Inorganic Chemicals Industry ›› 2024, Vol. 56 ›› Issue (3): 70-79.doi: 10.19964/j.issn.1006-4990.2023-0200
• Research & Development • Previous Articles Next Articles
WEI Jincai1(), CHEN Jingyuan2(
), SONG Guichun2, JIA Jiantuan2, GONG Guoli1
Received:
2023-04-26
Online:
2024-03-10
Published:
2024-03-14
Contact:
CHEN Jingyuan
E-mail:1511778350@qq.com;493383716@qq.com
CLC Number:
WEI Jincai, CHEN Jingyuan, SONG Guichun, JIA Jiantuan, GONG Guoli. Study on efficiency of liquefaction mining of solid potassium ore in western Qarhan area of Qarhan Salt Lake[J]. Inorganic Chemicals Industry, 2024, 56(3): 70-79.
Table 1
Grade and thickness of KCl,NaCl,MgCl2 in boreholes"
钻孔编号 | 固体钾盐厚度/m | KCl品位/% | 固体石盐厚度/m | NaCl品位/% | 固体镁盐厚度/m | MgCl2品位/% |
---|---|---|---|---|---|---|
H19206 | 2.08 | 0.25 | 7.25 | 66.79 | 7.25 | 4.01 |
H21204 | 6.56 | 0.36 | 8.60 | 73.29 | 8.60 | 3.07 |
H20810 | 2.00 | 0.23 | 12.20 | 73.37 | 12.20 | 2.84 |
H20813 | 11.23 | 1.52 | 15.60 | 73.60 | 15.60 | 4.10 |
H20815 | 0.72 | 0.24 | 18.00 | 76.56 | 18.00 | 2.21 |
B22401 | 2.26 | 0.22 | 10.00 | 73.36 | 10.00 | 2.08 |
B22403 | 0.50 | 0.34 | 11.50 | 81.61 | 11.50 | 1.90 |
B22405 | 1.00 | 0.32 | 16.50 | 76.00 | 16.50 | 2.84 |
B22407 | 4.80 | 0.45 | 16.50 | 76.66 | 16.50 | 3.10 |
B22409 | 7.50 | 0.82 | 17.00 | 77.15 | 17.00 | 3.08 |
H24802 | 2.45 | 0.24 | 11.40 | 73.32 | 11.40 | 2.06 |
H25201 | 16.18 | 1.02 | 16.10 | 72.53 | 16.10 | 3.48 |
Table.2
Variation of grade and thickness of KCl in brine"
孔号 | 2013年 | 2021年 | 变化值 | 变化率/% | |||||||
---|---|---|---|---|---|---|---|---|---|---|---|
品位/ % | 厚度/ m | 品位/ % | 厚度/ m | 品位/ % | 厚度/ m | 品位/ % | 厚度/ m | ||||
H21614 | 0.88 | 14.65 | 1.7 | 16.870 | +0.82 | +2.22 | +93.18 | +15.15 | |||
H21612 (CG25) | 0.19 | 3.96 | 0.53 | 7.759 | +0.34 | +3.799 | +178.95 | +95.93 | |||
H21609 (CG26) | 1.33 | 5.50 | 0.59 | 8.905 | -0.74 | +3.405 | -55.64 | +61.91 | |||
H23202 | 1.23 | 2.91 | 0.61 | 6.198 | -0.62 | +3.288 | -50.41 | +112.99 | |||
H24803 (CG39) | 1.90 | 1.80 | 0.20 | 6.676 | -1.7 | +4.876 | -89.47 | +270.89 | |||
H24802 | 1.15 | 2.70 | 0.68 | 4.343 | -0.47 | +1.643 | -40.87 | +60.85 |
1 | 袁见齐,霍承禹,蔡克勤.干盐湖阶段的沉积特征兼论钾盐矿层的形成[J].地球科学,1985,10(4):1-9. |
YUAN Jianqi, HUO Chengyu, CAI Keqin.Characteristics of salt deposits in the dry salt lake and the formation of potash beds[J].Earth Science,1985,10(4):1-9. | |
2 | 龙鹏宇,赵艳军,胡宇飞,等.马海盐湖北部矿段低品位固体钾矿中钾盐矿物的赋存特征及成因探讨[J].地球学报,2022,43(3):338-346. |
LONG Pengyu, ZHAO Yanjun, HU Yufei,et al.Occurrence characteristics and genetic study of potassium salt minerals in low grade solid potassium ore in the north section of Mahai salt lake[J].Acta Geoscientica Sinica,2022,43(3):338-346. | |
