非晶态镍-硼合金柱撑膨润土催化剂的制备及其加氢性能的研究

doi:10.19964/j.issn.1006-4990.2021-0025

Abstract

Abstract:

Amorphous Ni-B alloy pillared bentonite catalyst was prepared by an impregnation followed chemical reduction method.The effect of preparation conditions on the catalytic performance of the catalyst for hydrogenation of nitrobenzene to aniline were investigated.The crystal phase,morphology,and specific surface area of the catalyst were characterized.The results showed that the amorphous Ni-B alloy pillared bentonite catalyst had a large specific surface area,and the amorphous Ni-B alloy had good dispersion in the pores of the pillared bentonite,and exhibited good catalytic hydrogenation performance and stability.Under the conditions of initial pressure of 2.0 MPa,reaction temperature of 110 ℃ and reaction time of 2 h,the conversion rate of nitrobenzene and the selectivity of aniline over the amorphous Ni-B pillared bentonite catalyst reached 92.6% and 96.1%,respectively.After the catalyst was used for 6 times,the conversion rate of nitrobenzene and the selectivity of aniline were maintained at 88.9% and 93.8%,respectively.

Key words: amorphous Ni-B, pillared bentonite, nitrobenzene, aniline, hydrogenation

CLC Number:

TQ138.13

Wang Yanhua,Liu Zili,Wang Qianzhu,Hu Zhendan,Zeng Deming. Study on preparation and hydrogenation performance of amorphous Ni-B alloy pillared bentonite catalyst[J]. Inorganic Chemicals Industry, 2021, 53(8): 106-111.

