水淬渣-粉煤灰基4A沸石的制备及性能表征

doi:10.19964/j.issn.1006-4990.2021-0399

Abstract

Abstract:

Fly ash is often used as the raw material for synthetic zeolite because of its main components are SiO₂ and Al₂O₃.The main types of synthetic zeolite are X-type,Y-type,A-type,ZSM-5,etc.The related synthesis technology is also very mature.Water quenching slag is the blast furnace slag produced by quenching of blast furnace ironmaking water.Its main utilization method is as cement and roadbed materials,all of which are low value-added utilization.4A zeolite was synthesized by the alkali melting hydrothermal method using water quenching slag and fly ash mixed raw materials.The influence of silicon-toaluminum ratio,melting temperature,melting time,and crystallization time on the quality of the prepared zeolite samples was explored preliminarily,and the obtained best preparation conditions were：silicon-to-aluminum ratio of 1.0,alkali-to-ash ratio of 1.5,alkali melting time of 1 h,alkali melting temperature of 600 ℃,aging time of 12 h,gray-water ratio of 1∶5,crystallization temperature of 90 ℃,crystallization time of 16 h.The synthesized zeolite was characterized by XRD,XRF,SEM,FT-IR,etc.The results showed that the 4A zeolite synthesized by water quenching slag and fly ash had good performance in all aspects and had ultra-high industrial production value.

Key words: fly ash, water quenching slag, 4A zeolite, performance characterization

CLC Number:

O643.36

CUI Jiaxin,WANG Lianyong,LI Yao,HE Yan,WANG Rui,HAN Jianli. Preparation and properties characterization of water quenching slag-fly ash based 4A zeolite[J]. Inorganic Chemicals Industry, 2022, 54(4): 135-140.

Figures/Tables 16

Table 1

Table 2

Table 3

Fig.1

Fig.2

Fig.3

Fig.4

Fig.5

Fig.6

Fig.7

Fig.8

Fig.9

Table 4

Fig.10

Fig.11

Fig.12

References 15

[1]	TRIPATHY S K, DASU J, MURTHY Y, et al. Utilisation perspective on water quenched and air-cooled blast furnace slags[J]. Journal of Cleaner Production, 2020, 262.Doi: 10.1016/j.jclepro.2020.121354. doi: 10.1016/j.jclepro.2020.121354
[2]	孙红燕, 孔馨, 张瑾勋, 等. 铅冶炼水淬渣球磨工艺研究[J]. 湿法冶金, 2019, 38(5):412-415.
[3]	李峰, 马国军, 张翔, 等. 微波强化冰乙酸浸出高炉渣中钙的行为[C]// 中国金属学会.第十一届中国钢铁年会论文集-S15.能源与环保, 2017.
[4]	罗雪梅, 唐朝培, 韦星华, 等. 水淬矿渣的综合利用[J]. 中国资源综合利用, 2006(4):18-21.
[5]	LUO Y, WU Y H, MA S H, et al. Utilization of coal fiy ash in China:A mini-review on challenges and future directions[J]. Environmental Science and Pollution Research, 2021, 15(18):18727-18740.
[6]	张祥成, 孟永彪. 浅析中国粉煤灰的综合利用现状[J]. 无机盐工业, 2020, 52(2):1-5.
[7]	冯文丽, 吕学斌, 熊健, 等. 粉煤灰高附加值利用研究进展[J]. 无机盐工业, 2021, 53(4):25-31.
[8]	ZHOU Q, TANG Y G. Utilization of coal ash in China[J]. Advanced Materials Research, 2013, 2115:2386-2390.
[9]	CHEN X J, GUO Y X, CHENG F Q, et al. Application of modified coal fly ash as an absorbent for ammonia-nitrogen wastewater treatment[J]. Advanced Materials Research, 2012, 1793:2380-2384.
[10]	WANG Z, FAN Y, LI Y W, et al. Synjournal of zeolite/hydrous lanthanum oxide composite from coal fly ash for efficient phosphate removal from lake water[J]. Microporous and Mesoporous Materials, 2016, 222:226-234. doi: 10.1016/j.micromeso.2015.10.028
[11]	MAHSHID A, SYED S B, HOSSEIN K, et al. A low-cost adsorbent from coal fly ash for mercury removal from industrial wastewater[J]. Journal of Environmental Chemical Engineering, 2017, 1(5):391-399.
[12]	GABRIELE V, LORENZO C, BENEDETTA D C, et al. Study of the parameters of zeolites synjournal from coal fly ash in order to optimize their CO₂ adsorption[J]. Fuel, 2020, 276.Doi: 10.1016/j.fuel.2020.118041. doi: 10.1016/j.fuel.2020.118041
[13]	RAJAKRISHNAMOORTHY P, KARTHIKEYAN D, SARAVANAN C G. Emission reduction technique applied in SI engines exhaust by using zsm5 zeolite as catalysts synthesized from coal fly ash[J]. Materials Today:Proceedings, 2020, 3(22):499-506.
[14]	李勃. 粉煤灰合成A型沸石处理制革废水试验研究[D]. 兰州:兰州大学, 2009.
[15]	廉先进, 葛宝勋, 李凯琦. 用煤矸石作原料合成A型沸石分子筛工艺条件的探讨[J]. 郑州大学学报:理学版, 1998(2):36-41.

