱花，王森林，王丽品. 电沉积多孔复合Ni-P/LaNi₅电极及其析氢电催化性能［J］. 物理化学学报， 2013， 29（1）：123- 130.
	DUAN Qianhua， WANG Senlin， WANG Lipin. Electro-deposition of the porous composite Ni-P/LaNi₅ electrode and its electro-catalytic performance toward hydrogen evolution reaction［J］. Acta Physico-Chimica Sinica， 2013， 29（1）：123-130. doi: 10.3866/PKU.WHXB201210095
19	TIAN Gaoqi， WEI Songrui， GUO Zhangtao， et al. Hierarchical NiMoP₂-Ni₂P with amorphous interface as superior bifunctional electrocatalysts for overall water splitting［J］. Journal of Materials Science & Technology， 2021， 77：108-116.
20	ZHAO Hongwu， LIANG Jicai， ZHENG Qifeng. Construction of core-shell heterostructure NiO@Co_0.5Fe_0.5P as efficient bifunctional electrocatalysts for overall water splitting［J］. Journal of Alloys and Compounds， 2022， 905：164264. doi: 10.1016/j.jallcom.2022.164264
21	SUN Hongming， YAN Zhenhua， LIU Fangming， et al. Self-supported transition-metal-based electrocatalysts for hydrogen and oxygen evolution［J］. Advanced Materials， 2020， 32（3）： e1806326.
22	MA Xingxing， CHANG Yaqing， ZHANG Zhe， et al. Forest-like NiCoP@Cu₃P supported on copper foam as a bifunctional catalyst for efficient water splitting［J］. Journal of Materials Chemistry A， 2018， 6（5）：2100-2106. doi: 10.1039/C7TA09619D
23	DING Yu， MIAO Boqiang， LI Shuni， et al. Benzylamine oxidation boosted electrochemical water-splitting：Hydrogen and benzonitrile co-production at ultra-thin Ni₂P nanomeshes grown on nickel foam［J］. Applied Catalysis B：Environmental， 2020， 268：118393.
24	ZENG Min， LI Yanguang. Recent advances in heterogeneous electrocatalysts for the hydrogen evolution reaction［J］. Journal of Materials Chemistry A， 2015， 3（29）：14942-14962. doi: 10.1039/C5TA02974K
25	孙善善. 电沉积法制备镍磷化物多孔电极及其析氢性能研究［D］. 镇江：江苏大学， 2020.
	SUN Shanshan. Preparation of nickel phosphide porous electrode by electrodeposition and its hydrogen evolution performance［D］. Zhenjiang： Jiangsu University， 2020.
26	XIANG Zhongcheng， ZHANG Zhong， XU Xijin， et al. MoS₂ nanosheets array on carbon cloth as a 3D electrode for highly efficient electrochemical hydrogen evolution［J］. Carbon， 2016， 98：84-89. doi: 10.1016/j.carbon.2015.10.071
27	LI Jiachen， ZHANG Chi， MA Huijun， et al. Modulating interfacial charge distribution of single atoms confined in molybdenum phosphosulfide heterostructures for high efficiency hydrogen evoluti-on［J］. Chemical Engineering Journal， 2021， 414：128834. doi: 10.1016/j.cej.2021.128834
28	葛晨娇，崔伟，田坚. 生长在碳布上的磷化镍纳米颗粒膜的制备及其电催化析氢反应性能［C］// 中国新材料技术协会. 第三届国防装备轻质高强新材料应用研讨会， 2015.
29	YANG Fan， YANG Shuqin， NIU Qianqian， et al. Fabrication of a 3D self-supporting Ni-P/Ni₂P/CC composite and its robust hydrogen evolution reaction properties in alkaline solution［J］. New Journal of Chemistry， 2020， 44（20）：8183-8190. doi: 10.1039/D0NJ00727G
30	CHEN Xiaogang， ZHAO Xuan， WANG Yuanyuan， et al. Layered Ni-Co-P electrode synthesized by CV electrodeposition for hydrogen evolution at large currents［J］. ChemCatChem， 2021， 13（16）：3619-3627. doi: 10.1002/cctc.v13.16
31	LU Bowen， WANG Yanhui， LI Wei， et al. Ni-P alloy@carbon nanotubes immobilized on the framework of Ni foam as a 3D hierarchical porous self-supporting electrode for hydrogen evolution reaction［J］. International Journal of Hydrogen Energy， 2021， 46（45）：23245-23253. doi: 10.1016/j.ijhydene.2021.04.139
32	NOVOSELOV K S， GEIM A K， MOROZOV S V， et al. Electric field effect in atomically thin carbon films［J］. Science， 2004， 306（5696）：666-669. doi: 10.1126/science.1102896 pmid: 15499015
33	GEIM A K， NOVOSELOV K S. The rise of graphene［J］. Nature Materials， 2007， 6（3）：183-191. doi: 10.1038/nmat1849 pmid: 17330084
34	BALANDIN A A， GHOSH S， BAO Wenzhong， et al. Superior thermal conductivity of single-layer graphene［J］. Nano Letters， 2008， 8（3）：902-907. doi: 10.1021/nl0731872 pmid: 18284217
35	QIU Bocheng， ZHOU Yi， MA Yunfei， et al. Facile synthesis of the Ti³⁺ self-doped TiO₂-graphene nanosheet composites with enhanced photocatalysis［J］. Scientific Reports， 2015， 5：8591. doi: 10.1038/srep08591 pmid: 25716132
