活性炭协同酸/碱改性粉煤灰对亚甲基蓝的吸附研究

doi:10.19964/j.issn.1006-4990.2023-0419

Abstract

Abstract:

Fly ash and activated carbon were used as the raw materials. Sodium hydroxide，potassium hydroxide，phosphoric acid and hydrochloric acid solutions were used as the activators respectively. The modified fly ash microspheres were prepared by suspension solidification method，and the mixture was according to the design ratio m（activated carbon）∶m（fly ash）∶m（activator）∶m（H₂O）=3∶7∶6∶14.The microspheres were characterized by XRD，SEM，BET and UV visible spectrophotometer.The effects of mass，concentration，temperature，time，and other factors on the adsorption of methylene blue on the microspheres were explored. The results showed that the microspheres had good pore size，good specific surface area value，and good adsorption effect.Among them，C-NaOH-FM，C-KOH-FM，and C-HCl-FM microspheres exhibited better adsorption performance than C-H₃PO₄-FM microspheres.At T=55 ℃，the removal rate of C-HCl-FM microspheres reached 100%.Under the conditions（m=0.10 g、ρ₀=10 mg/L、T=25 ℃），the adsorption process of C-KOH-FM and C-HCl-FM microspheres followed the pseudo-second-order kinetic equation，the equilibrium adsorption capacities were 8.93 mg/g and 9.07 mg/g，the removal rates were 90.05% and 95.36%.

Key words: fly ash, activated carbon, acid/alkali synergistic modification, adsorption, methylene blue

CLC Number:

TQ536.4

LI Qiaoyun, HUANG Xiuxing, WEI Wenye, CHEN Zhen. Study on adsorption of methylene blue by activated carbon with acid/alkali synergistically modified fly ash[J]. Inorganic Chemicals Industry, 2024, 56(3): 131-136.

Figures/Tables 10

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样品	BET比表面积/ （m² ·g^-1）	孔径/ nm	孔容/ （cm³·g^-1）
C-NaOH-FM	88.53	9.00	0.21
C-KOH-FM	101.40	4.05	0.10
C-H₃PO₄-FM	98.29	9.22	0.22
C-HCl-FM	72.02	9.43	0.17

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Study on adsorption of methylene blue by activated carbon with acid/alkali synergistically modified fly ash

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