半导体核壳材料光催化剂分解水制氢研究进展

doi:10.19964/j.issn.1006-4990.2022-0187

Abstract

Abstract:

Photocatalytic decomposition of water to hydrogen is a green way to effectively convert solar energy to hydrogen energy.Among them，semiconductor core-shell photocatalyst shows excellent performance in solar decomposition of water to hydrogen.From the perspective of semiconductor material modification，the latest research progress of hydrogen production from water decomposition by semiconductor core-shell photocatalyst at home and abroad was reviewed and commented.The basic principles and modification effects of common oxides，nitrogen oxides，nitrides and sulfide core-shell semiconductor photocatalysts in hydrogen production from water decomposition were emphatically expounded.The effects of modification methods such as doping ions，constructing heterojunctions and loading co-catalysts on changing the band gap of photocatalyst，reducing the recombination probability of photogenerated carriers，accelerating the transmission rate of photogenerated charges and increasing the active sites of hydrogen production were analyzed.It was proposed that the future research direction of hydrogen production from water decomposition photocatalyst could be further developed for crystal-plane-dependent nano-composite photocatalytic materials，auxiliary-modified photocatalytic materials and new photocatalytic semiconductor materials.

Key words: semiconductor, core-shell structure, photochemical catalysis, hydrogen production

CLC Number:

O643.36

LI Liangrong, YANG Xiaozhe, CHEN Chuxin, LIU Yan, ZHANG Mengling, DING Yonghong. Research progress of photocatalytic water splitting of semiconductor core-shell materials for hydrogen production[J]. Inorganic Chemicals Industry, 2023, 55(3): 10-20.