Figures/Tables 9

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References 26

[1]	Yin X, Wang Q, Duan D, et al. Amorphous NiB alloy decorated by Cu as the anode catalyst for a direct borohydride fuel cell[J]. International Journal of Hydrogen Energy, 2019, 44(21):10971-10981. doi: 10.1016/j.ijhydene.2019.02.150
[2]	Liu P, Zhu Y L, Zhou L, et al. Amorphous nickel phosphide nanopar-ticles for selective hydrogenation of cinnamaldehyde[J]. Catalysis Letters, 2020, 150(9):2695-2702. doi: 10.1007/s10562-019-03022-z
[3]	Bao X, Li Y, Wang J, et al. Amorphous-crystalline Co-B-P catalyst for synergistically enhanced hydrogen evolution reaction[J], 2020, 12(24):6259-6264.
[4]	Su T, Jiang Y, Xu Y, et al. Ba-modified Ni-P amorphous alloy/aci-dified bentonite catalyst:Preparation and the catalytic hydrogena-tion of nitrobenzene to aniline[J]. Reaction Kinetics,Mechanisms and Catalysis, 2020, 131(2):805-818. doi: 10.1007/s11144-020-01894-6
[5]	Wang H, Gao D, Wang L, et al. Highly dispersed surfactant-free sm-orphous NiCoB nanoparticles and their remarkable catalytic activity for hydrogen generation from ammonia borane dehydrogenation[J]. Catalysis Letters, 2018, 148(6):1739-1749. doi: 10.1007/s10562-018-2374-8
[6]	程庆彦, 刘栋杰, 王明明, 等. Ni-Co-P非晶态合金催化香草醛HDO性能的研究[J]. 燃料化学学报, 2019, 47(10):1205-1213.
[7]	程庆彦, 王明明, 张凯, 等. Ni-W-P非晶态合金催化剂的制备及催化硝基苯液相加氢性能[J]. 石油学报:石油加工, 2019, 35(4):628-637.
[8]	Wang S, He P, Xie Z, et al. Tunable nanocotton-like amorphous ter-nary Ni-Co-B:A highly efficient catalyst for enhanced oxygen evolution reaction[J]. Electrochimica Acta, 2019, 296:644-652. doi: 10.1016/j.electacta.2018.11.099
[9]	陈悦蓉, 靳惠明, 俞亮, 等. Cr掺杂的Co-B非晶态合金的制备及催化硼氢化钠水解制氢[J]. 无机盐工业, 2020, 52(2):91-96.
[10]	邵阳阳, 靳惠明, 俞亮, 等. Mo掺杂Co-B非晶态合金的制备及催化硼氢化钠水解制氢性能[J]. 材料导报, 2020, 34(2):2063-2066,2082.
[11]	Chen J, Duan Z, Song Z, et al. Relationship between surface pro-perty and catalytic application of amorphous NiP/Hβ catalyst for n-hexane isomerization[J]. Applied Surface Science, 2017, 425:448-460. doi: 10.1016/j.apsusc.2017.07.019
[12]	孙海杰, 陈志浩, 陈凌霞, 等. 自搅拌下CoB/SiO₂催化剂催化硼氢化钠水解制氢研究[J]. 无机盐工业, 2020, 52(3):101-106.
[13]	蒋丽红, 宋爽爽, 潘登, 等. Ni-P/TiO₂非晶态催化剂对α-蒎烯加氢的性能[J]. 化工进展, 2019, 38(6):2768-2775.
[14]	Li F, Ma R, Cao B, et al. Effect of loading method on selective hy-drogenation of chloronitrobenzenes over amorphous Ni-B/CNTs catalysts[J]. Catalysis Communications, 2016, 80:1-4. doi: 10.1016/j.catcom.2016.03.009
[15]	孙海杰, 黄振旭, 王雅苹, 等. 非晶态合金Ru-B/ZrO₂催化剂催化硼氢化钠水解制氢性能的研究[J]. 化工新型材料, 2018, 46(1):102-105.
[16]	李发达, 李红伟, 季东, 等. 低负载量Ru-W-B/NaY催化剂制备及其对对苯二酚加氢性能[J]. 精细化工, 2019, 36(6):1124-1131.
[17]	申晨, 王亚明, 蒋丽红, 等. Ni-P/rGO复合催化剂的制备、表征及其松香加氢性能研究[J]. 林产化学与工业, 2019, 39(3):57-64.
[18]	黄旋燕, 刘自力, 何家武, 等. 硝基苯在负载型非晶态合金催化剂Ni-B/K₂Ti₆O₁₃上加氢合成苯胺[J]. 精细化工, 2015, 32(4):403-407,433.
[19]	韩红青, 朱岳. 膨润土改性及其应用研究[J]. 无机盐工业, 2011, 43(10):5-8.
[20]	黄荣强, 阙绍娟. 我国膨润土资源开发应用现状[J]. 西部资源, 2010(5):36-38.
[21]	张文娟, 王其伟, 丁艳蓉, 等. 铝-稀土柱撑膨润土的制备与表征[J]. 稀土, 2020, 41(6):55-63.
[22]	郑举功, 杨婷, 刘晓东, 等. Al₁₃柱撑膨润土的制备及柱化影响因素的研究[J]. 非金属矿, 2010, 33(4):9-12.
[23]	徐云, 蒋月秀, 秦祖赠, 等. Ni-P非晶态合金/酸化膨润土的制备及加氢性能[J]. 化工进展, 2017, 36(5):1719-1726.
[24]	张文娟, 马莹, 郝一凡, 等. Al-Ce柱撑膨润土的制备研究[J]. 功能材料, 2019, 50(7):7199-7204,7209.
[25]	Liu Z, Md A U, Sun Z. FT-IR and XRD analysis of natural Na-ben-tonite and Cu(Ⅱ)-loaded Na-bentonite[J]. Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy, 2011, 79(5):1013-1016. doi: 10.1016/j.saa.2011.04.013
[26]	王润平, 毛树红, 段秀琴, 等. 不同载体Ni基负载型催化剂对甲烷部分氧化制合成气催化行为研究[J]. 燃料化学学报, 2015, 43(2):228-234.

催化剂	转化率/%	选择性/%
Ni-B	71.2	80.8
Ni-B/BN-15%	82.3	84.7
Ni-B/PBN-15%	92.6	96.1

催化剂	比表面积/ （m²·g^-1）	催化剂	比表面积/ （m²·g^-1）
BN	47	Ni-B/PBN-5%	143
Ni-B	27	Ni-B/PBN-15%	60
Ni-B/BN-15%	36	Ni-B/PBN-25%	41
PBN	176

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Study on preparation and hydrogenation performance of amorphous Ni-B alloy pillared bentonite catalyst

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