无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2012, Vol. 44 ›› Issue (1): 37-.

• 论文 • 上一篇    下一篇

用液相组成研究昆特依盐湖光卤石矿分解

朱建荣1,2,肖学英1,张志宏1,董生发1,马艳芳1,张永峰1,2,杜建宁3   

  1. 1.中国科学院青海盐湖研究所,青海西宁 810008;2.中国科学院研究生院;3.冷湖滨地钾肥有限责任公司
  • 出版日期:2012-01-10 发布日期:2012-01-16

Study on carnallite decomposition of Kunteyi Salt Lake through analysis of components in liquid phase

Zhu Jianrong1,2,Xiao Xueying1,Zhang Zhihong1,Dong Shengfa1,Ma Yanfang1,Zhang Yongfeng1,2,Du Jianning3   

  1. 1.Qinghai Institute of Salt Lakes,Chinese Academy of Sciences,Xining 810008,China;2.Graduate University,Chinese Academy of Sciences;3.Lenghu Bindi Postash Co.,Ltd.
  • Published:2012-01-10 Online:2012-01-16

摘要: 昆特依盐湖卤水属于硫酸镁亚型,利用昆特依盐湖卤水晒制的光卤石矿含有硫酸镁,硫酸镁影响光卤石矿加水分解过程,因此研究此类光卤石加水分解过程是很必要的。研究此光卤石矿物分解最直观的指标为,以光卤石完全分解为最佳。采用矿物恒温冷分解的实验方法,利用液相组分对共存固相进行分析,通过分析分解液相中钾离子和镁离子含量、固相中镁和硫酸根物质的量比及相图4种互相关联的指标,从而得到一种准确简便地确定光卤石矿分解条件的方法,这种方法指出利用液相中镁离子或钾离子作为判断指标是可行且合理可靠的。通过本方法获得最佳加水量和分解时间。

关键词: 光卤石, 分解, 加水量

Abstract: Brine in Kunteyi Salt Lake belongs to Sub-type magnesium sulfate,and carnallite made from Kunteyi Salt Lake brine contains magnesium sulfate,which affects the process of decomposition of carnallite by adding water.Therefore,it is very necessary to research decomposition process of this kind of carnallite.Most intuitive index for carnallite decomposition is completely decomposition of carnallite.Taking mineral-thermostatic-cold-decomposition experimental method,using analysis of components in liquid phase and it′s coexisting solid phase,and through the analysis of four interrelated indexes that contents of K+ and Mg2+in the liquid,amount-of-substance ratio of Mg2+ and SO2-4 in solid phase and phase diagram,an accurate,and convenient method for making sure the conditions of carnallite decomposition was obtained.This method pointed out that the use of Mg2+ or K+ in liquid phase as judging-index is reasonable,reliable,and practicable.By this method the best amount of water-adding,and the most reasonable resolving-time could be achieved.

Key words: carnallite, decomposition;water-adding quantity

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