36	ZOU Haiyuan， LI Ge， DUAN Lele， et al. In situ coupled amorphous cobalt nitride with nitrogen-doped graphene aerogel as a trifunctional electrocatalyst towards Zn-air battery deriven full water splitting［J］. Applied Catalysis B：Environmental， 2019， 259：118100.
37	DING Guosheng， ZHANG Yixin， DONG Jing， et al. Fabrication of Ni₂P/Ni₅P₄ nanoparticles embedded in three-dimensional N-doped graphene for acidic hydrogen evolution reaction［J］. Materials Letters， 2021， 299：130071. doi: 10.1016/j.matlet.2021.130071
38	HUANG Changshui， LI Yongjun， WANG Ning， et al. Progress in research into 2D graphdiyne-based materials［J］. Chemical Reviews， 2018， 118（16）：7744-7803. doi: 10.1021/acs.chemrev.8b00288 pmid: 30048120
39	YIN Xuepeng， LU D， WANG Jiawei， et al. 2D/2D heterojunction of Ni-Co-P/graphdiyne for optimized electrocatalytic overall water splitting［J］. ChemCatChem， 2019， 11（22）：5407-5411. doi: 10.1002/cctc.201901173
40	GAO Juan， LI Yaxin， YU Xin， et al. Graphdiyne reinforced multifunctional Cu/Ni bimetallic Phosphides-Graphdiyne hybrid nanostructure as high performance electrocatalyst for water splitting［J］. Journal of Colloid and Interface Science， 2022， 628：508-518. doi: 10.1016/j.jcis.2022.07.150 pmid: 35933868
41	XU Xiaodan， ZHANG Yelong， SUN Hongyang， et al. Progress and perspective：MXene and MXene-based nanomaterials for high-performance energy storage devices［J］. Advanced Electronic Materials， 2021， 7（7）：1-16.
42	Luna TIE， LI Neng， YU Chongfei， et al. Self-supported nonprecious MXene/Ni₃S₂ electrocatalysts for efficient hydrogen generation in alkaline media［J］. ACS Applied Energy Materials， 2019， 2（9）：6931-6938. doi: 10.1021/acsaem.9b01529
43	KUZNETSOV D A， CHEN Zixuan， KUMAR P V， et al. Single site cobalt substitution in 2D molybdenum carbide（MXene） enhances catalytic activity in the hydrogen evolution reaction［J］. Journal of the American Chemical Society， 2019， 141（44）：17809-17816. doi: 10.1021/jacs.9b08897
44	LEE S， KIM E H， YU S， et al. Polymer-laminated Ti₃C₂T _X MXene electrodes for transparent and flexible field-driven electronics［J］. Journal of the American Chemical Society， 2021， 15（5）：8940-8952.
45	KELLY T G， CHEN J G. Metal overlayer on metal carbide substrate：Unique bimetallic properties for catalysis and electrocatalysis［J］. Chemical Society Reviews， 2012， 41（24）：8021-8034. doi: 10.1039/c2cs35165j
46	WU Yuting， NIE Ping， WANG Jiang， et al. Few-layer MXenes delaminated via high-energy mechanical milling for enhanced sodium-ion batteries performance［J］. ACS Applied Materials & Interfaces， 2017， 9（45）：39610-39617.
47	LUKATSKAYA M R， KOTA S， LIN Zifeng， et al. Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides［J］. Nature Energy， 2017， 2（8）：17105. doi: 10.1038/nenergy.2017.105
48	GHIDIU M， LUKATSKAYA M R， ZHAO Mengqiang， et al. Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance［J］. Nature， 2014， 516（7529）：78-81. doi: 10.1038/nature13970
49	WANG Pengyan， PU Zonghua， LI Wenqiang， et al. Coupling NiSe₂-Ni₂P heterostructure nanowrinkles for highly efficient overall water splitting［J］. Journal of Catalysis， 2019， 377：600- 608. doi: 10.1016/j.jcat.2019.08.005
50	PU Zonghua， LIU Tingting， AMIINU I S， et al. Transition-metal phosphides：Activity origin，energy-related electrocatalysis applications，and synthetic strategies［J］. Advanced Functional Materials， 2020， 30（45）：2004009. doi: 10.1002/adfm.v30.45
51	LUO Xu， JI Pengxia， WANG Pengyan， et al. Interface engineering of hierarchical branched Mo-doped Ni₃S₂/Ni _x P _y hollow heterostructure nanorods for efficient overall water splitting［J］. Advanced Energy Materials， 2020， 10（17）：1903891. doi: 10.1002/aenm.v10.17
52	JI Pengxia， JIN Huihui， XIA Hongliang， et al. Double metal diphosphide pair nanocages coupled with P-doped carbon for accelerated oxygen and hydrogen evolution kinetics［J］. ACS Applied Materials & Interfaces， 2020， 12（1）：727-733.
53	LV Zepeng， WANG Meng， LIU Dong， et al. Synergetic effect of Ni₂P and MXene enhances catalytic activity in the hydrogen evolution reaction［J］. Inorganic Chemistry， 2021， 60（3）：1604-1611. doi: 10.1021/acs.inorgchem.0c03072 pmid: 33428387

