无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (6): 35-.

• 论文 • 上一篇    下一篇

无机铝盐辅助活性氧化铝水热合成拟薄水铝石

李晓云,于海斌,孙彦民,李世鹏,曾贤君,隋云乐,周 鹏   

  1. 中海油天津化工研究设计院有限公司,催化技术重点实验室,天津 300131
  • 出版日期:2016-06-10 发布日期:2016-06-02

Inorganic aluminum salt assisted hydrothermal synthesis of pseudoboehmite by activated alumina

LI  Xiao-Yun, YU  Hai-Bin, SUN  Yan-Min, LI  Shi-Peng, ZENG  Xian-Jun, SUI  Yun-Le, ZHOU   Peng   

  1. Key Laboratory of Catalysis Technology,CenerTech Tianjin Chemical Research and Design Institute Co.,Ltd.,Tianjin 300131,China
  • Online:2016-06-10 Published:2016-06-02

摘要: 采用活性氧化铝为主要原料,直接水热合成或以铝盐水解产物为晶种通过水热法制备了形貌各异的拟薄水铝石,并利用扫描电镜、X射线衍射、物理吸附仪对其表观形貌、物相结构和孔结构进行了表征。结果表明,活性氧化铝具有很强的可塑性,可直接水热合成或在晶种存在下形成棱柱状、绒球状、片状等多种形貌的拟薄水铝石,为制备形貌可控的拟薄水铝石提供了一条新的制备方法。

关键词: 拟薄水铝石, 活性氧化铝, 无机铝盐, 水热法

Abstract: Pseudoboehmites with a variety of morphologies were prepared via hydrothermal method using activated alumina as main material directly or with the hydrolysis product of aluminum salt as seed crystal.The morphology,phase structure,and pore structure were characterized by scanning electron microscopy,X-ray diffraction,and physical adsorption.It was shown that the activated alumina was plastic,and can form pseudoboehmite with different morphologies,such as prismatic shape,pompon,and flake.A new method was provided for preparation of controllable morphology of pseudoboehmite.

Key words: pseudoboehmite, activated alumina, inorganic aluminum salt, hydrothermal method

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