Inorganic Chemicals Industry ›› 2021, Vol. 53 ›› Issue (6): 199-204.doi: 10.19964/j.issn.1006-4990.2020-0421
• Catalytic Materials • Previous Articles Next Articles
Chen Lingxia1(),Wang Qi1,Sun Haijie1(),Chen Zhihao2,Liu Ranran1
Received:
2020-07-25
Online:
2021-06-10
Published:
2021-07-08
Contact:
Sun Haijie
E-mail:chenlingxia2120@vip.163.com;sunhaijie406@163.com
CLC Number:
Chen Lingxia,Wang Qi,Sun Haijie,Chen Zhihao,Liu Ranran. Study on preparation of bentonite supported Ru catalysts and their performance for hydrogen generation from catalytic hydrolysis of ammonia borane[J]. Inorganic Chemicals Industry, 2021, 53(6): 199-204.
Table 1
Apparent activation energy of Ru catalysts supported with different supports for hydrolysis of NH3BH3towards hydrogen generation "
催化剂 | 表观活化能/ (kJ·mol-1) | 催化剂 | 表观活化能/ (kJ·mol-1) |
---|---|---|---|
Ru/g-C3N4[ | 37 | Ru/MIL-96[ | 48 |
Ru/C[ | 35 | Ru/MIL-101[ | 51 |
Ru/Graphene[ | 12 | Ru/micro HAP[ | 58 |
Ru/Carbon[ | 76 | Ru/TiO2[ | 87 |
Ru/γ-Al2O3[ | 67 | Ru/Ce(OH)CO3[ | 60 |
Ru/Al2O3[ | 48 | Ru/HAP[ | 44 |
Ru/MIL-41[ | 42 | Ru/Ben(本研究) | 15 |
Ru/MIL-53[ | 29 |
[1] | 聂文丹, 杨齐凤, 卢章辉. 介孔硅负载超细Pd纳米粒子催化甲酸分解脱氢[J]. 江西师范大学学报:自然科学版, 2019,43(4):416-424. |
[2] | 孙海杰, 陈凌霞, 张玉凤, 等. 钴-硼/二氧化锆催化剂催化硼氢化钠水解制氢研究[J]. 无机盐工业, 2019,51(3):72-76. |
[3] | 孙海杰, 陈凌霞, 黄振旭, 等. 第四周期过渡金属催化硼氢化钠水解制氢研究[J]. 无机盐工业, 2017,49(5):14-17. |
[4] | 孙海杰, 黄振旭, 王雅苹, 等. 非晶态合金Ru-B/ZrO2催化剂催化硼氢化钠水解制氢性能的研究[J]. 化工新型材料, 2018,46(1):102-105. |
[5] | 张帅, 王斯瑶, 姜召, 等. 静电纺丝技术在氨硼烷水解脱氢催化剂制备中的应用[J]. 化工进展, 2019,38(7):3194-3206. |
[6] | 杨晓婧, 尚伟, 李兰兰, 等. 金属催化氨硼烷制氢研究进展[J]. 电源技术, 2014,38(7):1387-1389. |
[7] | 桑婉璐, 李兰兰, 高若源, 等. 氨硼烷水解制氢催化剂载体的研究进展[J]. 材料导报, 2017,31(9):27-33. |
[8] | 刘仲毅, 孙海杰, 王东斌, 等. 纳米ZrO2作分散剂的Ru-Zn催化剂上苯选择加氢制环己烯[J]. 催化学报, 2010,31(2):150-152. |
[9] | 姚鹏泉, 祝琳华, 司甜. 从天然膨润土制备钠基蒙脱石催化剂载体[J]. 非金属矿, 2013,36(1):24-26. |
[10] | Wang W T, Liu H Z, Wu T B, et al. Ru catalyst supported on ben-tonite for partial hydrogenation of benzene to cyclohexene[J]. Jo-urnal of Molecular Catalysis A:Chemical, 2012,355:174-179. |
[11] | 周雷雷, 张荣斌, 张婷婷, 等. 钐对Ni/膨润土催化性能的改性研究[J]. 非金属矿, 2013,37(2):27-29. |
[12] | 孙海杰, 陈凌霞, 陈秀丽. ZrO2织构性质对Ru-B/ZrO2催化剂的结构及其苯选择加氢性能的影响[J]. 石油化工, 2015,44(9):1066-1070. |
[13] | 孙海杰, 陈凌霞, 黄振旭, 等. Ru-Zn催化剂在苯选择加氢制环己烯反应中的粒径效应[J]. 高等学校化学学报, 2015,36(10):1969-1976. |
[14] |
Cao N, Luo W, Cheng G Z. One-step synjournal of graphene suppor-ted Ru nanoparticles as efficient catalysts for hydrolytic dehydro-genation of ammonia borane[J]. International Journal of Hydrogen Energy, 2013,38(27):11964-11972.
