铋基双金属光催化剂合成及降解有机污染物研究进展

doi:10.19964/j.issn.1006-4990.2021-0615

摘要/Abstract

摘要：

铋基双金属光催化剂包括铋基双金属氧化物、铋基双金属配合物及铋酸盐。综述了铋基双金属光催化剂分类、制备方法及其在光催化降解水中有机污染物的研究进展。系统介绍了铋基双金属材料制备方法,包括水热法、溶剂热法、化学溶液分解法、熔盐法、沉淀法、高温固相法等。同时重点阐述了铋基双金属光催化剂掺杂和复合改性,并对铋基双金属光催化剂的研究方向进行了展望,目的是为开发高性能的铋基双金属光催化剂提供实用指南。

关键词: 铋基双金属, 光催化, 有机污染物, 掺杂

Abstract:

Bismuth based bimetal photocatalysts（Bbbps） include bismuth based bimetal oxides,bismuth based bimetal coordination complexes and bismuth salts.The classification,preparation methods of Bbbps and their research advances in photocatalytic degradation of organic pollutants in water were reviewed.The synthesis methods of bismuth bimetallic materials were systematically introduced,including hydrothermal method,solvothermal method,chemical solution decomposition method,molten salt method,precipitation method,high temperature solid phase method,etc.At the same time,the doping and compound modification of Bbbps were emphasized,and the research direction of Bbbps was prospected.The aim was to provide a practical guide for the development of Bbbps with high performance.

Key words: bismuth based bimetal, photocatalysis, organic pollutant, doping

中图分类号:

TQ135.32

梁芳,史发年. 铋基双金属光催化剂合成及降解有机污染物研究进展[J]. 无机盐工业, 2022, 54(4): 61-68.

LIANG Fang,SHI Fanian. Research progress on synthesis of bismuth based bimetallic photocatalyst and degradation of organic pollutants[J]. Inorganic Chemicals Industry, 2022, 54(4): 61-68.