3 | 王兴富,王石军,田红斌,等.青海盐湖提钾技术进展与我国钾肥工业的发展[J].化工矿物与加工,2017,46(11):48-52. |
WANG Xingfu, WANG Shijun, TIAN Hongbin,et al.Potassium extraction technology progress in Qinghai Salt Lake and development of potash fertilizer industry in China[J].Industrial Minerals & Processing,2017,46(11):48-52. | |
4 | 王文祥,李文鹏,刘振英,等.察尔汗盐湖低品位固体钾矿液化开采的现场试验研究探讨[J].矿床地质,2010,29(4):697-703. |
WANG Wenxiang, LI Wenpeng, LIU Zhenying,et al.A tentative discussion on in situ experimental liquefaction and exploitation of low grade solid potassium resources in Qarhan salt lake[J].Mineral Deposits,2010,29(4):697-703. | |
5 | 李海民,何继辉,胡生忠.马海盐湖钾矿区北部矿段低品位地表固体钾矿开发利用主要方法[J].盐湖研究,2021,29(3):1-8. |
LI Haimin, HE Jihui, HU Shengzhong.Main methods of development and utilization of low grade surface solid potassium ore in the north section of Mahai salt lake potassium mining area[J].Journal of Salt Lake Research,2021,29(3):1-8. | |
6 | 熊增华,王石军.中国钾资源开发利用技术及产业发展综述[J].矿产保护与利用,2020,40(6):1-7. |
XIONG Zenghua, WANG Shijun.Overview of potassium resources exploitation & utilization technology and potash industry development[J].Conservation and Utilization of Mineral Resources,2020,40(6):1-7. | |
7 | 李积升,魏明.柴达木盐湖化工产业关键技术研究[J].无机盐工业,2019,51(9):7-11. |
LI Jisheng, WEI Ming.Research on key technologies of chemical industry in Qaidam Salt Lake[J].Inorganic Chemicals Industry,2019,51(9):7-11. | |
8 | LI Ruiqin, LIU Chenglin, JIAO Pengcheng,et al.Simulation study on the mining conditions of dissolution of low grade solid potash ore in Qarhan Salt Lake[J].Scientific Reports,2021,11:10539. |
9 | 刘喜业,李勇刚,张兴儒,等.察尔汗盐湖表层低品位钾矿溶矿实验及数值模拟分析[J].无机盐工业,2014,46(8):18-20. |
LIU Xiye, LI Yonggang, ZHANG Xingru,et al.Dissolution experiment and numerical simulation on surface slat of Qarham Salt Lake[J].Inorganic Chemicals Industry,2014,46(8):18-20. | |
10 | 王文祥,李文鹏,安永会,等.察尔汗盐湖单级与增程驱动溶解固体钾矿试验对比研究[J].地质论评,2015,61(5):1177-1182. |
WANG Wenxiang, LI Wenpeng, AN Yonghui,et al.Research on comparision of one channel and multiple channel dissolving and driving solid potassium in qarhan salt lake[J].Geological Review,2015,61(5):1177-1182. | |
11 | 韩光,韩积斌,刘久波,等.开采背景下柴达木盆地东台吉乃尔盐湖氯化锂矿床变化特征[J].无机盐工业,2020,52(12):17-22. |
HAN Guang, HAN Jibin, LIU Jiubo,et al.Variation characteristics of LiCl deposit under condition of mining in East Taijnar Salt Lake,Qaidam Basin[J].Inorganic Chemicals Industry,2020, 52(12):17-22. | |
12 | 韩光,袁小龙,韩积斌,等.察尔汗盐湖霍布逊区段资源开采过程中储卤层系统变化特征研究[J].地球学报,2022,43(3):279-286. |
HAN Guang, YUAN Xiaolong, HAN Jibin,et al.Comparative analysis on the characteristic changes of the brine reservoir system before and after exploration of the qarhan salt lake(huobux-un area)[J].Acta Geoscientica Sinica,2022,43(3):279-286. | |