Figures/Tables 6

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Table 1

References 50

1	李建林，梁忠豪，李光辉，等.太阳能制氢关键技术研究[J].太阳能学报，2022，43（3）:2-11.
	LI Jianlin， LIANG Zhonghao， LI Guanghui，et al.Analysis of key technologies for solar hydrogen production[J].Acta Energiae Solaris Sinica，2022，43（3）:2-11.
2	王惠娟，王春玉，张琼.二维层状纳米片材料制备及在电解水中应用的研究进展[J].无机盐工业，2021，53（11）:25-29， 41.
	WANG Huijuan， WANG Chunyu， ZHANG Qiong.Research progress on the preparation of two-dimensional layered nanosheet materials and its application in electrolyzed water[J].Inorganic Che-micals Industry，2021，53（11）:25-29，41.
3	李亮荣，付兵，刘艳，等.生物质衍生物重整制氢研究进展[J].无机盐工业，2021，53（9）:12-17.
	LI Liangrong， FU Bing， LIU Yan，et al.Research progress of hydrogen production by reforming biomass-derived compounds[J].Inorganic Chemicals Industry，2021，53（9）:12-17.
4	完颜永劲.半导体-金属异质结构提高光催化有机合成性质研究[D].厦门:厦门大学，2018.
	WANYAN Yongjin.Constructing metal-semiconductor heterojunction-based catalysts to promote photocatalytic organic syntheses[D].Xiamen:Xiamen University，2018.
5	丁宁.以ZnIn₂S₄及C₃N₄为主的异质结构光催化剂的构建与性质研究[D].北京:中国科学院大学（中国科学院物理研究所），2018.
	DING Ning.The constructing and characteristic study of heterostructure photocatalyst based on ZnIn₂S₄ and C₃N₄ [D].Beijing:Institute of Physics，Chinese Academy of Sciences，2018.
6	NIU Bo， XU Zhenming.A stable Ta₃N₅@PANI core-shell photocatalyst:Shell thickness effect，high-efficient photocatalytic performance and enhanced mechanism[J].Journal of Catalysis，2019，371:175-184.
7	RAVI P， NAVAKOTESWARA RAO V， Shankar M V，et al.CuO@NiO core-shell nanoparticles decorated anatase TiO₂ nanospheres for enhanced photocatalytic hydrogen production[J].International Journal of Hydrogen Energy，2020，45（13）:7517-7529.
8	NAVAKOTESWARA RAO V， RAVI P， SATHISH M，et al.Metal chalcogenide-based core/shell photocatalysts for solar hydrogen production:Recent advances，properties and technology challen-ges[J].Journal of Hazardous Materials，2021，415.Doi:10.1016/j.jhazmat.2021.125588.
9	王健.ZnO纳米材料及核壳结构的制备和光催化性能研究[D].北京:中国科学院研究生院（长春光学精密机械与物理研究所），2016.
	WANG Jian.Synthesis and photocatalytic properties research of ZnO nanomaterials and core-shell structure[D].Beijing:Institute of Physics，Chinese Academy of Sciences，2016.
10	郭思瑶.新型光催化材料的形貌调控及其光解水制氢性能研究[D].武汉:华中科技大学，2014.
	GUO Siyao.Study on the morphology control of novel photocatalyst and their photocatalytic hydrogen production[D].Wuhan:Huazhong University of Science and Technology，2014.
11	SCHNEIDER J J.Magnetic core/shell and quantum-confined semi-conductor nanoparticles via Chimie douce organometallic synthesis[J].Advanced Materials，2001，13（7）:529-533.
12	陈彩选，黄浪欢，刘应亮.核壳结构TiO₂光催化剂的制备和性能[J].功能材料，2006，37（9）:1358-1361.
	CHEN Caixuan， HUANG Langhuan， LIU Yingliang.The preparation，properties of core-shell structure titania composite nanoparticles[J].Journal of Functional Materials，2006，37（9）:1358-1361.
13	李雷，李彦兴，姚瑶，等.核壳结构纳米材料的创制及在催化化学中的应用[J].化学进展，2013，25（10）:1681-1690.
	LI Lei， LI Yanxing， YAO Yao，et al.Progress and prospective in fabrication and application of core-shell structured nanomaterials in catalytic chemistry[J].Progress in Chemistry，2013，25（10）:1681-1690.
14	MADHUMITHA A， PREETHI V， KANMANI S.Photocatalytic hydrogen production using TiO₂ coated iron-oxide core shell particles[J].International Journal of Hydrogen Energy，2018，43（8）:3946-3956.
15	郭丽君，李瑞，刘建新，等.半导体光催化分解水的析氢效率研究[J].化学进展，2020，32（1）:46-54.
	GUO Lijun， LI Rui， LIU Jianxin，et al.Study on hydrogen evolution efficiency of semiconductor photocatalysts for solar water splitting[J].Progress in Chemistry，2020，32（1）:46-54.
16	FUJISHIMA A， HONDA K.Electrochemical photolysis of water at a semiconductor electrode[J].Nature，1972，238（5358）:37-38.
17	CHAKRABORTY M， ROY D， BISWAS A，et al.Structural，optical and photo-electrochemical properties of hydrothermally grown ZnO nanorods arrays covered with α-Fe₂O₃ nanoparticles[J].RSC Advances，2016，6（79）:75063-75072.
18	WANG Sheng， ZHU Bicheng， LIU Mingjin，et al.Direct Z-scheme ZnO/CdS hierarchical photocatalyst for enhanced photocatalytic H₂-production activity[J].Applied Catalysis B:Environmental，2019，243:19-26.
19	CHEN Yang， MAO Guobing， TANG Yawen，et al.Synthesis of core-shell nanostructured Cr₂O₃/C@TiO₂ for photocatalytic hydrogen production[J].Chinese Journal of Catalysis，2021，42（1）:225-234.
20	刘兵，宫辉力，刘锐，等.二氧化钛包裹金纳米棒核壳材料的制备及其光解水制氢[J].应用化学，2019，36（8）:939-948.
	LIU Bing， GONG Huili， LIU Rui，et al.Synthesis of TiO₂ coated gold nanorod with core-shell structure and its photocatalytic hydrogen evolution[J].Chinese Journal of Applied Chemistry，2019，36（8）:939-948.
21	余岩.基于钛基半导体的异质结光催化制氢[D].杭州:浙江工业大学，2019.
	YU Yan.Heterostructure based on titanium-based semiconductor for hydrogen generation[D].Hangzhou:Zhejiang University of Technology，2019.
22	DANESHVAR N， SALARI D， KHATAEE A R.Photocatalytic degradation of azo dye acid red 14 in water on ZnO as an alternative catalyst to TiO₂[J].Journal of Photochemistry and Photobiology A:Chemistry，2004，162（2/3）:317-322.
23	HE Shan， ZHANG Shitong， LU Jun，et al.Enhancement of visible light photocatalysis by grafting ZnO nanoplatelets with exposed （0001） facets onto a hierarchical substrate[J].Chemical Communications，2011，47（38）:10797-10799.
24	冯彩丽，孙建兴，段军红.三角和六角对称ZnO分支纳米结构及其光学特性研究[J].南昌航空大学学报:自然科学版，2015，29（2）:51-56.
	FENG Caili， SUN Jianxing， DUAN Junhong.Research on optical properties of triangular and hexagonal symmetry ZnO nanostructures[J].Journal of Nanchang Hangkong University:Natural Sciences，2015，29（2）:51-56.
25	SON N，DO J Y， KANG M.Characterization of core@shell-structured ZnO@Sb₂S₃ particles for effective hydrogen production from water photo spitting[J].Ceramics International，2017，43（14）:11250-11259.