图/表 2

参考文献 50

[1]	刘莹. 铁酸镁光催化剂合成与多种染料降解活性对比研究[J]. 无机盐工业, 2020, 52(11):103-107.
[2]	黄夏梦. 光催化材料Bi₄O₇/BiOBr的制备及其光催化性能研究[J]. 无机盐工业, 2021, 53(4):112-116.
[3]	KALLAWAR G A, BARAI D P, BHANVASE B A. Bismuth titanate based photocatalysts for degradation of persistent organic compounds in wastewater:A comprehensive review on synjournal methods,performance as photocatalyst and challenges[J]. Journal of Cleaner Production, 2021, 318.Doi: 10.1016/j.jclepro.2021.128563. doi: 10.1016/j.jclepro.2021.128563
[4]	MENG Xiangchao, ZHANG Zisheng. Facile synjournal of BiOBr/Bi₂WO₆ heterojunction semiconductors with high visible-light-driven photocatalytic activity[J]. Journal of Photochemistry and Photobiology A:Chemistry, 2015, 310:33-44. doi: 10.1016/j.jphotochem.2015.04.024
[5]	GAO Xiaoming, GAO Kailong, FU Feng, et al. Synergistic introducing of oxygen vacancies and hybrid of organic semiconductor:Realizing deep structure modulation on Bi₅O₇I for high-efficiency photocatalytic pollutant oxidation[J]. Applied Catalysis B:Environmental, 2020, 265.Doi: 10.1016/j.apcatb.2019.118562. doi: 10.1016/j.apcatb.2019.118562
[6]	TAHIR M B, RAFIQUE M, RAFIQUE M S, et al. Photocatalytic nanomaterials for degradation of organic pollutants and heavy metals[M]// Nanotechnology and Photocatalysis for Environmental Applications.Amsterdam:Elsevier, 2020:119-138.
[7]	BAI Song, ZHANG Ning, GAO Chao, et al. Defect engineering in photocatalytic materials[J]. Nano Energy, 2018, 53:296-336. doi: 10.1016/j.nanoen.2018.08.058
[8]	SUN Pingping, ZHANG Yuhang, PAN Guangxin, et al. Application of NiO-modified NiCo₂O₄ hollow spheres for high performance lithium ion batteries and supercapacitors[J]. Journal of Alloys and Compounds, 2020, 832.Doi: 10.1016/j.jallcom.2020.154954. doi: 10.1016/j.jallcom.2020.154954
[9]	KANG Ying, ZHANG Yuhang, SUN Pingping, et al. Bimetallic coordination polymer composites:A new choice of electrode materials for lithium ion batteries[J]. Solid State Ionics, 2020, 350.Doi: 10.1016/j.ssi.2020.115310. doi: 10.1016/j.ssi.2020.115310
[10]	SHI Fanian, BAI Yiwen, LU Miao, et al. A one-dimensional Mn(Ⅱ)-based metal organic oxide:Structure and properties[J]. Transition Metal Chemistry, 2017, 42(7):605-614. doi: 10.1007/s11243-017-0165-5
[11]	SHI Fanian, LU Miao, BAI Yiwen, et al. pH controlled excellent photocatalytic activity of a composite designed from CuBi-based metal organic oxide and graphene[J]. Crystal Growth & Design, 2018, 18(9):5045-5053. doi: 10.1021/acs.cgd.8b00490
[12]	LIANG Fang, LU Miao, ZHANG Yuhang, et al. Synjournal and structure of a bismuth-cobalt bimetal coordination polymer for green efficient photocatalytic degradation of organic wastes under visible light[J]. Journal of Molecular Structure, 2021, 1230.Doi: 10.1016/j.molstruc.2020.129636. doi: 10.1016/j.molstruc.2020.129636
[13]	YUE Zilong, FENG Yuquan, NG S W. A linear heterometallic bismuth-copper coordination polymer containing two types of organic ligands[J]. Acta Crystallographica Section C:Structural Chemistry, 2015, 71:100-102. doi: 10.1107/S2053229614028125
[14]	PEARSON T J, FATAFTAH M S, FREEDMAN D E. Enhancement of magnetic anisotropy in a Mn-Bi heterobimetallic complex[J]. Chemical Communications(Cambridge,England), 2016, 52(76):11394-11397.
[15]	SHI Fanian, SILVA A R, YANG Tinghai, et al. Mixed Cu(ii)-Bi(iii) metal organic framework with a 2D inorganic subnetwork and its catalytic activity[J]. CrystEngComm, 2013, 15(19):3776-3779. doi: 10.1039/c3ce27056d
[16]	SHI Fanian, ROSA SILVA A, BIAN Liang. Bi-Mn mixed metal organic oxide:A novel 3d-6p mixed metal coordination network[J]. Journal of Solid State Chemistry, 2015, 225:45-52. doi: 10.1016/j.jssc.2014.11.027
[17]	崔玉民, 李慧泉. 铋基光催化材料[M]. 北京: 化学工业出版社, 2015.
[18]	LU Dingze, YANG Minchen, KUMAR K K, et al. Grape-like Bi₂WO₆ / CeO₂ hierarchical microspheres:A superior visible-light-driven photoelectric efficiency with magnetic recycled characteristic[J]. Separation and Purification Technology, 2018, 194:130-134. doi: 10.1016/j.seppur.2017.11.039