13 | 李梦玲,袁小龙,张西营,等.补水溶矿过程中达布逊湖北岸地下卤水水化学变化特征初步研究[J].盐湖研究,2022,30(2):99-109. |
LI Mengling, YUAN Xiaolong, ZHANG Xiying,et al.Preliminary study on the hydrochemical characteristics of underground brines during replenishing dissolved minerals on the north shore of dabson lake[J].Journal of Salt Lake Research,2022,30(2):99-109. | |
14 | 李瑞琴,刘成林,焦鹏程,等.现代盐湖低品位固体钾盐溶矿数值模拟研究:以察尔汗盐湖别勒滩矿区为例[J].地质学报,2021,95(7):2150-2159. |
LI Ruiqin, LIU Chenglin, JIAO Pengcheng,et al.Numerical simulation analysis on potash dissolution extraction from low-grade solid potash ore in modern salt lake:A case study from Bieletan mining area in the Qarhan salt lake[J].Acta Geologica Sinica,2021,95(7):2150-2159. | |
15 | 刘琦,冯振华,管川,等.钾石盐溶浸开采溶解实验研究[J].化工矿物与加工,2019,48(11):19-23. |
LIU Qi, FENG Zhenhua, GUAN Chuan,et al.Experimental study on solution of sylvinite leaching mining[J].Industrial Minerals & Processing,2019,48(11):19-23. | |
16 | 王朝旭,赵艳军,赵宪福,等.沉积特征对低品位钾矿水溶开采的影响:以柴达木盆地马海盐湖北部矿段全新统为例[J].岩石矿物学杂志,2022,41(5):929-940. |
WANG Zhaoxu, ZHAO Yanjun, ZHAO Xianfu,et al.Influence of sedimentary characteristics on water solution mining of low-grade potassium ore:A case study of Holocene in the northern ore section of Mahai Salt Lake,Qaidam Basin[J].Acta Petrologica et Mineralogica,2022,41(5):929-940. | |
17 | 高丹丹,李东东,樊燕飞,等.察尔汗盐湖铷资源利用:从基础认知到技术创新[J].盐湖研究,2022,30(3):1-11,41. |
GAO Dandan, LI Dongdong, FAN Yanfei,et al.Economically utilization of the rubidium resources in qarhan salt lake:From fundamental study to technology innovation[J].Journal of Salt Lake Research,2022,30(3):1-11,41. | |
18 | 王晓静,张明哲.低品位盐矿驱动溶采方案模拟研究[J].化工机械,2022,49(6):946-953. |
WANG Xiaojing, ZHANG Mingzhe.Simulation study on driving solution mining scheme for low-grade salt mine[J].Chemical Engineering & Machinery,2022,49(6):946-953. | |
19 | LI Wenpeng, LIU Zhenying.Numerical modelling of dissolving and driving exploitation of potash salt in the qarhan play a—a coupled model of reactive solute transport and chemical equilibrium in a multi-component:Underground brine system[J].Acta Geologica Sinica-English Edition,2008,82(5):1070-1082. |
20 | WEISBROD N, ALON-MORDISH C, KONEN E,et al.Dynamic dissolution of halite rock during flow of diluted saline solutions[J].Geophysical Research Letters,2012,39(9):L09404. |
21 | 常政,袁小龙,刘万平,等.察尔汗盐湖固体钾盐溶解对溶剂注入速率响应机制研究[J].地球学报,2022,43(3):287-294. |
CHANG Zheng, YUAN Xiaolong, LIU Wanping,et al.A study on the mechanism of influence of the dissolution of solid potassium salt in qarhan salt lake to the rate of solvent injection[J].Acta Geoscientica Sinica,2022,43(3):287-294. | |
22 | CHEN Kezao, BOWLER J M.Late Pleistocene evolution of salt lakes in the Qaidam Basin,Qinghai Province,China[J].Palaeogeography,Palaeoclimatology,Palaeoecology,1986,54(1/2/3/4):87-104. |
