无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2022, Vol. 54 ›› Issue (12): 60-67.doi: 10.19964/j.issn.1006-4990.2022-0121

• 研究与开发 • 上一篇    下一篇

木耳碳基硫化钴复合材料的制备及电化学性能研究

易金亮(),杨敏(),宋方祥,陈前林   

  1. 贵州大学化学与化工学院,贵州 贵阳 550025
  • 收稿日期:2022-03-16 出版日期:2022-12-10 发布日期:2022-12-19
  • 作者简介:易金亮(1995— ),男,硕士研究生,主要从事生物质碳与过渡金属硫化物复合材料在超级电容器中应用的研究;E-mail:1316723936@qq.com
  • 基金资助:
    贵州省高层次人才培养计划—“百”层次人才(黔科合平台人才[2016]5658)

Study on preparation and electrochemical properties of agaric carbon-based cobalt sulfide composites

YI Jinliang(),YANG Min(),SONG Fangxiang,CHEN Qianlin   

  1. School of Chemistry and Chemical Engineering,Guizhou University,Guiyang 550025,China
  • Received:2022-03-16 Published:2022-12-10 Online:2022-12-19

摘要:

以木耳制备的均匀溶液为碳源,加入ZIF-67前驱体,通过水热合成和高温煅烧制备氮硫共掺杂的木耳碳与硫化钴多孔片层复合材料(CoS/NSAC)。实验结果表明,该材料具有大的比表面积和高导电性,电化学性能良好。CoS/NSAC在电流密度为0.5 A/g时比容量达到484.8 F/g,在20 A/g高电流密度下循环5 000次容量保持率为78.8%。用该材料组装的非对称超级电容器具有优异的电化学性能,在0.6 A/g电流密度下比容量为154 F/g。当功率密度为362.3 W/kg时,能量密度为7.4 W?h/kg,经过1 800次循环容量保持率为81.95%。

关键词: 生物质木耳, 硫化钴, 氮硫共掺杂, 复合材料, 超级电容器

Abstract:

The homogeneous solution prepared from agaric was used as carbon sources,and porous sheet composites of N,S co-doped agaric carbon and CoS(CoS/NSAC) were prepared by hydrothermal synthesis and high temperature calcination after adding ZIF-67 precursor.The results showed that the materials had large specific surface area and high electrical conductivity with good electrochemical properties.The CoS/NSAC achieved a specific capacity of 484.8 F/gat current density of 0.5 A/g.Its capacity retention rate was 78.8% after 5 000 cycles at a high current density of 20 A/g.The asymmetric supercapacitor assembled with this materials had excellent electrochemical performance with a specific capacity of 154 F/g at current density of 0.6 A/g.When the power density was 362.3 W/kg,the energy density was 7.4 W·h/kg and the capacity retention rate was 81.95% after 1 800 cycles.

Key words: biomass agaric, cobalt sulfide, N,S co-doped, composites, supercapacitor

中图分类号: