无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2012, Vol. 44 ›› Issue (1): 59-.

• 论文 • 上一篇    

含铁沸石分子筛中硅铝比的测定

李帅,张杰,聂光华   

  1. 贵州大学矿业学院,贵州贵阳 550003
  • 出版日期:2012-01-10 发布日期:2012-01-16

Determination of Si/Al ratio in zeolite molecular sieves containing iron

 LI  Shuai, ZHANG  Jie, NIE  Guang-Hua   

  1. School of Mining,Guizhou University,Guiyang 550003,China
  • Published:2012-01-10 Online:2012-01-16

摘要: 针对含铁沸石分子筛,提出用硅钼蓝光度法测硅,用EDTA和硝酸铅滴定法测铝铁合量,再用磺基水杨酸光度法测铁,根据测试结果计算硅、铝、铁的含量及求出硅铝物质的量比,并通过实验证明该方法简单可行。通过硅铝物质的量比的测定,能为分子筛产品的性能提供重要参考指标和理论依据,而且,根据实际需要,还可调整沸石的硅铝物质的量比,来满足所需性能。另外,本方法因为所需化学药剂常见,在一般实验室均可进行,所以在经济上和适用范围上都有较明显的优势,参考价值显著。

关键词: 沸石分子筛, 铁, 硅铝比

Abstract: On the iron containing zeolite molecular sieves (iron-zeolite),it′s proposed to determine Si by using silicomolybdate blue photometry,to determine the combined amount of Al and Fe by EDTA-Pb(NO3)2 titration,and to determine iron by sulfosalicylic acid-spectrophotometry.Finally the silicon,aluminum,and iron contents could be calculated,and the Si/Al ratio could be obtained.Experiments proved that this method was simple and feasible.Determination of Si/Al ratio could provide important reference index and theoretical foundation for zeolite performance and it could also help to decide what kind of molecular sieve can meet the requirements.In addition,the chemicals required in this experiment are very common,and the experiment can be carried out in general laboratory,so it has some obvious advantages in economic costs and application scope.Also the reference value is significant.

Key words: zeolite molecular sieve, iron, Si/Al ratio

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