氮化硼纳米片的制备及其在电解水中应用的研究进展

doi:10.19964/j.issn.1006-4990.2025-0073

摘要/Abstract

摘要：

氢能源一直被认为是化石能源最有潜力的替代者。电解水制氢是一种简单有效的方法，但其中涉及的析氢和析氧反应均为缓慢的动力学过程，这严重阻碍了电解水制氢的商业化应用，因此开发低成本、高效、稳定的催化剂来提升电解水的效率是当前迫切需要解决的问题。氮化硼纳米片因其具有独特的二维结构、优异的抗氧化性、热稳定性、宽带隙等特点，使其在电解水析氢和析氧反应中表现出优异的电催化活性。因此，氮化硼纳米片在电解水领域中有着广阔的应用前景。论文综述了近些年国内外氮化硼纳米片的主要制备方法，包括机械剥离法、化学剥离法和化学气相沉积，并分析了这些方法的优缺点。同时，还综述了氮化硼纳米片在电解水领域中应用的研究进展，包括析氢反应和析氧反应。最后，对氮化硼纳米片在制备方法和电解水领域的未来发展趋势进行了展望。

关键词: 氮化硼纳米片, 电催化剂, 析氢反应, 析氧反应

Abstract:

Hydrogen energy is considered to be one of the most potential alternative energy sources for fossil energy.Hydrogen production by electrolysis of water is a simple and effective method，but the hydrogen evolution reaction（HER） and oxygen evolution reactions（OER） involved in this process are slow kinetic reactions which seriously hindering the commercialization of hydrogen production by water electrolysis.Therefore，the development of low-cost，efficient and stable catalysts to improve the efficiency of the water electrolysis process is an urgent problem to be solved.Boron nitride nanosheets（BNNSs） have shown excellent catalytic activity in the electrochemical hydrogen and oxygen evolution，due to their unique two-dimensional structure，excellent oxidation resistance，thermal stability and wide gap.Therefore，BNNSs showed broad application prospect in the field of water splitting.The main preparation methods of BNNSs at home and abroad in recent years were reviewed，including mechanical stripping，chemical exfoliation and chemical vapor deposition，and their advantages and disadvantages were analyzed.In addition，the application of BNNSs in water electrolysis was reviewed，including HER and OER.Finally，the current problem and solution were summarized and the future research direction was prospected.

Key words: boron nitride nanosheets, electrocatalyst, hydrogen evolution reaction, oxygen evolution reaction

中图分类号:

TQ128.1

杜淼, 刘琦, 王佳仪, 董浩然, 牛静, 黄馨仪, 殷九洲, 于长江. 氮化硼纳米片的制备及其在电解水中应用的研究进展[J]. 无机盐工业, 2025, 57(9): 13-20.

DU Miao, LIU Qi, WANG Jiayi, DONG Haoran, NIU Jing, HUANG Xinyi, YIN Jiuzhou, YU Changjiang. Research progress on preparation of boron nitride nanosheets and its application in water electrolysis[J]. Inorganic Chemicals Industry, 2025, 57(9): 13-20.

图/表 5

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