Zn/Co-ZIF衍生多孔碳钯基催化剂的制备及在甲酸制氢中的应用

doi:10.19964/j.issn.1006-4990.2023-0517

Abstract

Abstract:

Highly active Ag₁Pd₇@HPNC catalyst were obtained through anchoring Ag and Pd on Zn/Co-ZIF derived nitrogen-doped porous carbon（HPNC），which was obtained by HNO₃immersion and（NH₄）₂HPO₄ phosphating.Zn/Co-ZIF，porous carbon supports and prepared catalysts were characterized and systematically analyzed by a series of characterization methods such as XRD，TEM，SEM and EDS，etc.The results showed that Zn and most of Co species in porous carbon could be effectively removed by high-temperature sintering and acidification treatment，and small-size Pd and Ag nanoparticles could be efficiently loaded on the surface of HPNC porous carbon carriers.By exploring the effects of different catalyst supports and different m_Ag∶m_Pd on the catalyst catalysts，it was demonstrated that the Ag₁Pd₇@HPNC catalysts had excellent formic acid catalytic activity.The formic acid dehydrogenation experiment showed that the catalytic activity of Pd@HPNC treated by（NH₄）₂HPO₄ was superior to that of untreated Pd@HNC catalyst，and the catalytic activity of Ag _x Pd _y @HPNC （x>0） prepared by doping Ag species had been further improved.When the mass ratio of m_Ag∶m_Pd=1∶7，the catalytic activity of Ag₁Pd₇@HPNC for formic acid decomposition was optimal with a turnover frequency（TOF） of 1 025 h^-1for formic acid at 318 K，and the catalyst was recycled for five times with the TOF value of 920 h^-1，indicating its good recycling stability.Ag₁Pd₇@HPNC showed a good application prospect to formic acid dehydrogenation.

Key words: formic acid, hydrogen production, ZIF, Pd catalyst, porous carbon

CLC Number:

TQ132.41

LIU Qingcui, LI Yunqing, PANG Ruiqi, TIAN Yaping, CHEN Yiying, LI Fang, LI Qiming. Preparation of Zn/Co-ZIF derived porous carbon supported Pd as catalyst and its application to formic acid dehydrogenation[J]. Inorganic Chemicals Industry, 2024, 56(6): 147-152.

Figures/Tables 7

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Preparation of Zn/Co-ZIF derived porous carbon supported Pd as catalyst and its application to formic acid dehydrogenation

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