23 | 王石军.察尔汗盐湖钾镁盐矿床可采储量特征及其开采探讨[J].化工矿物与加工,2005,34(1):30-32. |
WANG Shijun.Discussion on characteristics of workable reserves of potassium and magnesium salt deposit in Chaerhan Salt Lake and its mining[J].Industrial Minerals and Processing,2005, 34(1):30-32. | |
24 | Casas E, Lowenstein T, Spencer R,et al.Carnallite mineralization in the nonmarine,Qaidam basin,China:Evidence for the early diagenetic origin of potash evaporites[J].SEPM Journal of Sedimentary Research,1992,62:881-898. |
25 | LOWENSTEIN T K, SPENCER R J, YANG Wenbo,et al.Major-element and stable-isotope geochemistry of fluid inclusions in halite,Qaidam Basin,Western China:Implications for late Pleistocene/Holocene brine evolution and paleoclimates[M]//Geological Society of America Special Papers,Geological Society of America,1994,289:19-32. |
26 | 王盼盼,刘鲤君,金世红,等.察尔汗盐湖溶矿研究进展[J].中国资源综合利用,2021,39(9):110-112. |
WANG Panpan, LIU Lijun, JIN Shihong,et al.Research progress on mine salt dissolution in qarhan salt lake[J].China Resources Comprehensive Utilization,2021,39(9):110-112. | |
27 | 常政.柴达木盆地察尔汗盐湖浅部储卤层渗流-溶解室内模拟实验研究[D].西宁:中国科学院大学(中国科学院青海盐湖研究所),2022. |
CHANG Zheng.Indoor simulation experiment research on seepage-dissolution of shallow brine reservoirs in the qarhan salt lake,Qaidam basin[D].Xining:Qinghai Institute of Salt Lakes,Chinese Academy of Sciences,2022. | |
28 | 袁小龙,张西营,盛金昌,等.环境温度对盐湖卤水化学组成及储卤层渗透性变化的制约[J].地质学报,2018,92(8):1724-1732. |
YUAN Xiaolong, ZHANG Xiying, SHENG Jinchang,et al.Constraint of environmental temperature on chemical composition of brine and permeability of aquifer in the saline lake[J].Acta Geologica Sinica,2018,92(8):1724-1732. | |
29 | 王兴富,王石军,王罗海,等.柴达木低品位固体钾矿溶解转化率与品位关系[J].盐湖研究,2020,28(3):61-65. |
WANG Xingfu, WANG Shijun, WANG Luohai,et al.Relationship of conversion rate with solid potash content for Qaidam low-grade solid potash[J].Journal of Salt Lake Research,2020,28(3):61-65. | |
30 | 王兴富,王石军,王罗海,等.柴达木低品位固体钾矿溶解转化实验及应用前景[J].化工矿产地质,2019,41(4):299-305. |
WANG Xingfu, WANG Shijun, WANG Luohai,et al.Dissolution and transformation experiment of low-grade solid potash for Qaidam and its application prospect[J].Geology of Chemical Minerals,2019,41(4):299-305. | |
31 | 张萍.察尔汗盐湖铁路以东固体钾矿溶采试验研究[J].化工矿物与加工,2014,43(7):43-45. |
ZHANG Ping.Tests of solution mining in solid potash mine east of rail line,Qarhan Salt Lake[J].Industrial Minerals & Processing,2014,43(7):43-45. | |
32 | 赵有璟,王敏,李锦丽,等.察尔汗盐湖铁路以东固体钾矿的溶采试验[J].应用化工,2016,45(2):260-264. |
ZHAO Youjing, WANG Min, LI Jinli,et al.Dissolving exploitation of solid potassium deposit east of Qarhan Salt Lake rail-way[J].Applied Chemical Industry,2016,45(2):260-264. | |
