无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2019, Vol. 51 ›› Issue (12): 44-48.doi: 10.11962/1006-4990.2019-0023

• 无机盐工业 • 上一篇    下一篇

钛液水解工艺对金红石二氧化钛消色力的影响

路瑞芳,吴健春,刘 婵   

  1. 攀钢集团研究院有限公司,钒钛资源综合利用国家重点实验室,四川攀枝花 617000
  • 出版日期:2019-12-10 发布日期:2019-12-20
  • 作者简介:路瑞芳(1984— ),女,高级工程师,攀枝花市学术与技术带头人后备人选,长期从事钛白工艺及设备开发,发表相关论文10余篇;Email:lulu195658@163.com。

Influence of titanyl sulfate solution hydrolysis process on tintreducing power of rutile titanium dioxide

Lu Ruifang,Wu Jianchun,Liu Chan   

  1. Pangang Group Research Institute Co.,Ltd.,State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization,Panzhihua 617000,China
  • Online:2019-12-10 Published:2019-12-20

摘要: 以工业钛液为原料,采用外加晶种常压水解工艺制备了金红石型二氧化钛,研究了水解钛液的组成和操作参数对二氧化钛消色力的影响。实验结果表明:二氧化钛消色力(Tcs)和蓝相光谱值(Scx)随晶种添加量的增加先增大后减小,随判灰延时时间的增加先增大后减小,随钛液F值的增加先稍有增加后明显降低,随钛液二氧化钛质量浓度的增大而增加。在钛液F值(游离硫酸加上与钛结合的硫酸之和与二氧化钛质量浓度的比值)为1.90左右、铁钛比(铁元素与二氧化钛质量浓度的比值)<0.5、二氧化钛质量浓度为190~200 g/L、晶种添加量(晶种中二氧化钛质量与对应批次水解浓钛液中二氧化钛质量的比值)为2.0%~2.2%、灰点为“基点+20 min”、熟化时间为0~30 min、稀释水在二沸后100 min加入的条件下进行水解,经过一次洗涤—漂白—二次洗涤—盐处理—煅烧,所得金红石型二氧化钛的消色力更好。

关键词: 钛液水解工艺;金红石型二氧化钛;消色力

Abstract: Using industrial condensed titanyl sulfate solution as raw material,Rutile titanium dioxide was prepared by hydr olysis process within adding external seeds.The influences of composition of titanyl sulfate solution and operation conditions on the tintreducing power of rutile titanium dioxide were studied.The experimental results showed that the Tcs and Scx of titanium dioxide increased first and then decreased with the increase of seed addition and delay time of grey point judgment; and increased slightly and then decreased with the increase of F value,and increased with the increase of titanium dioxide concentration.The F value of titanium solution(the mass concentration ratio of free sulfuric acid+sulfuric acid combined with Ti to TiO2) was about 1.90,the ratio of Fe/TiO2 (the mass concentration ratio of Fe to titanium dioixde) was less than 0.5,the mass concentration of TiO2 was 190~200 g/L,the dosage of seeds(the mass ratio of titanium dioxide in crystal seed to the titanium dioxide in related industrial condensed titanyl sulfate solution) was controlled at 2.0%~2.2%,the grey point was “base point + 20 min”,the aging time was 0~30 min,and the diluted water was added at the time of 100 min after the second boiling.Under these conditions,the rutile titanium dioxide obtained by the processes of primary washing,bleaching,secon dary washing,salt treatment and calcination has better tintreducing power.

Key words: titanyl sulfate solution hydrolysis process;rutile titanium dioxide;tintreducing power

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