二维MXene材料——Ti3C2Tx在钠离子电池中的研究进展

doi:10.19964/j.issn.1006-4990.2020-0450

摘要/Abstract

摘要：

作为第一个被制备出来的MXene材料,Ti₃C₂T_x独特的二维层状结构使其具有良好的电学、光学、力学与热电等性质,在电化学储能领域展现出巨大的潜力。由于钠储量在地球中较为丰富且远高于锂储量,因此钠离子电池具有成本低等优点,成为近几年储能领域的研究热点。主要围绕Ti₃C₂T_x的特性,介绍了其通过插层、造孔等改性方法以及与单质、金属氧化物、金属硫化物结合构成复合材料作为钠离子电池电极材料的研究进展。最后指出应采取基于钠离子脱嵌或反应的更有针对性的优化方法提升总体的电化学性能。

关键词: MXene, Ti₃C₂T_x, 改性, 复合材料, 钠离子电池

Abstract:

As the first prepared mxene material,Ti₃C₂T_x has excellent electrical,optical,mechanical and thermoelectric prop-erties due to its unique two-dimensional layered structure,showing great potential in the field of electrochemical energy stor-age.Due to the abundance of sodium in the earth and much higher than that of lithium,sodium-ion battery has the advantages of low cost and has become a research hotspot in the field of energy storage in recent years.Based on the properties of Ti₃C₂T_x,the modification methods of Ti₃C₂T_x,such as intercalation and pore-forming,and the research progress of composite materials composed of monomers,metal oxides and metal sulfides as electrodes materials for sodium-ion batteries were introduced.Finally,it was pointed out that more targeted optimization methods based on sodium ion deintercalation or reaction should be adopted to improve the overall electrochemical performance.

Key words: MXene, Ti₃C₂T_x, modification, composite material, sodium-ion batteries

中图分类号:

TQ134.11

周彬,白小洁,刘昊,廖立兵. 二维MXene材料——Ti₃C₂T_x在钠离子电池中的研究进展[J]. 无机盐工业, 2021, 53(8): 21-26.

Zhou Bin,Bai Xiaojie,Liu Hao,Liao Libing. Research progress of two-dimensional MXene material of Ti₃C₂T_x in sodium-ion batteries[J]. Inorganic Chemicals Industry, 2021, 53(8): 21-26.

