无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2015, Vol. 47 ›› Issue (1): 63-.

• 论文 • 上一篇    下一篇

石墨烯/二氧化钛复合材料的制备及催化性能研究

孟祖超,叶绿生,尹云超,薛 鹏,贺娜娜   

  1. 西安石油大学化学化工学院,陕西西安 710065
  • 出版日期:2015-01-10 发布日期:2015-01-14

Preparation and catalytic properties of graphene/titania composites

 MENG  Zu-Chao, YE  Lu-Sheng, YIN  Yun-Chao, XUE   Peng, HE  Na-Na   

  1. School of Chemistry and Chemical Engineering,Xi′an Shiyou University,Xi′an 710065,China
  • Online:2015-01-10 Published:2015-01-14

摘要: 以石墨粉和钛酸四丁酯为原料,通过水热法一步合成了石墨烯/二氧化钛复合材料。采用XRD和SEM对该复合物进行了表征,并研究了光照条件、石墨烯含量、煅烧温度、光催化时间和pH等因素对聚丙烯酰胺降黏性能的影响。实验结果表明:在石墨烯/二氧化钛复合材料中,二氧化钛纳米颗粒均匀地分散在石墨烯层上;当在石墨烯质量分数为10%、煅烧温度为450 ℃、pH为6~7、光催化30 min等条件下,石墨烯/二氧化钛复合材料在紫外光下对聚丙烯酰胺的光催化降黏率能达到96%以上。

关键词: 石墨烯, 二氧化钛, 复合材料, 光催化降解, 聚丙烯酰胺

Abstract: Graphene/titania(GR/TiO2) composites were prepared by facile hydrothermal reaction with graphite powder and n-butyl titanate as raw materials.The composites were characterized by X-ray diffraction(XRD) and scanning electron micro- scope(SEM).The influences of graphene content,lighting conditions,calcination temperature,lighting time,and pH etc.on photocatalytic degradation activities of GR/TiO2 to polyacrylamide(PAM) were evaluated.Results showed that TiO2 nanoparticles were dispersed on the surface of graphene sheets uniformly in the GR/TiO2 composites.When the GR mass fraction was 10%,the calcination temperature was 450 ℃,the photocatalytic time was 30 min,and pH was at 6~7,the UV photocatalytic degradation of GR/TiO2 to PAM could reach more than 96%.

Key words: graphene, titania, composites, photocatalytic degradation, polyacrylamide

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