燃煤炉渣吸附水中铅的性能研究

doi:10.19964/j.issn.1006-4990.2022-0684

Abstract

Abstract:

As a solid waste，coal-fired slag is mainly used in construction materials and other fields.In order to gain insight into the adsorption performance of coal-fired slag on lead in water，the characterization and analysis of coal-fired slag were carried out by scanning electron microscopy，infrared spectroscopy and X-ray diffraction.The effects of pH，addition and substrate concentration on the adsorption of lead ions by coal-fired slag were investigated，and the Box-Behnken model with response surface method was used for its optimization，and the isothermal adsorption model was used to explore the adsorption mechanism.The results showed that the removal of lead ions by 77.27 mg of coal-fired slag was 47.66% at the solution pH of 5.70，the temperature of 45 ℃ and the initial mass concentration of 233.20 mg/L in 25 mL of lead solution，and the actual value was close to the predicted value，the adsorption of lead ions by coal-fired slag was in accordance with the Langmuir adsorption isotherm model，with a maximum adsorption capacity of 143.86 mg/g.The results of the study indicated that coal-fired slag could be used as a cheap and efficient adsorbent for the treatment of lead-contaminated wastewater.

Key words: coal-fired slag, wastewater containing lead, response surface methodology, adsorption isotherm

CLC Number:

X751

WANG Yingnan, SHENG Linlin, HUANG Juan, HUANG Zhanbin. Study on adsorption performance of lead from water by coal-fired slag[J]. Inorganic Chemicals Industry, 2023, 55(8): 109-115.

Figures/Tables 9

Table 1

Fig.1

Fig.2

Fig.3

Table 2

Fig.4

Fig.5

Table 3

Table 4

References 18

1	王华国.燃煤炉渣理化特性及用于污水处理的可行性研究［J］.能源与节能，2021（7）：105-106.
	WANG Huaguo.Study on physical and chemical properties of coal-fired slag and its feasibility for sewage treatment［J］.Energy and Energy Conservation，2021（7）：105-106.
2	居殿春，周夏芝，张李睿，等.高炉渣对La³⁺的吸附性能研究［J］.无机盐工业，2019，51（8）：44-47，87.
	JU Dianchun， ZHOU Xiazhi， ZHANG Lirui，et al.Study on adsorption properties of blast furnace slag for La³⁺ ［J］.Inorganic Chemicals Industry，2019，51（8）：44-47，87.
3	李昌新，喻源，张庆武，等.高炉渣吸附亚甲基蓝的性能研究［J］.应用化工，2022，51（1）：107-109，113.
	LI Changxin， YU Yuan， ZHANG Qingwu，et al.Adsorption properties of methylene blue from aqueous solution by blast furnace slag［J］.Applied Chemical Industry，2022，51（1）：107-109，113.
4	LI Sanmei， WU Mingda， LU Linghong，et al.Removal of Cd（Ⅱ） from water by HPEI modified humin［J］.Sustainability，2020，12（19）：7931.
5	邓奇根，王颖南，吴喜发，等.硫酸盐还原菌处理煤矿酸性废
	水的研究及其影响因素［J］.水处理技术，2020，46（5）：8-11， 29.
	DENG Qigen， WANG Yingnan， WU Xifa，et al.Study on the treatment of acid coal mine drainage by sulfate reducing bacteria and its influence factors［J］.Technology of Water Treatment，2020，46（5）：8-11，29.
6	王亚丽，杨宁，崔素萍，等.高炉渣对废水中Cu²⁺的吸附率和吸附行为［J］.北京工业大学学报，2021，47（2）：186-193.
	WANG Yali， YANG Ning， CUI Suping，et al.Adsorption rate and adsorption behavior of Cu²⁺ in wastewater by blast furnace slag［J］.Journal of Beijing University of Technology，2021，47（2）：186- 193.
7	BAHRAMI M， AMIRI M J， BAGHERI F.Optimization of the lead removal from aqueous solution using two starch based adsorbents：Design of experiments using response surface methodology （RSM）［J］.Journal of Environmental Chemical Engineering，2019，7（1）：102793.
8	谢亚平，陈爱侠，陈贝，等.响应曲面法对污泥热解剩余半焦吸附水中刚果红的优化［J］.环境工程学报，2020，14（3）：622-631.
	XIE Yaping， CHEN Aixia， CHEN Bei，et al.Optimization of Congo red adsorption in water by semicoke residuals from sludge pyrolysis based on response surface methodology［J］.Chinese Journal of Environmental Engineering，2020，14（3）：622-631.
9	李莉，张赛，何强，等.响应面法在试验设计与优化中的应用［J］.实验室研究与探索，2015，34（8）：41-45.
	LI Li， ZHANG Sai， HE Qiang，et al.Application of response surface methodology in experiment design and optimization［J］.Research and Exploration in Laboratory，2015，34（8）：41-45.
10	李亚娇，赵艺伟，鞠恺，等.基于响应面法的粉煤灰氨含量测定过程浸提条件优化研究［J］.无机盐工业，2022，54（4）：145-151.
	LI Yajiao， ZHAO Yiwei， JU Kai，et al.Study on optimization of extraction conditions in process of determination of ammonia content in fly ash based on response surface method［J］.Inorganic Chemicals Industry，2022，54（4）：145-151.
11	罗树琼，赵明慧，杨雷，等.水热合成托贝莫来石固化重金属研究进展［J］.新型建筑材料，2022，49（2）：9-14，29.
	LUO Shuqiong， ZHAO Minghui， YANG Lei，et al.A review on solidifying heavy metals through hydrothermal synthesis of tobermorite［J］.New Building Materials，2022，49（2）：9-14，29.
12	HAKAMI O， ZHANG Yue， BANKS C J.Thiol-functionalised mesoporous silica-coated magnetite nanoparticles for high efficiency removal and recovery of Hg from water［J］.Water Research，2012，46（12）：3913-3922.
13	宋俊颖，黄占斌.MnFe₂O₄@硅藻土复合材料的制备与染料去除性能研究［J］.矿业科学学报，2020，5（5）：564-574.
	SONG Junying， HUANG Zhanbin.Preparation and dye removal performance of MnFe₂O₄@diatomite composite［J］.Journal of Mining Science and Technology，2020，5（5）：564-574.
14	石贵明，周意超，叶长兵，等.铜闪速炉渣对重金属镉离子的吸附特性［J］.离子交换与吸附，2019，35（3）：270-279.
	SHI Guiming， ZHOU Yichao， YE Changbing，et al.Research of copper flash smelter slag for the adsorption of heavy metal Cd²⁺ ions［J］.Ion Exchange and Adsorption，2019，35（3）：270-279.
15	高宏宇.利用水淬高炉渣制备吸附剂及其在环境污染控制中的应用［D］.武汉：中国地质大学，2017.
	GAO Hongyu.The preparation method of adsorbents using granulated blast furnace slag and the applications in environment
	pollution control［D］.Wuhan：China University of Geosciences， 2017.
16	GHAEDI A M， KARAMIPOUR S， VAFAEI A，et al.Optimization and modeling of simultaneous ultrasound-assisted adsorption of ternary dyes using copper oxide nanoparticles immobilized on activated carbon using response surface methodology and artificial neural network［J］.Ultrasonics Sonochemistry，2019，51：264- 280.
17	门姝慧，黄占斌，李昉泽，等.黑腐酸对Cd²⁺的吸附响应面优化及机理研究［J］.中国环境科学，2020，40（6）：2615-2626.
	Shuhui MEN， HUANG Zhanbin， LI Fangze，et al.Adsorption of Cd²⁺ by humin：Response surface methodology and mechanism study［J］.China Environmental Science，2020，40（6）：2615-2626.
18	DIZAJ KHALILI A， GHAEMI A.Utilization of response surface methodology，kinetic and thermodynamic studies on cadmium adsorption from aqueous solution by steel slag［J］.Journal of the Iranian Chemical Society，2021，18（11）：3031-3045.