[19]	YANG Qing, LUO Maolan, LIU Kewei, et al. A composite of singlecrystalline Bi₂WO₆ and polycrystalline BiOCl with a high percentage of exposed(00l) facets for highly efficient photocatalytic degradation of organic pollutants[J]. Chemical Communications(Cambridge,England), 2019, 55(40):5728-5731.
[20]	DUAN Jihai, LIU Miyu, SONG Xiaokun, et al. Enhanced photocatalytic degradation of organic pollutants using carbon nanotube mediated CuO and Bi₂WO₆ sandwich flaky structures[J]. Nanotechnology, 2020, 31(42).Doi: 10.1088/1361-6528/ab9bd3. doi: 10.1088/1361-6528/ab9bd3
[21]	ZHAO Yu, XIE Yi, ZHU Xi, et al. Surfactant-free synjournal of hyperbranched monoclinic bismuth vanadate and its applications in photocatalysis,gas sensing,and lithium-ion batteries[J]. Chemistry-A European Journal, 2008, 14(5):1601-1606. doi: 10.1002/chem.200701053
[22]	ZHANG Lili, LONG Jinxin, PAN Wenwen, et al. Efficient removal of methylene blue over composite-phase BiVO₄ fabricated by hydrothermal control synjournal[J]. Materials Chemistry and Physics, 2012, 136(2/3):897-902. doi: 10.1016/j.matchemphys.2012.08.016
[23]	JAYARAMAN V, AYAPPAN C, MANI A. Facile preparation of bismuth vanadate-sheet/carbon nitride rod-like interface photocatalyst for efficient degradation of model organic pollutant under direct sunlight irradiation[J]. Chemosphere, 2022, 287.Doi: 10.1016/j.chemosphere.2021.132055. doi: 10.1016/j.chemosphere.2021.132055
[24]	SHIMODAIRA Y, KATO H, KOBAYASHI H, et al. Photophysical properties and photocatalytic activities of bismuth molybdates under visible light irradiation[J]. The Journal of Physical Chemistry B, 2006, 110(36):17790-17797. doi: 10.1021/jp0622482
[25]	MARTÍNEZ-DE LA CRUZ A, GRACIA LOZANO L G. Photoas sisted degradation of organic dyes by β-Bi₂Mo₂O₉[J]. Reaction Kinetics,Mechanisms and Catalysis, 2010, 99(1):209-215.
[26]	ZHANG Xing, CHEN Suhang, LIAN Xiaoyan, et al. Efficient activation of peroxydisulfate by g-C₃N₄/Bi₂MoO₆ nanocomposite for enhanced organic pollutants degradation through non-radical dominated oxidation processes[J]. Journal of Colloid and Interface Science, 2022, 607:684-697. doi: 10.1016/j.jcis.2021.08.198
[27]	ZHOU Wenliu, ZHAO Zongyan. Electronic structures of efficient MBiO₃(M=Li,Na,K,Ag) photocatalyst[J]. Chinese Physics B, 2016, 25(3):325-332.
[28]	LI Linna, LIU Zhangsheng, GUO Litong, et al. NaBiO₃/BiO₂-_x composite photocatalysts with post-illumination “memory” activity[J]. Materials Letters, 2019, 234:30-34. doi: 10.1016/j.matlet.2018.09.062
[29]	BORUAH B, GUPTA R, MODAK J M, et al. Novel insights into the properties of AgBiO₃ photocatalyst and its application in immobilized state for 4-nitrophenol degradation and bacteria inactivation[J]. Journal of Photochemistry and Photobiology A:Chemistry, 2019, 373:105-115. doi: 10.1016/j.jphotochem.2018.11.001
[30]	RAMACHANDRAN R, SATHIYA M, RAMESHA K, et al. Photocatalytic properties of KBiO₃ and LiBiO₃ with tunnel structures[J]. Journal of Chemical Sciences, 2011, 123(4):517-524. doi: 10.1007/s12039-011-0080-9
[31]	GUO Xiaoxia, WU Dan, LONG Xia, et al. Nanosheets-assembled Bi₂WO₆ microspheres with efficient visible-light-driven photocatalytic activities[J]. Materials Characterization, 2020, 163.Doi: 10.1016/j.matchar.2020.110297. doi: 10.1016/j.matchar.2020.110297
[32]	TAN Ye, YIN Changjiu, ZHENG Shuilin, et al. Design and controllable preparation of Bi₂MoO₆/attapulgite photocatalyst for the removal of tetracycline and formaldehyde[J]. Applied Clay Science, 2021, 215.Doi: 10.1016/j.clay.2021.106319. doi: 10.1016/j.clay.2021.106319
[33]	MA Yongchao, ZHANG Yuanyuan, WANG Lili, et al. Single solvent-induced one-step solvothermal method:A general strategy for controllable synjournal of ternary and multiplex Bi-based composites[J]. Journal of Alloys and Compounds, 2019, 784:405-413. doi: 10.1016/j.jallcom.2019.01.065
[34]	LIU H, SHON H K, OKOUR Y H, et al. Photocatalytic degradation of acid red G by bismuth titanate in three-phase fluidized bed photoreactor[J]. Journal of Advanced Oxidation Technologies, 2011, 14(1):115-121.
[35]	ZHU Gangqiang, LIANG Jia, HOJAMBERDIEV M, et al. Ethylenediamine(EDA) -assisted hydrothermal synjournal of nitrogen-doped Bi₂WO₆ powders[J]. Materials Letters, 2014, 122:216-219. doi: 10.1016/j.matlet.2014.02.044
