无机盐工业 ›› 2022, Vol. 54 ›› Issue (4): 61-68.doi: 10.19964/j.issn.1006-4990.2021-0615
收稿日期:
2021-10-18
出版日期:
2022-04-10
发布日期:
2022-04-18
作者简介:
梁芳(1983— ),女,博士研究生,高工,主要研究方向为金属配位聚合物材料设计与结构优化;E-mail: Received:
2021-10-18
Published:
2022-04-10
Online:
2022-04-18
摘要:
铋基双金属光催化剂包括铋基双金属氧化物、铋基双金属配合物及铋酸盐。综述了铋基双金属光催化剂分类、制备方法及其在光催化降解水中有机污染物的研究进展。系统介绍了铋基双金属材料制备方法,包括水热法、溶剂热法、化学溶液分解法、熔盐法、沉淀法、高温固相法等。同时重点阐述了铋基双金属光催化剂掺杂和复合改性,并对铋基双金属光催化剂的研究方向进行了展望,目的是为开发高性能的铋基双金属光催化剂提供实用指南。
中图分类号:
梁芳,史发年. 铋基双金属光催化剂合成及降解有机污染物研究进展[J]. 无机盐工业, 2022, 54(4): 61-68.
LIANG Fang,SHI Fanian. Research progress on synthesis of bismuth based bimetallic photocatalyst and degradation of organic pollutants[J]. Inorganic Chemicals Industry, 2022, 54(4): 61-68.
表1
铋基双金属光催化剂制备方法和降解不同种类污染物光催化效率
催化剂 | 制备方法 | 禁带宽度/eV | 污染物及浓度 | 光催化效率 |
---|---|---|---|---|
CuBi-MOO/Gr[ | 水热法 | 2.67 | 5 mg/L罗丹明B | 10 min降解完全 |
BiCo-MCP[ | 水热法 | 1.65 | 10 mg/L吡虫啉农药 | 5 h降解81% |
BiVO4[ | 水热法 | 2.34 | 10 mg/L亚甲基蓝 | 2 h降解95% |
BiVO4[ | 水热法 | 2.30 | 5×10-5 mol/L罗丹明B | 45 min降解90% |
β-BiMo2O9[ | 固相法 | 3.10 | 5 mg/L罗丹明B | 403 min降解50% |
30 mg/L靛蓝胭脂红 | 295 min降解50% | |||
15 mg/L茜素红 | 282 min降解50% | |||
10 mg/L罗丹明B | 90 min降解完全 | |||
10 mg/L双酚A | 150 min降解完全 | |||
AgBiO3[ | 水热法 | 0.75 | 20 mg/L 4-硝基苯酚 | 5 h降解90% |
Bi2WO6[ | 水热法 | 2.95 | 5 μg/L罗丹明B | 50 min降解98% |
Bi12TiO20[ | 溶剂热法 | — | 25 mg/L酸性品红 | 3 h降解92% |
Bi2Ti2O7[ | 化学溶液分解法 | 2.95 | 10 mg/L甲基橙 | 7.5 min脱色50% |
Bi4Ti3O12[ | 化学溶液分解法 | 3.08 | 10 mg/L甲基橙 | 2.6 h脱色50% |
Bi4Ti3O12[ | 熔盐法 | — | 20 mg/L亚甲基蓝 | 2 h降解完全 |
Bi4Ti3O12[ | 氧化剂过氧化物法 | 2.63 | 10 mg/L罗丹明B | 3 h降解98% |
Bi12TiO20[ | 2.66 |
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