无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (11): 1-.

• 论文 •    下一篇

粉煤灰沸石碱性活化方法研究

邓 慧,郭 畅,姜虎生   

  1. 辽宁石油化工大学化学化工与环境学部,辽宁抚顺  113001
  • 出版日期:2014-11-10 发布日期:2014-11-13

Study on alkali-activated fly ash methods for zeolite

 DENG   Hui, GUO   Chang, JIANG  Hu-Sheng   

  1. College of Chemistry,Chemical and Environmental Engineering,Liaoning Shihua University,Fushun 113001,China
  • Published:2014-11-10 Online:2014-11-13

摘要: 粉煤灰是一种主要成分为硅铝酸盐的工业废弃物,粉煤灰沸石合成转化是其高值化应用的一个发展方向。利用碱性试剂活化粉煤灰是粉煤灰合成沸石的重要途径,研究比较了粉煤灰碱性活化合成沸石的干法和湿法工艺,包括水热法、高温熔融水热法和盐熔法的现状、特点、合成机理,并对碱性活化剂氢氧化钠、硅铝比、煅烧条件等影响因素做了分析研究。

关键词: 粉煤灰, 沸石, 合成, 碱活化

Abstract: Fly ash is a kind of industrial solid waste whose major component is crystal aluminum-silicate.Synthesizing zeolite from fly ash is a development trend for high-value application.The alkali-activation of fly ash is an important way for synthesis of zeolite.The dry and wet technologies of alkali-activation of fly ash for synthesis of zeolite were summarized.Current study situation,characteristics,and reaction mechanism of hydrothermal process,high temperature fusion followed by hydrothermal process and alkaline molten-salt process were researched,respectively.The factors,such as NaOH(alkaline activating agent),ratio of SiO2 to Al2O3,and calcination conditions,were also studied and analyzed.

Key words: fly ash, zeolite, synthesis, alkaline activation

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