铂基丙烷脱氢催化剂研究进展

doi:10.19964/j.issn.1006-4990.2023-0060

Abstract

Abstract:

Propane dehydrogenation（PDH） is an industrial technology for direct propylene production，which has received extensive attention and realized large-scale application.At present，the commercial platinum-based catalysts suffer from fast deactivation and inferior stability resulting from active species sintering and coke depositing.Based on the above problems，the reaction kinetics and active sites of the platinum based catalysts for propane dehydrogenation were analyzed，and it was pointed out that dispersion and stability of Pt nanoclusters were the key factors affecting the dehydrogenation performance.Then the strategies to improve the stability of the platinum-based propane dehydrogenation catalyst were systematically summarized from the perspectives of controlling the active sites of the catalyst and modifying the support.Finally，the future development prospects of propane dehydrogenation catalysts were discussed，and it was pointed out that the precise design of platinum-based catalyst structures based on reaction mechanisms and development of new alternative platinum-based catalysts were important directions in the research of propane dehydrogenation process，providing new ideas for further industrial application of propane dehydrogenation to propylene.

Key words: propane dehydrogenation, platinum-based catalysts, promoters, support, stability

CLC Number:

TQ426.94

WANG Yansu, LIU Guozhu, YU Haibin. Research progress of platinum-based propane dehydrogenation catalysts[J]. Inorganic Chemicals Industry, 2023, 55(7): 1-9.