项目	w （SiO₂）	w （Al₂O₃）	w （CaO）	w （Fe₂O₃）	w （C）	w （其他）
预处理前	61.88	19.56	6.28	3.69	2.64	5.95
预处理后	70.13	17.82	2.48	1.58	0.00	7.99

样品名称	w（SiO₂）	w（Al₂O₃）	w（Fe₂O₃）	w（CaO）	w（Na₂O）
商用沸石	55.29	36.26	1.31	2.22	1.97
自制沸石	53.19	35.56	2.98	3.98	2.06

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Preparation and properties characterization of water quenching slag-fly ash based 4A zeolite

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 16

References 15

Related Articles 15

Metrics

Comments

Recommended 0

[1]	ZHAO Feiyan, ZHANG Xiaodong, DU Yanxia, WANG Qiang, LI Xiaoyan. Preparation technology and research progress of fly ash ceramsite [J]. Inorganic Chemicals Industry, 2024, 56(4): 16-23.
[2]	LI Kuai, LI Zhaoshuai, DONG Tingxuan, LI Dan, GUO Shengwei, HAN Fenglan. Study on effect of wet magnetic separation on distribution of Fe and heavy metal in fly ash [J]. Inorganic Chemicals Industry, 2024, 56(4): 98-104.
[3]	LI Qiaoyun, HUANG Xiuxing, WEI Wenye, CHEN Zhen. Study on adsorption of methylene blue by activated carbon with acid/alkali synergistically modified fly ash [J]. Inorganic Chemicals Industry, 2024, 56(3): 131-136.
[4]	LI Wen, WANG Wenxiang, FANG Hongsheng, WU Pingxiao. Study on effect mechanism of silicon-aluminum additives on stabilization of heavy metals in fly ash by mechanochemical stabilization method [J]. Inorganic Chemicals Industry, 2023, 55(4): 84-91.
[5]	SUN Zhigao, WU Yuan, YANG Xingchun, ZHANG Dongliang, WANG Mitang. Preparation and properties of high-magnesium nickel slag-fly ash based geopolymer [J]. Inorganic Chemicals Industry, 2023, 55(11): 139-146.
[6]	YANG Hongjun, WANG Min, GE Haiwen, QIAO Youmin, QIAO Ziyang. Study on recycling process of potassium from calcium aluminate fly ash [J]. Inorganic Chemicals Industry, 2023, 55(10): 121-127.
[7]	HE Wenchao,XUE Jing,WANG Wei. Research on strength and creep characteristics of concrete containing fly ash microbead [J]. Inorganic Chemicals Industry, 2023, 55(1): 124-128.
[8]	ZHENG Bin,JIANG Liang,HAN Fenglan,MA Hongru,QI Zhihong,SU Hui. Study on reformation and extracting iron of copper slag and silicon-manganese water quenched slag composites [J]. Inorganic Chemicals Industry, 2023, 55(1): 136-143.
[9]	LIU Darui,XU Lijun,LI Shichun,CAO Kun,TU Ya,LI Wenqing,LIU Qingliang. Research progress of recovery of strategic metal lithium from fly ash [J]. Inorganic Chemicals Industry, 2023, 55(1): 56-63.
[10]	LEI Ming,ZHU Hanyu,LIU Zilong,CHEN Guopeng,YUAN Junsheng. Distribution and speciation of heavy metals in hardened solid of net slurry co?disposed by cement kiln [J]. Inorganic Chemicals Industry, 2022, 54(8): 107-113.
[11]	CUI Jiaxin,WANG Lianyong,LU Simeng,SUN Yanwen,WANG Rui,HE Yan,HAN Jianli. Research on performance of hydrothermally synthesized zeolite with fly ash from different producing areas [J]. Inorganic Chemicals Industry, 2022, 54(5): 96-100.
[12]	LI Yajiao,ZHAO Yiwei,JU Kai,TANG Renlong,LI Longqing,SHAO Xiaoping,ZHANG Gaofeng,REN Wuang. Study on optimization of extraction conditions in process of determination of ammonia content in fly ash based on response surface method [J]. Inorganic Chemicals Industry, 2022, 54(4): 145-151.
[13]	MA Yue,CHENG Yan. Effect of thermal treatment on structure and hydrophobicity of SiO₂aerogels derived from fly ash acid sludge [J]. Inorganic Chemicals Industry, 2022, 54(3): 109-112.
[14]	CHANG Wei,LIU Honghui,JIANG Xuguang. Study on dechlorination and heavy metal leaching characteristics of MSWI fly ash during water-washing [J]. Inorganic Chemicals Industry, 2022, 54(3): 113-118.
[15]	XUE Haiyue,WANG Lianyong,LIU Xiangyu,HAN Jianli,YANG Yifan. Analysis and prospect of using fly ash based zeolite for infrared suppression of tail flame of aircraft [J]. Inorganic Chemicals Industry, 2022, 54(3): 23-30.