水平	因素
水平	X₁（pH）	X₂（吸附剂添加量）/mg	X₃（铅离子质量浓度）/（mg·L^-1）
-1	2	10	200
0	4	50	600
+1	6	90	1 000

方差来源	平方和	自由度	均方	F	P	显著性
模型	1 655.75	9	183.97	141.20	＜0.000 1	显著
X₁	312.75	1	312.75	240.03	＜0.000 1	显著
X₂	455.27	1	455.27	349.41	＜0.000 1	显著
X₃	319.16	1	319.16	244.95	＜0.000 1	显著
X₁X₂	18.28	1	18.28	14.03	0.007 2
X₁X₃	441.21	1	441.21	338.62	＜0.000 1	显著
X₂X₃	67.08	1	67.08	51.48	0.000 2
X₁²	1.50	1	1.50	1.15	0.319 5
X₂²	41.03	1	41.03	31.49	0.000 8
X₃²	0.54	1	0.54	0.42	0.540 0
残差	9.12	7	1.30
失拟项	3.73	3	1.24	0.923 3	0.506 4	不显著
纯误差	5.39	4	1.35
总值	1 664.87	16

温度/ ℃	Langmuir			Freundlich
温度/ ℃	q_m/ （mg·g^-1）	K_L/ （L·mg^-1）	R_L²	K_F/（mg·g^-1）·（L·mg^-1）^1/ⁿ	n	R_F²
25	72.36	0.003 2	0.99	2.42	0.46	0.98
35	140.34	0.003 2	0.99	4.63	0.46	0.97
45	143.86	0.003 5	0.98	6.31	0.43	0.98

类型	ρ（Pb）	ρ（Cd）	ρ（Hg）
本研究	3.4	0.01	0.007
GB 5085.3—2007	5.0	1.00	0.100

[1]	ZHANG Conghua, YAN Wenbin, XIAO Jiajun, ZHAO Ke, PENG Shangquan, WEI Yuhong. Reductive leaching technology of manganese anode slag using tartaric acid as reducing agent optimized by RSM [J]. Inorganic Chemicals Industry, 2023, 55(9): 106-113.
[2]	TENG Jiayang, FENG Qingge, ZHANG Xuan, QIN Fanghong, FENG Jinghang, HU Jiawen, CHEN Chaohong. Study on preparation of pseudo-boehmite from aluminum dross resource treatment [J]. Inorganic Chemicals Industry, 2023, 55(11): 130-138.
[3]	ZHANG Zhiqiang, CUI Kangping, CHEN Xing, LI Haiyang. Optimization of preparation of ultrafine chromium oxide by carbothermal reduction of sodium dichromate by response surface methodology [J]. Inorganic Chemicals Industry, 2023, 55(10): 136-144.
[4]	FANG Weicheng,CHENG Xingxing,SUN Changrong. Optimization of preparation of sludge/fly ash composite ceramsite filler materials by response surface methodology [J]. Inorganic Chemicals Industry, 2022, 54(9): 119-125.
[5]	FU Ziqi, ZHANG Cheng, SHENG Yong, JI Lijun. Study on preparation of phosphoric acid by leaching fluoride residue from wet-process phosphoric acid with organic solvents [J]. Inorganic Chemicals Industry, 2022, 54(7): 129-134.
[6]	LI Yajiao,ZHAO Yiwei,JU Kai,TANG Renlong,LI Longqing,SHAO Xiaoping,ZHANG Gaofeng,REN Wuang. Study on optimization of extraction conditions in process of determination of ammonia content in fly ash based on response surface method [J]. Inorganic Chemicals Industry, 2022, 54(4): 145-151.
[7]	Huang Jiming,Liu Runqing,Wu Sizhan,Song Juan. Optimization of extraction process of chlorination roasting-water leaching process for low-grade rhodochrosite by response surface methodology [J]. Inorganic Chemicals Industry, 2019, 51(3): 34-37.
[8]	CHEN Bo, SONG Xing-Fu, XU Yan-Xia, SUN Yu-Zhu, YU Jian-Guo. Optimization of preparation of calcium carbonate from continuous crystallization process of ammonium carbonate and conversion of calcium sulfate by response surface methodology [J]. INORGANICCHEMICALSINDUSTRY, 2016, 48(9): 18-.
[9]	Liu Jia;Xie Tian;Qiu Shuyi;Hu Hong;Zeng Guang. Optimization of technology for preparation of ammonium sulphate from phosphogysum by response surface methodology [J]. INORGANICCHEMICALSINDUSTRY, 2009, 0(5): 0-0.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Study on adsorption performance of lead from water by coal-fired slag

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 9

References 18

Related Articles 9

Metrics

Comments

Recommended 0