Figures/Tables 5

References 55

1	CHEN Sai， CHANG Xin， SUN Guodong，et al.Propane dehydrogenation：Catalyst development，new chemistry，and emerging technologies［J］.Chemical Society Reviews，2021，50（5）：3315-3354.
2	XU Zhikang， XU Rui， YUE Yuanyuan，et al.Bimetallic Pt-Sn nanocluster from the hydrogenolysis of a well-defined surface compound consisting of［（AlO）Pt（COD）Me］and ［（AlO）SnPh₃］fragments for propane dehydrogenation［J］.Journal of Catalysis，2019，374：391-400.
3	ZHA Shenjun， SUN Guodong， WU Tengfang，et al.Identification of Pt-based catalysts for propane dehydrogenation via a probability analysis［J］.Chemical Science，2018，9（16）：3925-3931.
4	SATTLER J J H B， RUIZ-MARTINEZ J， SANTILLAN-JIMENEZ E，et al.Catalytic dehydrogenation of light alkanes on metals and metal oxides［J］.Chemical Reviews，2014，114（20）：10613-10653.
5	郭秋双，蔡奇，孙彦民，等.低碳烷烃脱氢催化剂的研究进展［J］.无机盐工业，2016，48（8）：11-15.
	GUO Qiushuang， CAI Qi， SUN Yanmin，et al.Research progress of low carbon alkane dehydrogenation catalyst［J］.Inorganic Chemicals Industry，2016，48（8）：11-15.
6	QI Wei， YAN Pengqiang， SU Dangsheng.Oxidative dehydrogenation on nanocarbon：Insights into the reaction mechanism and kinetics via in situ experimental methods［J］.Accounts of Chemical Research，2018，51（3）：640-648.
7	CARRERO C A， SCHLOEGL R， WACHS I E，et al.Critical literature review of the kinetics for the oxidative dehydrogenation of propane over well-defined supported vanadium oxide catalysts［J］.ACS Catalysis，2014，4（10）：3357-3380.
8	ZHANG Haijuan， WAN Hai， ZHAO Yue，et al.Effect of chlorine elimination from Pt-Sn catalyst on the behavior of hydrocarbon
	reconstruction in propane dehydrogenation［J］.Catalysis Today， 2019，330：85-91.
9	李晓云，胡远明，蔡奇，等.铂系低碳烷烃脱氢催化剂研究进展［J］.无机盐工业，2021，53（5）：1-6.
	LI Xiaoyun， HU Yuanming， CAI Qi，et al.Research progress of Pt-based catalysts for dehydrogenation of low-carbon alkanes［J］.Inorganic Chemicals Industry，2021，53（5）：1-6.
10	ZHANG Wei， WANG Haizhi， JIANG Jiawei，et al.Size dependence of Pt catalysts for propane dehydrogenation：From atomically dispersed to nanoparticles［J］.ACS Catalysis，2020，10（21）：12932-12942.
11	SUN Guodong， ZHAO Zhijian， MU Rentao，et al.Breaking the scaling relationship via thermally stable Pt/Cu single atom alloys for catalytic dehydrogenation［J］.Nature Communications，2018，9：4454.
12	KAYLOR N， DAVIS R J.Propane dehydrogenation over supported Pt-Sn nanoparticles［J］.Journal of Catalysis，2018，367：181-193.
13	HE Yang， SONG Yuanjun， CULLEN D A，et al.Selective and stable non-noble-metal intermetallic compound catalyst for the direct dehydrogenation of propane to propylene［J］.Journal of the American Chemical Society，2018，140（43）：14010-14014.
14	CHEN Sai， PEI Chunlei， SUN Guodong，et al.Nanostructured catalysts toward efficient propane dehydrogenation［J］.Accounts of Materials Research，2020，1（1）：30-40.
15	WEINBERG W H， SUN Yongkui.Quantification of primary versus secondary C—H bond cleavage in alkane activation：Propane on Pt［J］.Science，1991，253（5019）：542-545.
16	JOHNSON D F， WEINBERG W H.Quantification of the selective activation of C—C bonds in short-chain alkanes.Reactivity of ethane，propane，isobutane，n-butane and neopentane on Ir（111）［J］.Physical Chemistry Chemical Physics，1995，91（20）：3695-3702.
17	MARCINKOWSKI M D， DARBY M T， LIU Jilei，et al.Pt/Cu single-atom alloys as coke-resistant catalysts for efficient C—H activation［J］.Nature Chemistry，2018，10（3）：325-332.
18	ZHU Jun， YANG Minglei， YU Yingda，et al.Size-dependent reaction mechanism and kinetics for propane dehydrogenation over Pt catalysts［J］.ACS Catalysis，2015，5（11）：6310-6319.
19	LIAN Zan，ALI S， LIU Tianfu，et al.Revealing the Janus character of the coke precursor in the propane direct dehydrogenation on Pt catalysts from a kMC simulation［J］.ACS Catalysis，2018， 8（5）：4694-4704.
