无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2019, Vol. 51 ›› Issue (10): 69-71.doi: 10.11962/1006-4990.2018-0581

• 无机盐工业 • 上一篇    下一篇

电解铝废渣提锂方法研究

郝建堂,温丰源,李 霞   

  1. 多氟多化工股份有限公司,河南焦作 454001
  • 出版日期:2019-10-10 发布日期:2020-03-06
  • 作者简介:郝建堂(1971— ),男,本科,高级工程师,主要从事氟化工行业研发及科技项目实施工作,获得发明专利4项,发表论文10余篇,获国家、省、部级专项及科技成果奖多项;E-mail:dfdhjt@126.com。

Study on extracting lithium from electrolytic aluminum waste residue

Hao Jiantang,Wen Fengyuan,Li Xia   

  1. Do-Fluoride Chemicals Co.,Ltd.,Jiaozuo 454001,China
  • Online:2019-10-10 Published:2020-03-06

摘要: 随着新能源汽车行业进入黄金发展期,动力锂电池行业呈爆发式增长,碳酸锂的需求量也逐年递增,含锂氟化盐的使用造成大量含锂电解铝废渣产生,如果得到合理回收利用,将有利于缓解新能源产业带来的用锂压力。重点研究了以含锂电解铝废渣和浓硫酸为原料,通过酸浸取等一系列工艺,制备电池级碳酸锂,同时副产冰晶石,并从实验原理、实验方法、工艺关键点控制、产品质量、工艺特点等方面进行了深度剖析。本工艺具有良好的社会效益、经济效益和环保效益,易于推广应用。

关键词: 碳酸锂;含锂废渣;苛化反应;碳化反应

Abstract: As the new energy vehicle industry enters the golden development period,the power lithium battery industry shows explosive growth and the demand for lithium carbonate is also increasing year by year.The use of lithium containing fluoride salt leads to a large amount of lithium containing electrolytic aluminum waste residue to be produced.Reasonable recycling and utilizing of these waste residue will help alleviate the pressure of lithium from new energy industry.The battery grade lithium carbonate was prepared and cryolite by produced through a series of processes with lithium containing electrolytic aluminum waste residue and concentrated sulfuric acid as raw materials.The aspects of experimental principle,experimental methods,control of process key point,product quality,process characteristics and etc.Were deeply analyzed.The process has good social,economic and environmental benefits,and is easy to popularize and apply.

Key words: lithium carbonate;lithiumcontaining waste residue;causticizing reaction;carbonation reaction

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