[36]	AGUSTINA E B, SURYANA R, IRIANI Y. Dependence of microstructure and optical properties on holding time and annealing temperature of BiFeO₃ thin film fabricated by chemical solution deposition(CSD)[J]. Materials Today:Proceedings, 2021, 44:3313-3318. doi: 10.1016/j.matpr.2020.11.534
[37]	YAO Weifeng, XU Xiaohong, WANG Hong, et al. Photocatalytic property of perovskite bismuth titanate[J]. Applied Catalysis B: Environmental, 2004, 52(2):109-116. doi: 10.1016/j.apcatb.2004.04.002
[38]	YAO Weifeng, WANG Hong, XU Xiaohong, et al. Photocatalytic property of bismuth titanate Bi₂Ti₂O₇[J]. Applied Catalysis A:General, 2004, 259(1):29-33. doi: 10.1016/j.apcata.2003.09.004
[39]	SHAO Luhua, YANG Zhenfei, LI Sijian, et al. Molten-salt growth of Bi₅FeTi₃O₁₅-based composite to dramatically boost photocatalytic performance[J]. Journal of Photochemistry and Photobiology A:Chemistry, 2021, 415.Doi: 10.1016/j.jphotochem.2021.113306. doi: 10.1016/j.jphotochem.2021.113306
[40]	ZHAO Wei, JIA Zhen, LEI E, et al. Photocatalytic degradation efficacy of Bi₄Ti₃O₁₂ micro-scale platelets over methylene blue under visible light[J]. Journal of Physics and Chemistry of Solids, 2013, 74(11):1604-1607. doi: 10.1016/j.jpcs.2013.06.003
[41]	NOH T H, HWANG S W, KIM J U, et al. Optical properties and visible light-induced photocatalytic activity of bismuth sillenites (Bi₁₂XO₂₀,X=Si,Ge,Ti)[J]. Ceramics International, 2017, 43(15):12102-12108. doi: 10.1016/j.ceramint.2017.06.067
[42]	NOGUEIRA A E, LONGO E, LEITE E R, et al. Synjournal and photocatalytic properties of bismuth titanate with different structures via oxidant peroxo method(OPM)[J]. Journal of Colloid and Interface Science, 2014, 415:89-94. doi: 10.1016/j.jcis.2013.10.010
[43]	GUO Pengyao, HU Xiaomin, WANG Min. Solution combusting synjournal of xFe-Bi₂MoO₆ nanoparticles with increased photocatalytic performance for organic pollutants degradation[J]. Optik, 2020, 222.Doi: 10.1016/j.ijleo.2020.165399. doi: 10.1016/j.ijleo.2020.165399
[44]	JAYARAMAN V, AYAPPAN C, VATTIKONDALA G, et al. Preparation and characterization of the Cu,Fe co-doped Bi₂Ti₂O₇/EGg-C₃N₄ material for organic model pollutants removal under direct sun light irradiation[J]. Materials Research Bulletin, 2021, 143.Doi: 10.1016/j.materresbull.2021.111439. doi: 10.1016/j.materresbull.2021.111439
[45]	YANG Zhengxin, WANG Ruiqi, XU Longjun, et al. Highly efficient flower-like Dy³⁺-doped Bi₂MoO₆ photocatalyst under simulated sunlight：Design,fabrication and characterization[J]. Optical Materials, 2021, 116.Doi: 10.1016/j.optmat.2021.111094. doi: 10.1016/j.optmat.2021.111094
[46]	HUA Chenghe, WANG Jiawei, DONG Xiaoli, et al. In situ plasmonic Bi grown on I^- doped Bi₂WO₆ for enhanced visible-light-driven photocatalysis to mineralize diverse refractory organic pollutants[J]. Separation and Purification Technology, 2020, 250.Doi: 10.1016/j.seppur.2020.117119. doi: 10.1016/j.seppur.2020.117119
[47]	HABIBI-YANGJEH A, PIRHASHEMI M, GHOSH S. ZnO/ZnBi₂O₄ nanocomposites with p-n heterojunction as durable visible-lightactivated photocatalysts for efficient removal of organic pollutants[J]. Journal of Alloys and Compounds, 2020, 826.Doi: 10.1016/j.jallcom.2020.154229. doi: 10.1016/j.jallcom.2020.154229
[48]	SELVARAJAN S, SUGANTHI A, RAJARAJAN M, et al. Fabrication of highly efficient mesoporous NaBiO₃/ZnO nanocomposites for recyclable photocatalytic degradation of organic pollutants[J]. Optik-International Journal for Light and Electron Optics, 2018, 153:16-30. doi: 10.1016/j.ijleo.2017.09.082
[49]	WANG Yan, JUNG D. Synjournal of novel BiOCl/LiBiO₃ p-n heterojunction photocatalysts and their enhanced photocatalytic performance[J]. Solid State Sciences, 2019, 91:42-48. doi: 10.1016/j.solidstatesciences.2019.03.013
[50]	ZHOU Bin, ZHAO Xu, LIU Huijuan, et al. Synjournal of visible-light sensitive M-BiVO₄ (M=Ag,Co,and Ni) for the photocatalytic degradation of organic pollutants[J]. Separation and Purification Technology, 2011, 77(3):275-282. doi: 10.1016/j.seppur.2010.12.017