doi: 10.1016/j.ijhydene.2013.06.125 |
[15] |
Basu S, Brockman A, Gagare P, et al. Chemical kinetics of Ru-catalyzed ammonia borane hydrolysis[J]. Journal of Power Sources, 2009,188(1):238-243.
doi: 10.1016/j.jpowsour.2008.11.085 |
[16] |
Giovanni P R, Umit B D, Philippe M, et al. Faicile synjournal by po-lyol method of a ruthenium catalyst supported on γ-Al2O3 for hy-drolytic dehydrogenation of ammonia borane[J]. Catalysis Today, 2011,170(1):85-92.
doi: 10.1016/j.cattod.2011.01.040 |
[17] | Can H, Metin Ö. A facile synjournal of early monodisperse ruthenium nanoparticles and their catalysis in the hydrolytic dehydrogenation of ammoniaborane for chemical hydrogen storage[J]. Applied Ca-talysis B:Environmental, 2012,125(3):304-310. |
[18] |
Akbayrak S, Erdek P, Özkar S. Hydroxyapatite supported rutheni-um(0)nanoparticles catalyst in hydrolytic dehydrogenation of ammonia borane:Insight to the nanoparticles formation and hydro-gen evolution kinetics[J]. Applied Catalysis B:Environmental, 2013,142-143:187-195.
doi: 10.1016/j.apcatb.2013.05.015 |
[19] | 孙海杰, 陈秀丽, 黄振旭, 等. NaOH浓度对苯选择加氢制环己烯Ru-Zn催化剂性能的影响[J]. 化工学报, 2016,67(4):1324-1332. |
[20] |
Hu S, Chen Y W. Partial hydrogenation of benzene to cyclohexene on ruthenium catalysts supported on La2O3-ZnO binary oxides[J]. Industrial & Engineering Chemistry Research, 1997,36(12):5153-5159.
doi: 10.1021/ie970300y |
[21] | 朱玉玲, 郑修成, 刘蒲. 磁性花生壳负载钯催化剂的制备及催化氨硼烷释氢性能[J]. 信阳师范学院学报:自然科学版, 2019,32(2):276-280. |
[22] |
Dong H, Yang H, Ai X, et al. Hydrogen production from catalytic hydrolysis of sodium borohydride solution using nickel boride ca-talyst[J]. International Journal Hydrogen Energy, 2003,28(10):1095-1100.
doi: 10.1016/S0360-3199(02)00235-5 |
[23] | 卢章辉, 杨宇雯, 陈祥树. 一种用于氨硼烷水解制氢的Ni-CeO2@graphene复合纳米催化剂及其制备方法:中国,103990465B [P]. 2016-10-05. |
[24] | Liang H Y, Chen G Z, Desinan S, et al. In situ facile synjournal of ruthenium nanocluster catalyst supported on carbon black for hy-drogen generation from the hydrolysis of ammonia-borane[J]. In-ternational Journal of Hydrogen Energy, 2012,37(23):17921-17927. |
[25] |
Park S, An J, Potts J R, et al. Hydrazine-reduction of graphite-and graphene oxide[J]. Carbon, 2011,49(9):3019-3023.
doi: 10.1016/j.carbon.2011.02.071 |
[26] |
Yang K Z, Zhou L Q, Yu G F, et al. Ru nanoparticles supported on MIL-53(Cr,Al) as efficient catalysts for hydrogen generation from hydrolysis of ammonia borane[J]. International Journal of Hydrogen Energy, 2016,41(15):6300-6309.
doi: 10.1016/j.ijhydene.2016.02.104 |
[27] | Wen L, Su J, Wu X J, et al. Ruthenium supported on MIL-96:An efficient catalyst for hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage[J]. International Journal of Hydro-gen Energy, 2014,39(30):17129-17135. |
[28] |
Cao N, Liu T, Su J, et al. Ruthenium supported on MIL-101 as an efficient catalyst for hydrogen generation from hydrolysis of amine boranes[J]. New Journal of Chemistry, 2014,38(9):4032-4035.
doi: 10.1039/C4NJ00739E |
[29] |
Kohsuke M, Kohei M, Hiromi Y, et al. Ru and Ru-Ni nanoparticles on TiO2 support as extremely active catalysts for hydrogen produc-tion from ammonia-borane[J]. ACS Catalysis, 2016,6(5):3128-3135.
doi: 10.1021/acscatal.6b00715 |
[30] | 陈健民, 卢章辉, 熊丽华. Ru/Ce(OH)CO3纳米复合材料催化氨硼烷水解产氢[J]. 无机化学学报, 2016,32(10):1816-1824. |
[31] | 孙海杰, 刘欣改, 陈志浩, 等. 羟基磷灰石负载Ru催化氨硼烷产氢性能研究[J]. 江西师范大学学报:自然科学版, 2020,44(4):424-428. |
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