26	YANG Xinying， LIU Haixia， LI Tianduo，et al.Preparation of flower-like ZnO@ZnS core-shell structure enhances photocatalytic hydrogen production[J].International Journal of Hydrogen Energy，2020，45（51）:26967-26978.
27	李燕瑞.基于半导体异质结构的光催化剂设计、合成及性质研究[D].合肥:中国科学技术大学，2017.
	LI Yanrui.Design，synthesis and properties of photocatalysts based on semiconductor heterostructures[D].Hefei:University of Science and Technology of China，2017.
28	YE Lin， WEN Zhenhai.ZnIn₂S₄ nanosheets decorating WO₃ nanorods core-shell hybrids for boosting visible-light photocatalysis hydrogen generation[J].International Journal of Hydrogen Energy，2019，44（7）:3751-3759.
29	Wei OU， PAN Jiaqi， LIU Yanyan，et al.Two-dimensional ultrathin MoS₂-modified black Ti³⁺-TiO₂ nanotubes for enhanced photocatalytic water splitting hydrogen production[J].Journal of Energy Chemistry，2020，43:188-194.
30	WANG Meng， LIU Hongxia， MA Jiantai，et al.The activity enhancement of photocatalytic water splitting by F^- pre-occupation on Pt（100） and Pt（111） co-catalyst facets[J].Applied Catalysis B:Environmental，2020，266.Doi:10.1016/j.apcatb.2020.118647.
31	MAHZOON S， HAGHIGHI M， NOWEE S M.Sonoprecipitation fabrication of enhanced electron transfer Cu（OH）₂/g-C₃N₄ nanophotocatalyst with promoted H₂-production activity under visible light irradiation[J].Renewable Energy，2020，150:91-100.
32	ZHANG Wei， ZHANG Hongwen， XU Jianzhong，et al.3D flower-like heterostructured TiO₂@Ni（OH）₂ microspheres for solar photocatalytic hydrogen production[J].Chinese Journal of Catalysis，2019，40（3）:320-325.
33	PAN Jiaqi， LIU Yanyan，Wei OU，et al.The photocatalytic hydrogen evolution enhancement of the MoS₂ lamellas modified g-C₃N₄/SrTiO₃ core-shell heterojunction[J].Renewable Energy，2020，161:340-349.
34	王鑫，薛冬峰.定向转化策略创制氮氧化物光催化剂[J].无机盐工业，2022，54（3）:1-6.
	WANG Xin， XUE Dongfeng.Preparation of oxynitrides photocatalysts by the oriented transformation strategy[J].Inorganic Chemicals Industry，2022，54（3）:1-6.
35	XIAO Mu， WANG Songcan， THAWEESAK Supphasin，et al.Tantalum（oxy）nitride:Narrow bandgap photocatalysts for solar hydrogen generation[J].Engineering，2017，3（3）:365-378.
36	张微.Rh修饰的核壳异质结构氮（氧）化钽光催化析氢材料研究[D].哈尔滨:哈尔滨师范大学，2018.
	ZHANG Wei.Study on Rh-modified core-shell heterostructure tantalum nitride for photocatalytic hydrogen evolution[D].Harbin:Harbin Normal University，2018.
37	WANG Xin， HISATOMI T， WANG Zheng，et al.Core-shell-structured LaTaON₂ transformed from LaKNaTaO₅ plates for enhanc-ed photocatalytic H₂ evolution[J].Angewandte Chemie，2019，58（31）:10666-10670.
38	PENG Zhiyuan， JIANG Yinhua， XIAO Yan，et al.CdIn₂S₄ surface-decorated Ta₃N₅ core-shell heterostructure for improved spatial charge transfer:In-situ growth，synergistic effect and efficient dual-functional photocatalytic performance[J].Applied Surface Science，2019，487:1084-1095.
39	XIAO Yan， ZHANG Wenli， XING Qingzeng，et al.Eco-friendly synthesis of core/shell ZnIn₂S₄/Ta₃N₅ heterojunction for strengthened dual-functional photocatalytic performance[J].Internatio-nal Journal of Hydrogen Energy，2020，45（55）:30341-30356.
40	齐跃红.g-C₃N₄基复合光催化剂的制备及其活性研究[D].唐山:华北理工大学，2016.
	QI Yuehong.The preparation and photocatalytic activity of g-C₃N₄ composition materials[D].Tangshan:North China University of Science and Technology，2016.
41	SHEN Rongchen， HE Kelin， ZHANG Aiping，et al.In-situ construction of metallic Ni₃C@Ni core-shell cocatalysts over g-C₃N₄ nanosheets for shell-thickness-dependent photocatalytic H₂ production[J].Applied Catalysis B:Environmental，2021，291.Doi:10.1016/j.apcatb.2021.120104.
42	LIU Li， QI Yuehong， HU Jinshan，et al.Efficient visible-light photocatalytic hydrogen evolution and enhanced photostability of core@shell Cu₂O@g-C₃N₄ octahedra[J].Applied Surface Science，2015，351:1146-1154.
43	LIAN Zhongqin， LIU Yichen， LIU Hong，et al.Fabrication of CdS@1T-MoS₂ core-shell nanostructure for enhanced visible-light-driven photocatalytic H₂ evolution from water splitting[J].Journal of the Taiwan Institute of Chemical Engineers，2019，105:57-64.
44	FANG Xueyou， CUI Lifeng， PU Tingting，et al.Core-shell CdS@MnS nanorods as highly efficient photocatalysts for visible light driven hydrogen evolution[J].Applied Surface Science，2018，457:863-869.
45	WANG Panhong， PAN Jiaqi， YU Qi，et al.The enhanced photocatalytic hydrogen production of the non-noble metal co-catalyst Mo₂C/CdS hollow core-shell composite with CdMoO₄ transition layer[J].Applied Surface Science，2020，508.Doi:10.1016/j.apsusc.2019.145203.
46	ZHOU Xiaopeng， ZHANG Ning， YIN Linxin.Few-layered WS₂ nanosheets onto 1D CdS@ZnCdS as efficient visible-light photocatalyst for hydrogen evolution[J].Ceramics International，2020，46（16）:26100-26108.
47	朱乔虹，邢明阳，张金龙.光催化分解水制氢中硫化物空心结构的研究进展[J].化工进展，2021，40（9）:4774-4781.
	ZHU Qiaohong， XING Mingyang， ZHANG Jinlong.Progress of hollow-structured-based sulfides in photocatalytic water splitting for hydrogen production[J].Chemical Industry and Engineering Progress，2021，40（9）:4774-4781.
48	NAVAKOTESWARA RAO V， RAVI P， SATHISH M，et al.Monodispersed core/shell nanospheres of ZnS/NiO with enhanced H₂ generation and quantum efficiency at versatile photocatalytic conditions[J].Journal of Hazardous Materials，2021，413.Doi:10.1016/j.jhazmat2021.125359.
49	LI Songsong， DAI Dongsheng， GE Lei，et al.Synthesis of layer-like Ni（OH）₂ decorated ZnIn₂S₄ sub-microspheres with enhanced visible-light photocatalytic hydrogen production activity[J].Dalton Transactions，2017，46（32）:10620-10629.
50	GUO Feng， HUANG Xiliu， CHEN Zhihao，et al.Formation of unique hollow ZnSnO₃@ZnIn₂S₄ core-shell heterojunction to boost visible-light-driven photocatalytic water splitting for hydrogen production[J].Journal of Colloid and Interface Science，2021，602:889-897.