33 | 张兆广,祁燕.察尔汗盐湖低品位卤水自然蒸发试验研究[J].盐湖研究,2006,14(1):17-23. |
ZHANG Zhaoguang, QI Yan.Study on the natural evaporation of low grade brines from chaerhan salt lake[J].Journal of Salt Lake Research,2006,14(1):17-23. | |
34 | 姜旭,周保华,乜贞.中国盐湖卤水蒸发实验研究进展[J].无机盐工业,2013,45(6):1-3,32. |
JIANG Xu, ZHOU Baohua, NIE Zhen.Experimental research progress in evaporation of salt lake brine[J].Inorganic Chemicals Industry,2013,45(6):1-3,32. | |
35 | 吴文辉,徐世光,杨玲.老挝万象钾盐矿水溶开采室内试验研究[J].中国井矿盐,2023,54(1):7-10. |
WU Wenhui, XU Shiguang, YANG Ling.Laboratory test study on solution mining of Vientiane potash mine in Laos[J].China Well and Rock Salt,2023,54(1):7-10. | |
36 | 王石军,王兴富.盐湖固体钾矿溶解转化溶剂组成对资源开发的影响[J].化工矿物与加工,2013,42(4):20-24. |
WANG Shijun, WANG Xingfu.Influence of solvent composition on dissolving solid potassium deposits of Chaerhan Salt Lake[J].Industrial Minerals & Processing,2013,42(4):20-24. | |
49 | 董继发,康鹏鹏,卢昌,等.湿法磷酸净化萃余酸在磷矿反浮选中的应用研究[J].磷肥与复肥,2023,38(4):31-32,39. |
DONG Jifa, KANG Pengpeng, LU Chang,et al.Application of raffinate acid from wet-process phosphoric acid purification apparatus in reverse flotation of phosphate rock[J].Phosphate & Compound Fertilizer,2023,38(4):31-32,39. | |
50 | 李文飞,郭举,张丹,等.一种利用萃余磷酸制备铝合金表面化学抛光液的方法:中国,201410074130.X[P].2014-06-11. |
51 | 韦昌桃,王智娟,赵彤.精制磷酸副产萃余酸的应用现状及建议[J].云南化工,2023,50(3):8-13. |
WEI Changtao, WANG Zhijuan, ZHAO Tong.Application situation and suggestion for raffinate acid by-product in the process of phosphoric acid extraction[J].Yunnan Chemical Technology,2023,50(3):8-13. | |
52 | 舒艺周,马航,匡家灵,等.湿法磷酸萃余酸用于肥料制备的研究综述[J].磷肥与复肥,2022,37(11):19-21,24. |
SHU Yizhou, MA Hang, KAUANG Jialing,et al.Review on application of raffinate acid from WPA purification in fertilizer preparation[J].Phosphate & Compound Fertilizer,2022,37(11):19-21,24. |
[1] | DING Xiaojiang, WU Yanni, LI Boyun, HUANG Youliang. Research on preparation of carnallite concentrate by pretreatment combined with reverse flotation [J]. Inorganic Chemicals Industry, 2024, 56(12): 113-119. |
[2] | ZHU Jian, DONG Guangfeng, CHEN Peng, JIA Feifei, MA Songliang, LIU Zhongjian, XIANG Xiaocheng. Study on influence mechanism of particle size composition of potassium mixed salt on its conversion flotation [J]. Inorganic Chemicals Industry, 2024, 56(10): 64-69. |
[3] | ZOU Yang, LU Zhiyan, HU Zhilin, SUN Ze. Study on metastable zone width and primary nucleation kinetics for cooling crystallization of KNO3 [J]. Inorganic Chemicals Industry, 2024, 56(9): 67-74. |
[4] | CHENG Chunchun, LI Yulong, ZHANG Zhiqiang, LIU Xuejing. Study on dissolution crystallization for extraction of potassium and separation of magnesium and lithium from salt lake brine [J]. Inorganic Chemicals Industry, 2024, 56(6): 34-39. |
