无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2015, Vol. 47 ›› Issue (4): 26-.

• 论文 • 上一篇    下一篇

硫酸钛液稳定性分析及偏钛酸粒度控制研究

杨 林,易德莲,汪 成,伍 林   

  1. 武汉科技大学化学工程与技术学院,湖北武汉 430081
  • 出版日期:2015-04-10 发布日期:2015-04-20

Analysis on stability of titanium sulfate solution and metatitanic acid size control

 YANG   Lin, YI  De-Lian, WANG   Cheng, WU   Lin   

  1. School of Chemical Engineering and Technology,Wuhan University of Science and Technology,Wuhan 430081,China
  • Published:2015-04-10 Online:2015-04-20

摘要: 测试了硫酸法钛白生产中系列浓度钛液在不同温度下的稳定性;并根据系列稳定性数据调节水解工艺,在水解初期适当延长升温时间,水解后期加入适量的稀碱液。用激光粒度分析仪、扫描电子显微镜测定偏钛酸的粒度分布及粒子形貌。结果显示,调节工艺后得到的偏钛酸粒度分布曲线的半峰宽缩小,整体均匀性较好;扫描电子显微镜照片显示调节工艺对小粒子的产生有明显抑制作用;水解率达到97.0%。

关键词: 硫酸钛液, 水解, 稳定性, 偏钛酸, 粒度分布

Abstract: The stability of titanium sulfate solution with series concentrations by sulfuric acid method at different temperatures was tested.According to the series stability data,the hydrolysis process was adjusted,such as appropriate extended the heating time at the beginning of the hydrolysis,and injected the right amount of dilute alkali liquor at later period of hydrolysis.The size distribution and particle morphology of metatitanic acid particles were determined by the laser particle size analyzer and scanning electron microscope.Results showed that after adjusted the process,half peak width of particle size distribution curve become narrow and uniform on the whole. Scanning electron microscope photographs showed that small particles had been inhibited obviously.The hydrolysis rate reached 97.0%.

Key words: titanium sulfate solution, hydrolysis, stability, metatitanic acid, particle size distribution

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