类型	种类	吸收边/ nm	优点	产氢速率/ （μmol·g^-1·h^-1）
氧化物核壳材料^[16-33]	Cr₂O₃/C@TiO₂	520	禁带宽度窄，对可见光响应更敏感；比表面积大，制氢活性位点多	446.00
	GNR@TiO₂	750		31.00
	ZnO@ZnS	390		126.18
	WO₃@ZnIn₂S₄	500		3 900.00
	MoS₂/SrTiO₃@g-C₃N₄	450		1 647.41
氮氧化物核壳材料^[34-37]	Rh₂O₃/Ta₂O₅@TaON	550	有效抑制光生载流子复合，延长光生电荷使用寿命	39.41
氮氧化物核壳材料^[34-37]	LaKNaTaO₅@LaTaON₂	620	有效抑制光生载流子复合，延长光生电荷使用寿命	~106.67
氮化物核壳材料^[38-42]	Ta₃N₅@ZnIn₂S₄	572	不易光腐蚀，光稳定性强可循环利用，电荷传输性能高，光生电荷分离快	834.86
氮化物核壳材料^[38-42]	Cu₂O@g-C₃N₄	470 530	不易光腐蚀，光稳定性强可循环利用，电荷传输性能高，光生电荷分离快	265
硫化物核壳材料^[43-50]	WS₂/CdS@ZCS	535	捕获和利用光能力强，不易光腐蚀，稳定性强，光催化产氢效率高	34 860.00
	ZnS@NiO	370		162 100.00
	ZnSnO₃@ZnIn₂S₄	500		16 340.18

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Research progress of photocatalytic water splitting of semiconductor core-shell materials for hydrogen production

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