无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (12): 57-.

• 论文 • 上一篇    下一篇

利用硼泥制备氢氧化镁工艺条件研究

杨雪梅1,胡 珊1,王凌刚1,郑 谦2,周美珍2   

  1. 1.中国地质大学材料与化学学院,湖北武汉 430074;2.丹东科漫材料有限公司
  • 出版日期:2014-12-10 发布日期:2014-12-08

Research on preparing magnesium hydroxide from boron slurry

Yang Xuemei1,Hu Shan1,Wang Linggang1,Zheng Qian1,Zhou Meizhen2   

  1. 1.School of Materials Science and Chemistry,China University of Geosciences,Wuhan 430074,China;
    2.Dandong Cosman Materials Co.,Ltd.
  • Online:2014-12-10 Published:2014-12-08

摘要: 以硼泥为镁源,氨水为沉淀剂,采用直接沉淀法制备出超细片状氢氧化镁粉体。通过研究不同反应条件对氢氧化镁产率的影响,最终得到合成氢氧化镁的最佳工艺条件。利用X射线衍射(XRD)、热重分析(TG)、扫描电镜(SEM)和粒度分析等手段对产物氢氧化镁进行了表征。结果表明:实验所得产物为超细片状氢氧化镁,且晶体比较完善,形貌为六方片状。最佳合成工艺条件:用盐酸在室温下浸出得到镁液,以氨水为沉淀剂,反应终点pH=11、反应温度为60 ℃,沉降时间为2 h、氨水稀释比例(体积比)为1∶1、氨水滴加速度为1滴/s。添加无水乙醇能有效改善氢氧化镁的胶结和分散性。

关键词: 硼泥, 氢氧化镁, 产率, 粒度, 形貌

Abstract: The superfine flaky magnesium hydroxide powder was prepared by direct precipitation method,with boron slurry as magnesium source and ammonia as precipitator.Through study on the influences of different reaction conditions on the production rate of magnesium hydroxide,the optimum technological conditions for synthesis of magnesium hydroxide were eventually obtained.The product was characterized by XRD,TG,SEM,and particle-size analyzer.The results showed that the product of the experiment was ultrafine magnesium hydroxide,the crystal was well structured,and the morphology of which was six-party flake.The optimum synthetic process conditions were as follows:leaching with hydrochloric acid at room temperature to get magnesium solution,pH was 11,reaction temperature was 60 ℃,subsidence time was 2 h,ammonia dilution ratio (volume ratio) was 1∶1,and dropping speed of ammonia was 1 drop/s.Adding anhydrous ethanol can effectively improve the binding and dispersity of magnesium hydroxide.

Key words: boron slurry, magnesium hydroxide, productivity, particle size, morphology