图/表 4

参考文献 37

[1]	Naguib M, Kurtoglu M, Presser V, et al. Two-dimensional nanocryst-als produced by exfoliation of Ti₃AlC₂[J]. Advanced Materials, 2011, 23(37):4248-4253. doi: 10.1002/adma.201102306
[2]	Hu Q, Sun D, Wu Q, et al. MXene:A new family of promising hydro-gen storage medium[J]. Journal of Physical Chemistry A, 2013, 117(51):14253-14260. doi: 10.1021/jp409585v
[3]	Anasori B, Lukatskaya M R, Gogotsi Y. 2D metal carbides and nitri-des(MXenes) for energy storage[J]. Nature Reviews Materials, 2017, 2(2).Doi: 10.1038/natrevmats.2016.98.
[4]	郑伟, 杨莉, 张培根, 等. 二维材料MXene的储能性能与应用[J]. 材料导报, 2018, 32(15):2513-2537.
[5]	郝峰. 锂离子电池的替代者——钠离子电池研究现状分析[J]. 化工管理, 2018(28):62.
[6]	Tang Q, Zhou Z, Shen P. Are MXenes promising anode materials for Li ion batteries? Computational studies on electronic properties and Li storage capability of Ti₃C₂ and Ti₃C₂X₂(X=F,OH) monolayer[J]. Journal of the American Chemical Society, 2012, 134(40):16909-16916. doi: 10.1021/ja308463r
[7]	Chae Y, Kim S J, Cho S Y, et al. An investigation into the factors go-verning the oxidation of two-dimensional Ti₃C₂ MXene[J]. Nanosc-ale, 2019, 11(17):8387-8393.
[8]	Lipatov A, Alhabeb M, Lukatskaya M R, et al. Effect of synjournal on quality,electronic properties and environmental stability of indivi-dual monolayer Ti₃C₂ MXene flakes[J]. Advanced Electronic Materials, 2016, 2(12):1600255-1600264. doi: 10.1002/aelm.v2.12
[9]	Sang X, Xie Y, Lin M W, et al. Atomic defects in monolayer titanium carbide(Ti₃C₂T_x) MXene[J]. Acs Nano, 2016, 10(10):9193-9200. doi: 10.1021/acsnano.6b05240
[10]	Hart J L, Hantanasirisakul K, Lang A C, et al. Control of MXenes′ electronic properties through termination and intercalation[J]. Nat-ure Communications, 2019, 10(1):522-531.
[11]	李友兵, 方菲. 二维过渡金属碳化物的研究现状及在吸波领域的应用[J]. 科技经济导刊, 2017(1):80.
[12]	Yun T, Kim H, Iqbal A, et al. Electromagnetic shielding of mono-layer MXene assemblies[J]. Advanced Materials, 2020, 32(9):1906769-1906777. doi: 10.1002/adma.v32.9
[13]	Fan Z, Wang D, Yuan Y, et al. A lightweight and conductive MXene/graphene hybrid foam for superior electromagnetic interference shielding[J]. Chemical Engineering Journal, 2020, 381(1):122696-122703. doi: 10.1016/j.cej.2019.122696
[14]	Wang X, Xi S, Gao Y, et al. Atomic-scale recognition of surface st-ructure and intercalation mechanism of Ti₃C₂X[J]. Journal of the American Chemical Society, 2015, 137(7):2715-2721. doi: 10.1021/ja512820k
[15]	Kajiyama S, Szabova L, Sodeyama K, et al. Sodium-ion intercalation mechanism in MXene nanosheets[J]. Acs Nano, 2016, 10(3):3334-3341. doi: 10.1021/acsnano.5b06958 pmid: 26891421
[16]	Song X L, Wang H, Jin S M, et al. Oligolayered Ti₃C₂T_x MXene to-wards high performance lithium/sodium storage[J]. Nano Rese-search, 2020, 13(6):1659-1667.
[17]	Xie X, Kretschmer K, Anasori B, et al. Porous Ti₃C₂T_x MXene for ultrahigh-rate sodium-ion storage with long cycle life[J]. ACS App-lied Nano Materials, 2018, 1(2):505-511.
[18]	Zhao M Q, Xie X, Ren C E, et al. Hollow MXene spheres and 3D macroporous MXene frameworks for Na-ion storage[J]. Advanced Materials, 2017, 29(37).Doi: 10.1002/adma.201702410.
[19]	谢银斯, 孙丁武, 林维捐, 等. 钠离子电池负极材料研究进展[J]. 电源技术, 2019, 43(2):351-353.
[20]	黄剑锋, 王彩薇, 李嘉胤, 等. 钠离子电池碳基负极材料的研究进展[J]. 材料导报, 2017, 31(21):19-23.
[21]	Zhang P, Soomro R A, Guan Z, et al. 3D carbon-coated MXene ar-chitectures with high and ultrafast lithium/sodium-ion storage[J]. Energy Storage Materials, 2020, 29:163-171. doi: 10.1016/j.ensm.2020.04.016
[22]	袁振洲, 刘丹敏, 田楠, 等. 二维黑磷的结构、制备和性能[J]. 化学学报, 2016, 74(06):488-497.
[23]	Zhao R, Qian Z, Liu Z, et al. Molecular-level heterostructures as-sembled from layered black phosphorene and Ti₃C₂ MXene as su-perior anodes for high-performance sodium ion batteries[J]. Nano Energy, 2019, 65:104037-104047. doi: 10.1016/j.nanoen.2019.104037
[24]	肖娜, 潘洋, 宋云, 等. 锑硅纳米复合薄膜作为钠离子电池负极材料的电化学行为研究[J]. 无机材料学报, 2018, 33(5):494-500.
[25]	Maughan P A, Seymour V R, Bernardo Gavito R, et al. Porous silica-pillared MXenes with controllable interlayer distances for long-life Na-ion batteries[J]. Langmuir, 2020, 36(16):4370-4382. doi: 10.1021/acs.langmuir.0c00462 pmid: 32275436
[26]	Wang P, Lu X, Boyjoo Y, et al. Pillar-free TiO₂/Ti₃C₂ composite with expanded interlayer spacing for high-capacity sodium ion batteri-es[J]. Journal of Power Sources, 2020, 451(1):227756-227764. doi: 10.1016/j.jpowsour.2020.227756
[27]	Yang C, Liu Y, Sun X, et al. In-situ construction of hierarchical ac-cordion-like TiO₂/Ti₃C₂ nanohybrid as anode material for lithium and sodium ion batteries[J]. Electrochimica Acta, 2018, 271(1):165-172. doi: 10.1016/j.electacta.2018.03.118
[28]	张帅, 李慧, 梁精龙. 二氧化钒的制备工艺现状[J]. 矿产综合利用, 2021(2):119-123.
[29]	Wu F, Jiang Y, Ye Z, et al. A 3D flower-like VO₂/MXene hybrid architecture with superior anode performance for sodium ion bat-teries[J]. Journal of Materials Chemistry A, 2019, 7(3):1315-1322. doi: 10.1039/C8TA11419F
[30]	Guo X, Xie X, Choi S, et al. Sb₂O₃/MXene(Ti₃C₂T_x) hybrid anode materials with enhanced performance for sodium-ion batteries[J]. Journal of Materials Chemistry A, 2017, 5(24):12445-12452. doi: 10.1039/C7TA02689G
[31]	马艳梅. 钠离子电池硫化物负极材料的研究进展[J]. 储能科学与技术, 2019, 8(3):488-494.
[32]	胡平, 陈震宇, 王快社, 等. 二维层状二硫化钼复合材料的研究进展及发展趋势[J]. 化工学报, 2017, 68(4):1286-1298.
[33]	Ma K, Jiang H, Hu Y, et al. 2D nanospace confined synjournal of pseudocapacitance-dominated MoS₂-in-Ti₃C₂ superstructure for ultrafast and stable Li/Na-ion batteries[J]. Advanced Functional Materials, 2018, 28(40).Doi: 10.1002/adfm.201804306.
[34]	Chauhan H, Singh M K, Hashmi S A, et al. Synjournal of surfactant-free SnS nanorods by a solvothermal route with better electroche-mical properties towards supercapacitor applications[J]. Rsc Advances, 2015, 5(22):17228-17235. doi: 10.1039/C4RA15563G
[35]	Zhang Y, Guo B, Hu L, et al. Synjournal of SnS nanoparticle-modi-fied MXene(Ti₃C₂T_x) composites for enhanced sodium storage[J]. Journal of Alloys and Compounds, 2018, 732(25):448-453. doi: 10.1016/j.jallcom.2017.10.223
[36]	Wen L, Feng L, Qidong L et al.Heterostructured Bi₂S₃-Bi₂O₃ nano-sheets with a built-in electric field for improved sodium storage[J]. ACS Applied Materials & Interfaces, 2018, 10(8):7201-7207.
[37]	Yang Q, Gao W, Zhong W, et al. A synergistic Bi₂S₃/MXene compo-site with enhanced performance as an anode material of sodium-ion batteries[J]. New Journal of Chemistry, 2020, 44(7):3072-3077. doi: 10.1039/C9NJ05986E

