无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2015, Vol. 47 ›› Issue (4): 65-.

• 论文 • 上一篇    下一篇

丁二腈作为电解液添加剂的研究

张春丽,叶学海,任春燕   

  1. 中海油天津化工研究设计院,天津 300131
  • 出版日期:2015-04-10 发布日期:2015-04-20

Study on succinonitrile as additive of electrolyte solution

 ZHANG  Chun-Li, YE  Xue-Hai, REN  Chun-Yan   

  1. CNOOC Tianjin Chemical Research & Design Institute,Tianjin 300131,China
  • Published:2015-04-10 Online:2015-04-20

摘要: 在1 mol/L 六氟磷酸锂/[碳酸乙烯酯(EC)+碳酸二甲酯(DMC)+碳酸甲乙酯(EMC)(体积比为1∶1∶1)]的电解液中加入添加剂丁二腈(SN),用循环伏安(CV)、恒流充放电、电化学阻抗谱(EIS)等方法,研究了丁二腈对电解液的电化学窗口、电池的比容量、电池的首次充放电效率和电池的循环性能的影响。结果表明,在电解液中加入一定量的高纯度丁二腈,能提高电池的比容量、首次充放电效率和拓宽电解液的电化学稳定窗口,从而提高电解液的热稳定性,改善电解液的循环性能。

关键词: 丁二腈, 电解液, 添加剂, 锂离子电池

Abstract: Succinonitrile(SN) was added to the electrolyte solution containing 1 mol/L LiPF6 in ethylene carbonate (EC), dimethyl carbonate(DMC),and methyl ethyl carbonate(EMC) (volume ratio of 1∶1∶1).The effects of SN on electrochemical windows,specific capacity,charge-discharge efficiency for the first cycle,and cycling performance of lithium ion battery were researched by cyclic voltammetry(CV),charge-discharge cycle performance,and electrochemical impedance spectra(EIS).The results indicated that the application of high purity SN improved the specific capacity,initial charge-discharge efficiency,electrochemical windows,thermal stability,and cycling performance of the electrolyte solution.

Key words: succinonitrile, electrolyte, additive, Li-ion battery

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