20	LIU Lichen， LOPEZ-HARO M， LOPES C W，et al.Structural modulation and direct measurement of subnanometric bimetallic PtSn clusters confined in zeolites［J］.Nature Catalysis，2020，3（8）：628-638.
21	FAN Xiaoqiang， LIU Dandan， SUN Xiaoying，et al.Mn-doping induced changes in Pt dispersion and Pt _x Mn _y alloying extent on Pt/Mn-DMSN catalyst with enhanced propane dehydrogenation stability［J］.Journal of Catalysis，2020，389：450-460.
22	MOTAGAMWALA A H， ALMALLAHI R， WORTMAN J，et al.Stable and selective catalysts for propane dehydrogenation operating at thermodynamic limit［J］.Science，2021，373（6551）：217-222.
23	常小虎，赵毅，周帅，等.Fe改性silicalite-1分子筛铂基催化剂的制备及其丙烷脱氢的催化性能［J］.合成化学，2022，30（7）：574-582.
	CHANG Xiaohu， ZHAO Yi， ZHOU Shuai，et al.Fe modified silicalite-1 supported Pt-based catalyst for propane dehydrogenation［J］.Chinese Journal of Synthetic Chemistry，2022，30（7）：574-582.
24	YAN Huan， HE Kun， SAMEK I A，et al.Tandem In₂O₃-Pt/Al₂O₃ catalyst for coupling of propane dehydrogenation to selective H₂ combustion［J］.Science，2021，371（6535）：1257-1260.
25	CAMACHO-BUNQUIN J， FERRANDON M S， SOHN H，et al.Atomically precise strategy to a PtZn alloy nanocluster catalyst for the deep dehydrogenation of n-butane to 1，3-butadiene［J］.ACS Catalysis，2018，8（11）：10058-10063.
26	JIANG Feng， ZENG Liang， LI Shuirong，et al.Propane dehydrogenation over Pt/TiO₂-Al₂O₃ catalysts［J］.ACS Catalysis，2015，5（1）：438-447.
27	LI Jiacheng， LI Jianmei， ZHAO Zhen，et al.Size effect of TS-1 supports on the catalytic performance of PtSn/TS-1 catalysts for propane dehydrogenation［J］.Journal of Catalysis，2017，352：361-370.
28	ZHOU Hualan， GONG Jingjing， XU Bolian，et al.PtSnNa/SUZ-4：An efficient catalyst for propane dehydrogenation［J］.Chinese Journal of Catalysis，2017，38（3）：529-536.
29	WANG Peng， YAO Jikang， JIANG Qike，et al.Stabilizing the isolated Pt sites on PtGa/Al₂O₃ catalyst via silica coating layers for propane dehydrogenation at low temperature［J］.Applied Catalysis B：Environmental，2022，300：120731.
30	YANG Ce， WU Zhenwei， ZHANG Guanghui，et al.Promotion of Pd nanoparticles by Fe and formation of a Pd₃Fe intermetallic alloy for propane dehydrogenation［J］.Catalysis Today，2019，323：123-128.
31	ZHANG Xiaotong， HE Ning， LIU Chunyan，et al.Pt-Cu alloy nanoparticles encapsulated in silicalite-1 molecular sieve：Coke-resistant catalyst for alkane dehydrogenation［J］.Catalysis Letters，2019，149（4）：974-984.
32	KAISER S K， CHEN Zupeng， FAUST A D，et al.Single-atom catalysts across the periodic table［J］.Chemical Reviews，2020，120（21）：11703-11809.
33	CHEN Sai， ZHAO Zhijian， MU Rentao，et al.Propane dehydrogenation on single-site ［PtZn₄］ intermetallic catalysts［J］.Chem，2021，7（2）：387-405.
34	NAKAYA Y， HIRAYAMA J， YAMAZOE S，et al.Single-atom Pt in intermetallics as an ultrastable and selective catalyst for propane dehydrogenation［J］.Nature Communications，2020，11：2838.
35	YANG Chaojun， MIAO Zhili， ZHANG Fan，et al.Hydrogenolysis of methyl glycolate to ethanol over a Pt-Cu/SiO₂ single-atom alloy catalyst：A further step from cellulose to ethanol［J］.Green Chemistry，2018，20（9）：2142-2150.
36	ZHAO E W， MALIGAL-GANESH R， XIAO Chaoxian，et al.Silica-encapsulated Pt-Sn intermetallic nanoparticles：A robust catalytic platform for parahydrogen-induced polarization of gases and liquids［J］.Angewandte Chemie，2017，56（14）：3925-3929.
37	QI Zhiyuan， XIAO Chaoxian， LIU Cong，et al.Sub-4 nm PtZn intermetallic nanoparticles for enhanced mass and specific activities in catalytic electrooxidation reaction［J］.Journal of the American Chemical Society，2017，139（13）：4762-4768.
38	CESAR L G， YANG Ce， LU Zheng，et al.Identification of a Pt₃Co surface intermetallic alloy in Pt-Co propane dehydrogenation catalysts［J］.ACS Catalysis，2019，9（6）：5231-5244.
