无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (11): 35-.

• 论文 • 上一篇    下一篇

溶液组成对焙烧-水化制备氢氧化镁纳米片的影响

陈泆君,马祥伟,易美桂   

  1. 四川大学化工学院,四川成都 610065
  • 出版日期:2016-11-10 发布日期:2016-11-28

Influence of solution composition on synthesis of dispersive Mg(OH)2 nanoplates via sintering-hydration route

 CHEN  Die-Jun, MA  Xiang-Wei, YI  Mei-Gui   

  1. College of Chemical Engineering,Sichuan University,Chengdu 610065,China
  • Published:2016-11-10 Online:2016-11-28

摘要: 以团聚态工业氢氧化镁为原料,采用焙烧-水化法制备高分散氢氧化镁纳米片,探讨了水化过程中溶液组成对产物形貌和分散性的影响。研究结果表明:采用1 mol/L MgCl2溶液为水化介质,可促进氢氧化镁的溶解-重结晶过程,利于形成形貌规则、分散性较好的氢氧化镁纳米片;同时,在水化介质中添加十二烷基硫酸钠可降低氢氧化镁表面电位,抑制纳米片团聚,可制备直径为0.5~0.8 μm、团聚粒径为3.3 μm的高分散氢氧化镁纳米片。

关键词: 氢氧化镁, 焙烧, 水化介质, 表面活性剂, 分散性

Abstract: Highly dispersive Mg(OH)2 nanoplates were synthesized from industrial Mg(OH)2  agglomerates via sintering- hydration method.The influence of solution composition in the hydration step on the morphology and dispersion of Mg(OH)2  nanoplates was studied.Experimental results indicated that taking MgCl2 solution with 1 mol/L as the hydration medium could promote the dissolution and recrystallization of Mg(OH)2,and it was also in favor of the formation of uniform and well-dis- persed Mg(OH)2  nanoplates.Meanwhile,the addition of sodium dodecyl sulfate led to the decrease of the zeta potential of Mg(OH)2,which inhibited the aggregation,leading to formation of high-dispersive Mg(OH)2  nanoplates with diameter at 0.5~0.8 μm and agglomerate size in 3.3 μm.

Key words: magnesium hydroxide;sintering, hydration media;surfactants;dispersion