催化剂	制备方法	禁带宽度/eV	污染物及浓度	光催化效率
CuBi-MOO/Gr^[11]	水热法	2.67	5 mg/L罗丹明B	10 min降解完全
BiCo-MCP^[12]	水热法	1.65	10 mg/L吡虫啉农药	5 h降解81%
BiVO₄^[20]	水热法	2.34	10 mg/L亚甲基蓝	2 h降解95%
BiVO₄^[21]	水热法	2.30	5×10^-5 mol/L罗丹明B	45 min降解90%
β-BiMo₂O₉^[24]	固相法	3.10	5 mg/L罗丹明B	403 min降解50%
			30 mg/L靛蓝胭脂红	295 min降解50%
			15 mg/L茜素红	282 min降解50%
			10 mg/L罗丹明B	90 min降解完全
			10 mg/L双酚A	150 min降解完全
AgBiO₃^[28]	水热法	0.75	20 mg/L 4-硝基苯酚	5 h降解90%
Bi₂WO₆^[30]	水热法	2.95	5 μg/L罗丹明B	50 min降解98%
Bi₁₂TiO₂₀^[31]	溶剂热法	—	25 mg/L酸性品红	3 h降解92%
Bi₂Ti₂O₇^[37]	化学溶液分解法	2.95	10 mg/L甲基橙	7.5 min脱色50%
Bi₄Ti₃O₁₂^[38]	化学溶液分解法	3.08	10 mg/L甲基橙	2.6 h脱色50%
Bi₄Ti₃O₁₂^[40]	熔盐法	—	20 mg/L亚甲基蓝	2 h降解完全
Bi₄Ti₃O₁₂^[42]	氧化剂过氧化物法	2.63	10 mg/L罗丹明B	3 h降解98%
Bi₁₂TiO₂₀^[42]	氧化剂过氧化物法	2.66	10 mg/L罗丹明B	3 h降解98%

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