[5] | CHEN Junhui, LIU Xiang, HU Qingxi, TIAN Bangxin, CHEN Jiale. Study on leaching extraction of high purity potassium chloride from sintering machine head ash [J]. Inorganic Chemicals Industry, 2024, 56(6): 102-108. |
[6] | YANG Hongjun, WANG Min, GE Haiwen, QIAO Youmin, QIAO Ziyang. Study on recycling process of potassium from calcium aluminate fly ash [J]. Inorganic Chemicals Industry, 2023, 55(10): 121-127. |
[7] | JIN Yinghao, WANG Siyuan, YU Xuefeng, WANG Jinjing, WEI Zhengying, LIU Liwu, TIAN Haifeng, ZHA Fei. Recombination and application on mixed amine collector(cationic/anionic) for KCl flotation [J]. Inorganic Chemicals Industry, 2023, 55(10): 93-99. |
[8] | DENG Wenqing,ZHU Jing,FAN Xiaojuan,CHEN Yan,LI Tianxiang. Phase equilibria of ternary system of KH2PO4-(NH2)2CO-H2O at 313.15 K [J]. Inorganic Chemicals Industry, 2023, 55(1): 100-105. |
[9] | DU Bingxuan,LI Haichao,LIN Zezhong. Study on preparation of food?grade potassium chloride by one?step adsorption and purification [J]. Inorganic Chemicals Industry, 2022, 54(9): 96-101. |
[10] | TAN Huiting,SUN Wei,CUI Yuzhao,WEI Qianqian,LI Tengsheng,YAN Dongyun. Present situation of potash resources and analysis of development and application of polyhalite [J]. Inorganic Chemicals Industry, 2022, 54(6): 23-30. |
[11] | DU Jingling,DONG Weibing,QIE Zhijia,MA Shengkui,TIAN Hongbin,WANG Gang. Study on effect of trisodium citrate on particle size of potassium chloride crystal prepared by decomposition of low sodium carnallite [J]. Inorganic Chemicals Industry, 2022, 54(4): 112-118. |
[12] | Zhang Tianliang,Li Jun,Xiong Wei,Zhang Haiyan,Tao Xiaoqiu. Study on one-step preparation of activated carbon with high specific surface by K2CO3 activation and its capacitance performance [J]. Inorganic Chemicals Industry, 2022, 54(4): 159-164. |
[13] | ZHANG Huanhuan,CHENG Zhuo,TANG Xiuhua,ZHANG Fengzhen. Determination and correlation of solubility of potassium dihydrogen phosphate in acetonitrile-water solvent [J]. Inorganic Chemicals Industry, 2022, 54(1): 83-85. |
[14] | Xiong Jiaqing,Zhang Yu,Zhu Junguo. Study on process of producing low-sodium carhalite by double brine mixing method [J]. Inorganic Chemicals Industry, 2021, 53(8): 44-49. |
[15] | Wan Junfeng,Dong Weibing,Chen Xulong,Du Jingling,Wang Gang. Coalescence crystallization of large particle KCl and its particle size control [J]. Inorganic Chemicals Industry, 2021, 53(8): 50-54. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||
|
Copyright © 2021 Editorial Office of Inorganic Chemicals Industry
Add:No.3 Road Dingzigu,Hongqiao District,Tianjin,China
E-mail:book@wjygy.com.cn 违法和不良信息举报电话: 022-26689297