球形氯化钾结晶过程与聚结机理研究

doi:10.19964/j.issn.1006-4990.2020-0488

无机盐工业 ›› 2021, Vol. 53 ›› Issue (7): 53-57.doi: 10.19964/j.issn.1006-4990.2020-0488

球形氯化钾结晶过程与聚结机理研究

陈许龙¹(),董伟兵^2,³,万俊峰²,王冬冬²,王刚^2,³()

1.青海民族大学物理与电子信息工程学院,青海西宁 810007
2.青海民族大学化学化工学院
3.青藏高原资源化学与生态环境保护国家民委重点实验室

收稿日期:2020-08-31 出版日期:2021-07-10 发布日期:2021-07-13
作者简介:陈许龙（1995— ）,男,在读硕士,主要研究方向为无机盐球形结晶;E-mail： xu_long_chen@163.com。
基金资助:
重点研发与转化计划-科技合作专项(2018-HZ-818);青海省自然科学基金团队项目(2019-ZJ-901)

Study on the crystallization process and agglomeration mechanism of spherical KCl

Chen Xulong¹(),Dong Weibing^2,³,Wan Junfeng²,Wang Dongdong²,Wang Gang^2,³()

1. College of Physics and Electronic Information Engineering,Qinghai University Nationalities,Xining 810007,China
2. College of Chemistry and Chemical Engineering,Qinghai Nationalities University
3. Key Laboratory of Resource Chemistry and Ecological Environment Protection of the Qinghai Tiber Plateall

Received:2020-08-31 Published:2021-07-10 Online:2021-07-13

摘要/Abstract

摘要：

针对球形氯化钾结晶过程与聚结机理不明的问题,以冷却结晶法通过过程取样制备与表征了两种不同形貌的氯化钾在不同结晶阶段的晶体形貌与粒度分布特征,从而对比分析了球形氯化钾的结晶过程。并从结晶热力学、经典浸润理论和Lifshitz-Van der Waals酸碱理论出发解释了球形氯化钾形成的主要机理是添加剂的添加减小了结晶体系的介稳区宽度及增大了晶体颗粒在结晶溶剂中的粘附自由能,导致结晶体系更容易以聚结的方式实现球形结晶。介稳区宽度减小和晶体颗粒在结晶溶剂中粘附自由能增大的同步调控有助于实现氯化钾的球形结晶。

关键词: 氯化钾, 球形, 结晶过程, 聚结机理

Abstract:

Aiming at the problems of unknown crystallization process and agglomeration mechanism of spherical KCl,two different morphologies of KCl at different crystallization stages were prepared and the crystal morphology and particle size distribution were characterized by cooling crystallization method through process sampling.Thus,the crystallization process of spherical KCl was comparatively analyzed.Based on the thermodynamics of crystallization,the classical Wetting Theory and the Lifshitz-Van der Waals acid-base approach,it was explained that the main mechanism of the formation of spherical KCl was that the width of crystallization metastable zone had been narrower and the adhesion free energy between crystal particles in the solution had been increased by addition of additives.Therefore,it was easier for the system to achieve spherical crystallization by agglomeration.The simultaneous adjustment of the reduction of the metastable zone and the increase of adhesion free energy between crystal particles in the solution was helpful to realize the spherical crystallization of KCl.

Key words: KCl, sphericity, rystallization process, agglomeration mechanism

中图分类号:

TQ131.13

陈许龙,董伟兵,万俊峰,王冬冬,王刚. 球形氯化钾结晶过程与聚结机理研究[J]. 无机盐工业, 2021, 53(7): 53-57.

Chen Xulong,Dong Weibing,Wan Junfeng,Wang Dongdong,Wang Gang. Study on the crystallization process and agglomeration mechanism of spherical KCl[J]. Inorganic Chemicals Industry, 2021, 53(7): 53-57.

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参考文献 16

[1]	Vogt J, Weiss H. The structure of NaCl(100) and KCl(100) single crystal surfaces a tensor low energy electron diffraction analysis[J]. Surface Science, 2001, 491:155-168.
[2]	何志强. 浅议我国钾肥生产技术现状及未来展望[J]. 盐科学与化工, 2018, 47(8):1-5.
[3]	侯献华, 樊馥, 郑绵平, 等. 青海盐湖钾盐资源开发利用及产业发展[J]. 科技导报, 2017, 35(12):67-71.
[4]	Chen M Y, Yu C Y, Yao M H, et al. The time and location dependent prediction of crystal caking by a modified crystal bridge growth model and DEM simulation considering particle size and shape[J]. Chemical Engineering Science, 2020, 214:115419-115438.
[5]	Orlewski P M, Ahn B, Mazzotti M. Tuning the particle sizes in sphe-rical agglomeration[J]. Crystal Growth & Design, 2018, 18(10):6257-6265.
[6]	Indrajit M, Vadake P M, Girish R D, et al. Crystallization of spheri-cal common salt in the submillimeter size range without habit mo-difier[J]. Industrial and Engineering Chemistry Research, 2010, 49:12197-12203.
[7]	靳沙沙, 李振方, 朱明河, 等. 结晶方式和添加剂对氯化钾晶体形貌作用的研究[J]. 盐科学与化工, 2018, 47(2):15-19.
[8]	Jin S S, Chen M Y, Li Z F, et al. Design and mechanism of the for-mation of spherical KCl particles using cooling crystallization wi-thout additives[J]. Powder Technology, 2018, 329:455-462.
[9]	Ulusoy U, Kursun I. Comparison of different 2D image analysis me-asurement techniques for the shape of talc particles produced by different media milling[J]. Minerals Engineering, 2011, 24:91-97.
[10]	Chen M Y, Wu S G, Tang W W, et al. Caking and adhesion free energy of maltitol:Studying of mechanism in adhesion process[J]. Powder Technology, 2015, 272:235-240.
[11]	Keshra S. Additives and crystallization processes:From fundamen-tals to applications[M]. West Sussex:John Wiley & Sons Ltd, 2007: 85-86.
[12]	Vanoss C J, Good R J, Chaudhury M K. Additive and nonadditive surface tension components and the interpretation of contact an-gles[J]. Langmuir, 1988, 4(4):884-891.
[13]	Chen M Y, Wu S G, Xu S J, et al. Caking of crystals: Characteriza-tion,mechanisms and prevention[J]. Powder Technology, 2018, 337:51-67.
[14]	Toldy A I, Badruddoza A Z M, Zheng L, et al. Spherical crystalliza-tion of glycine from monodisperse microfluidic emulsions[J]. Crys-tal Growth & Design, 2012, 12(8):3977-3982.
[15]	Ålander E M, Rasmuson Å C. Agglomeration and adhesion free en-ergy of paracetamol crystals in organic solvents[J]. AIChE Journal, 2007, 53(10):2590-2605.
[16]	Mersmann A. Crystallization technology handbook[M]. London: CRC Press, 2001:315-316.

样品	γ_L/（mN·m^-1）	cosθ	?G_SLS/（mJ·m^-2）
普通形貌	72.32	0.240	-26.47
球形	78.57	0.085	-48.36

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球形氯化钾结晶过程与聚结机理研究

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