无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2011, Vol. 43 ›› Issue (8): 11-.

• 论文 • 上一篇    下一篇

三氯氢硅的生产技术与研究进展

 张开仕   

  1. 宜宾学院化学与化工学院,四川宜宾 644007
  • 出版日期:2011-08-10 发布日期:2011-08-10

Production technology and research progress of trichlorosilane

 ZHANG  Kai-Shi   

  1. School of Chemistry and Chemical Engineering,Yibin University,Yibin 644007,China
  • Published:2011-08-10 Online:2011-08-10

摘要: 通过对国内外三氯氢硅的生产技术与研究进展进行评述,提出了三氯氢硅生产工艺的改进方法。三氯氢硅的生产方法有硅氢氯化法和四氯化硅氢化法,其中硅氢氯化法最为成熟。三氯氢硅氯化合成法工艺的关键是要在生产过程中,添加高效催化剂、优化精馏提纯工艺、采用合成尾气回收新技术,以增加收率、提高质量、降低成本。

关键词: 三氯氢硅, 硅, 氯化氢

Abstract: Production technology and research progress of trichlorosilane at home and abroad were reviewed. Improvement methods for trichlorosilane production technology were put forward.The preparation methods of trichlorosilane mainly include silicon-hydrogen chloride method and silicon tetrachloride hydrogenation method,but the former was more mature than the latter.The key points for the production of trichlorosilane are adding high-efficient catalyst,optimizing the distillation purification process,and adopting new technology to recover tail gas,so as to improve the yield and quality of trichlorosilane and reduce cost at the same time.

Key words: trichlorosilane, silicon, chlorine hydride

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