无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (1): 13-.

• 论文 • 上一篇    下一篇

正极材料LiFePO4/C掺杂改性的研究进展

毛佳宇,肖 杨   

  1. 中南民族大学化学与材料科学学院,湖北武汉 430074
  • 出版日期:2016-01-10 发布日期:2016-01-20

Research progress in doping modification of LiFePO4/C cathode materials

 MAO  Jia-Yu, XIAO   Yang   

  1. College of Chemistry and Material Science,South-Central University for Nationalities,Wuhan 430074,China
  • Published:2016-01-10 Online:2016-01-20

摘要: LiFePO4/C具有高温稳定性好、价格低廉、循环性能良好、环保等性能,是一种具有发展潜力的锂离子动力电池正极材料之一,因此在锂离子电池行业备受关注。但由于其电子电导率低以及锂离子扩散速率慢等缺点制约其发展。介绍了磷酸铁锂的结构、性能、充放电原理和掺杂机理,尤其对近年来LiFePO4/C材料的掺杂改性研究进行了综述。

关键词: 锂离子电池, 磷酸铁锂, 正极材料, 掺杂

Abstract: LiFePO4/C has been regarded as one of the most promising cathode material for power lithium-ion batteries due to its attractive properties,such as remarkable thermal stability,low cost,excellent cycling performance,and environmental be- nignity.Therefore,it attracted a lot of attentions in the lithium-ion battery industry.But the development of this cathode mate- rial was constrained by its low electrical conductivity and slow diffusion rate of Li+.The crystal structure,performance,princi- ple of charging and discharging,and doping mechanism were also introduced.Especially,the research progress in doping modification of the LiFePO4/C materials in recent years was reviewed.

Key words: lithium-ion battery, lithium iron phosphate, cathode material, doping

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