39	LIBRETTO N J， YANG Ce， REN Yang，et al.Identification of surface structures in Pt₃Cr intermetallic nanocatalysts［J］.Chemistry of Materials，2019，31（5）：1597-1609.
40	YE Chenliang， PENG Mao， WANG Yunhao，et al.Surface hexagonal Pt₁Sn₁ intermetallic on Pt nanoparticles for selective propane dehydrogenation［J］.ACS Applied Materials & Interfaces，2020，12（23）：25903-25909.
41	WEGENER E C， BUKOWSKI B C， YANG Dali，et al.Intermetallic compounds as an alternative to single-atom alloy catalysts：Geometric and electronic structures from advanced X-ray spectroscopies and computational studies［J］.ChemCatChem，2020，12（5）：1325-1333.
42	CAI Weiting， MU Rentao， ZHA Shenjun，et al.Subsurface catalysis-mediated selectivity of dehydrogenation reaction［J］.Science Advances，2018，4（8）：eaar5418.
43	YE Chenliang， PENG Mao， LI Yang，et al.Atomically dispersed Pt in ordered PtSnZn intermetallic with Pt-Sn and Pt-Zn pairs for selective propane dehydrogenation［J］.Science China Materials，2022，66：1071-1078.
44	JONES J， XIONG Haifeng， DELARIVA A T，et al.Thermally-stable single-atom platinum-on-ceria catalysts via atom trapp- ing［J］.Science，2016，353（6295）：150-154.
45	SHI Lei， DENG Gaoming， LI Wencui，et al.Al₂O₃ nanosheets rich in pentacoordinate Al³⁺ ions stabilize Pt-Sn clusters for propane dehydrogenation［J］.Angewandte Chemie，2015，54（47）：13994-13998.
46	RYOO R， KIM J，JO C，et al.Rare-earth-platinum alloy nanoparticles in mesoporous zeolite for catalysis［J］.Nature，2020， 585（7824）：221-224.
47	LIU Lichen， LOPEZ-HARO M， LOPES C W，et al.Regioselective generation and reactivity control of subnanometric platinum clusters in zeolites for high-temperature catalysis［J］.Nature Materials，2019，18（8）：866-873.
48	SEARLES K， CHAN K W， MENDES BURAK J A，et al.Highly productive propane dehydrogenation catalyst using silica-supported Ga-Pt nanoparticles generated from single-sites［J］.Journal of the American Chemical Society，2018，140（37）：11674-11679.
49	ZHANG Jiayun， DENG Yuchen， CAI Xiangbin，et al.Tin-assisted fully exposed platinum clusters stabilized on defect-rich graphene for dehydrogenation reaction［J］.ACS Catalysis，2019，9（7）：5998-6005.
50	SUN Xiaoying， LIU Meijun， HUANG Yaoyao，et al.Electronic interaction between single Pt atom and vacancies on boron nitride nanosheets and its influence on the catalytic performance in the direct dehydrogenation of propane［J］.Chinese Journal of Catalysis，2019，40（6）：819-825.
51	WANG Yansu， HU Zhongpan， TIAN Wenwen，et al.Framework-confined Sn in Si-beta stabilizing ultra-small Pt nanoclusters as direct propane dehydrogenation catalysts with high selectivity and stability［J］.Catalysis Science & Technology，2019，9（24）：6993-7002.
52	WANG Yansu， HU Zhongpan， Xianwei LÜ，et al.Ultrasmall PtZn bimetallic nanoclusters encapsulated in silicalite-1 zeolite with superior performance for propane dehydrogenation［J］.Journal of Catalysis，2020，385：61-69.
53	WANG Yansu， SUO Yujun， Xianwei LÜ，et al.Enhanced performances of bimetallic Ga-Pt nanoclusters confined within silicalite-1 zeolite in propane dehydrogenation［J］.Journal of Colloid and Interface Science，2021，593：304-314.
54	SUN Qiming， WANG Ning， FAN Qiyuan，et al.Subnanometer bimetallic platinum-zinc clusters in zeolites for propane dehydrogenation［J］.Angewandte Chemie，2020，59（44）：19450-19459.
55	LU Zheng， TRACY R W， LEIGH ABRAMS M，et al.Atomic layer deposition overcoating improves catalyst selectivity and longevity in propane dehydrogenation［J］.ACS Catalysis，2020，10（23）：13957-13967.

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Research progress of platinum-based propane dehydrogenation catalysts

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