Inorganic Chemicals Industry ›› 2024, Vol. 56 ›› Issue (4): 16-23.doi: 10.19964/j.issn.1006-4990.2023-0400
• Reviews and Special Topics • Previous Articles Next Articles
ZHAO Feiyan1(), ZHANG Xiaodong2(
), DU Yanxia1, WANG Qiang1, LI Xiaoyan1
Received:
2023-08-07
Online:
2024-04-10
Published:
2024-04-18
Contact:
ZHANG Xiaodong
E-mail:10580193@ceic.com;10580172@ceic.com
CLC Number:
ZHAO Feiyan, ZHANG Xiaodong, DU Yanxia, WANG Qiang, LI Xiaoyan. Preparation technology and research progress of fly ash ceramsite[J]. Inorganic Chemicals Industry, 2024, 56(4): 16-23.
Table 1
Sintering reaction of fly ash ceramic particles"
序号 | 反应类型 | 反应式 | 反应温度/℃ |
---|---|---|---|
1 | 碳的反应 | C+O2=CO2↑ 2C+O2=2CO↑ C+CO2=2CO↑ | 400~800 |
2 | 碳酸盐反应 | MgCO3=MgO+CO2↑ CaCO3=CaO+CO2↑ | 400~500 850~900 |
3 | 氧化铁分解 | 2Fe2O3=4FeO+O2↑ Fe2O3+FeO=Fe3O4 2Fe3O4=6FeO+O2↑ | 1 100 |
4 | 碳与铁反应 | 2Fe2O3+C=4FeO+CO2↑ 2Fe2O3+3C=4Fe+3CO2↑ Fe2O3+C=2FeO+CO↑ Fe2O3+3C=2Fe+3CO↑ | 1 000~1 300 |
5 | 水分蒸发 | 100 |
Table 2
Process comparison of fly ash sintered ceramsite and non fired ceramsite"
类型 | 介绍 | 单线规模/ (万m3·a-1) | 优势 | 劣势 | 国内代 表厂家 |
---|---|---|---|---|---|
粉煤 灰烧 结陶 粒 | 陶粒密度通过调节膨胀组分含量进行控制,吨天然气消耗量为50~70 m3,吨产品能源造价超200元,适合生产高强陶粒 | 20~30 | 1)技术成熟,成本存在下降空间,可利用煤泥、生物质等作为补充能源可进一步降低生产成本;2)产品质量好,陶粒内气孔孔径差别小、分布均匀,通过改变原料比或生产工艺,生产不同等级陶粒,能够更好地适应市场需求;3)可实现连续生产,不受季节影响 | 1)生产成本高,吨产品能耗大;2)单线规模小,规模难以进一步扩大;3)粉煤灰黏结性能差,造粒成型需加入一定黏结剂;4)占地面积大 | 河南郑矿机器、山东恒远利废 |
粉煤 灰免 烧陶 粒 | 产品采用硅、钙无机矿物元素为主要原料,经特殊工艺制备而成,密度介于500~1 000 kg/m3 | 10~20 | 1)养护代替了焙烧流程,能源消耗大大减少;2)零排放,废气、废水、废料场内循环利用;3)生产效率高,生产装备自动化程度高;4)占地面积小 | 1)成本相对较高,需要添加多种辅助材料,且粉煤灰添加量低;2)强度劣于烧结型陶粒,吸水率较高;3)规模放大能力不足;4)目前国内生产厂家较少,蒸压养护受温度影响较大 | 浙江中劲环保 |
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