无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (11): 17-.

• 论文 • 上一篇    下一篇

温度梯度下湿法磷酸合成工业磷酸一铵研究

何宾宾1,2,张 晖1,王孟来1,2,李小双1,2,方世祥1,2,傅 英1   

  1. 1.云天化集团云南磷化集团有限公司,云南昆明 650113;2.国家磷资源开发利用工程技术研究中心
  • 出版日期:2014-11-10 发布日期:2014-11-13

Study on production of industrial MAP by purification of wet-process phosphoric acid at temperature gradient

He Binbin1,2,Zhang Hui1,Wang Menglai1,2,Li Xiaoshuang1,2,Fang Shixiang1,2,Fu Ying1   

  1. 1.Yunnan Phosphate Chemical Group Co.Ltd,Kunming 650113,China;2.National Engineering and Technology
    Center for the Development & Utilization of Phosphorous Resources
  • Published:2014-11-10 Online:2014-11-13

摘要: 以湿法磷酸净化连续生产工业级磷酸一铵新工艺为背景,以五氧化二磷质量分数为20%的湿法磷酸为原料,钡盐为脱硫剂,碳酸钾为脱氟剂,二氧化硅为助剂,采用化学沉淀法一次性除硫脱氟预处理,脱硫率及脱氟率分别为83%和87.82%,再通过连续2次的氨中和、连续双效浓缩、连续结晶,制备得到工业级磷酸一铵。合成的工业磷酸一铵的化学组成(质量分数):N,11.85%、P2O5,59.62%、NH4H2PO4,96.68%、F-,0.17%、SO42-,0.64%,达到了工业级磷酸一铵优等品标准(GB 10205—2009《磷酸一铵、磷酸二铵》)。

关键词: 脱氟, 脱硫, 工业磷酸一铵

Abstract: Taking the new continuous production technology of  industrial monoammonium phosphate(MAP) by the purification of wet-process phosphoric acid as the background,with 20%(mass fraction) P2O5 wet-process phosphoric acid as raw material,barium salt as desulfurizing agent,potassium carbonate as defluorination agent,and silica as additive, one-time pretreatment was made for desulfurization and defluorination by chemical precipitation method.The rates of desulfurization and defluorination were 83% and 87.82%,respectively.Then industrial grade MAP was obtained by the ammonia neutralization for two times in a row,twice concentration in consecutive double-effect,and by continuous crystallization.The prepared industrial MAP′s chemical composition(mass fraction) was as follows:N(11.85%),P2O5 (59.62%),NH4H2PO4 (96.68%),F-(0.17%),and  SO42- (0.64%),which reached the requirements of Industrial Grade MAP Standard(GB 10205—2009).

Key words: defluorination, desulfurization, industrial MAP