[1]	LUO Chengling, FAN Xiaofan. Research progress of microstructure-regulated catalysts for urea oxidation reactions [J]. Inorganic Chemicals Industry, 2025, 57(2): 26-35.
[2]	ZHANG Feigang, LIU Zhongli. Study on application of CuO/g-C₃N₄ composites in organic dye degradation and supercapacitors [J]. Inorganic Chemicals Industry, 2025, 57(1): 129-136.
[3]	XIE Jiang, GUO Ge, QIU Jie. Treatment of methylene blue simulated wastewater by supported activated carbon particle with three-dimensional electrode method [J]. Inorganic Chemicals Industry, 2024, 56(5): 78-86.
[4]	CHEN Xingliang, FAN Wenjuan, CHANG Hui, HUANG Haiping, JIANG Zhiqiang. Study on collaborative strategy between Fe³⁺ and Ni-based metal-organic frameworks for boosting electrocatalytic oxygen evolution [J]. Inorganic Chemicals Industry, 2024, 56(2): 152-158.
[5]	CHEN Junxue, MO Jianxin, ZHOU Zhiyu, LI Zhonglin, WANG Ding, LI Yuping, HU Yongjun, JIANG Xuexian, LI Yibing. Study on synthesis of NaFe _x Cr _y （SO₄）₂（OH）₆ and their electrochemical properties [J]. Inorganic Chemicals Industry, 2023, 55(8): 71-76.
[6]	LAN Yinghua, CHEN Yanmei, MA Ruixiao, ZHANG Yanhui. Preparation and photocatalytic performance of Ce-Ti oxide-attapulgite composites [J]. Inorganic Chemicals Industry, 2023, 55(4): 133-140.
[7]	WU Luming, YU Haibin, WANG Yaquan. Study on preparation of porous carbon materials and oxygen reduction properties of their metal phosphide [J]. Inorganic Chemicals Industry, 2023, 55(4): 104-110.
[8]	WANG Yansu, LIU Guozhu, YU Haibin. Research progress of non-precious metal catalysts for propane dehydrogenation [J]. Inorganic Chemicals Industry, 2023, 55(12): 1-11.
[9]	WANG Dian,SU Qiong,PANG Shaofeng,CAO Shijun,KANG Lihui,LIANG Lichun,WANG Yanbin,LI Zhaoxia. Study on high-performance supercapacitors based on Fe₂O₃/biomass carbon composites [J]. Inorganic Chemicals Industry, 2022, 54(3): 59-65.
[10]	ZHENG Yangzi,JIN Mingshang. Strategy to improve catalytic performance of Pt-based core-shell catalysts for fuel cells [J]. Inorganic Chemicals Industry, 2022, 54(11): 1-7.
[11]	WANG Wei,LIU Wei,WU Yang,YANG Shenshen. Research progress on molybdenum disulfide-based anode materials for lithium-ion batteries [J]. Inorganic Chemicals Industry, 2022, 54(10): 87-95.
[12]	Jiang Yuncai,Li Xuemei,Wu Zhaoxian,Cao Changdie,Mei Yi,Lian Peichao. Research progress on preparation and application in energy storage of black phosphorus [J]. Inorganic Chemicals Industry, 2021, 53(6): 59-71.
[13]	Yang Huanhuan,Yu Binlu,Wang Jiahong,Yu Xuefeng. Preparation,surface functionalization and photoelectrocatalysis of two-dimensional black phosphorus [J]. Inorganic Chemicals Industry, 2021, 53(5): 13-20.
[14]	CHEN Jingjuan,LÜ Lin,WAN Houzhao,WANG Hao. Recent progress on Cu-based chalcogenides for electrocatalytic carbon dioxide reduction to formate [J]. Inorganic Chemicals Industry, 2021, 53(12): 14-20.
[15]	Ma Ruixiao,Xu Juan,Zhang Yanhui. Application status of attapulgite-based composite materials in field of catalysis [J]. Inorganic Chemicals Industry, 2021, 53(10): 22-27.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Research progress of nickel-based phosphide composites in improving of catalytic water electrolysis for hydrogen evolution performance

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References 53

Related Articles 15

Metrics

Comments

Recommended 0