首页

全国无机盐信息中心

中国化工学会

无机酸碱盐专业委员会

二维MXene材料——Ti₃C₂T_x在钠离子电池中的研究进展

Research progress of two-dimensional MXene material of Ti₃C₂T_x in sodium-ion batteries

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 4

参考文献 37

相关文章 15

Metrics

本文评价

推荐阅读 10

[1]	赵段,周庚,侯顺丽,蓝兹炜,张建茹,李健,王甲泰. 锂离子电池高镍三元材料的包覆改性研究进展[J]. 无机盐工业, 2021, 53(8): 1-7.
[2]	管若伶,孙畅,卓先勤. 含银高分子膜材料的应用及研究进展[J]. 无机盐工业, 2021, 53(6): 110-117.
[3]	蒋运才,李雪梅,吴兆贤,曹昌蝶,梅毅,廉培超. 黑磷的制备及储能应用研究进展[J]. 无机盐工业, 2021, 53(6): 59-71.
[4]	王玲,熊雨婷,崔兆纯,贾蓝波,范晨子,刘淑贤,聂轶苗. 橄榄石酸溶制备超细二氧化硅改性研究[J]. 无机盐工业, 2021, 53(3): 34-37.
[5]	包科杰,路凌然. 新能源汽车电池负极材料的制备与性能研究[J]. 无机盐工业, 2021, 53(3): 54-59.
[6]	韩琮,孙丽娜,张婷,朱慧霞,李玲. 负载改性钾长石吸附废水中苯酚的研究[J]. 无机盐工业, 2021, 53(2): 71-76.
[7]	杭美艳,彭雅娟,刘欣欣,张海燕,陶旭. 基于砂浆强度解耦法量化研究对铬铁渣的改性影响[J]. 无机盐工业, 2021, 53(1): 72-76.
[8]	陈立甲,陈海彬,李荣泳. 机械涂覆技术在光催化材料制备中的应用进展[J]. 无机盐工业, 2020, 52(8): 1-5.
[9]	胡冬婉,马占玲,马骁,励建荣. 改性果胶-Fe₃O₄磁性微球制备及对Pb ²⁺吸附性能[J]. 无机盐工业, 2020, 52(6): 24-29.
[10]	景亭. 改性纳米碳酸钙用于硅酮胶挤出性研究[J]. 无机盐工业, 2020, 52(4): 57-60.
[11]	朱佳新,熊裕华,郭锐. 二氧化钛光催化剂改性研究进展[J]. 无机盐工业, 2020, 52(3): 23-27.
[12]	龙云飞,苏静,吕小艳,文衍宣. 锂/钠离子电池过渡金属氟磷酸盐正极材料研究进展[J]. 无机盐工业, 2020, 52(3): 28-34.
[13]	王国胜,韩思宇,唐凤翔,徐榕徽. 改性碱式氯化镁晶须/丁苯橡胶复合材料制备与性能研究[J]. 无机盐工业, 2020, 52(3): 51-54.
[14]	王木村,郭小甫,赵颖颖,袁俊生. 沸石法苦卤提钾工艺研究[J]. 无机盐工业, 2020, 52(2): 23-29.
[15]	杭美艳,彭雅娟,路兰,张海燕,陶旭. 基于铬铁渣骨料与水泥浆体界面结构的改性研究与机理分析[J]. 无机盐工业, 2020, 52(12): 75-79.

首 页