Inorganic Chemicals Industry ›› 2022, Vol. 54 ›› Issue (2): 21-29.doi: 10.19964/j.issn.1006-4990.2021-0266
• Reviews and Special Topics • Previous Articles Next Articles
ZHAO Yuanyuan1(), CHEN Haifeng1, LIU Yunyun1, ZHANG Hong1, WU Yongmin2, ZHANG Jingze2, TANG Weiping2(
)
Received:
2021-05-19
Online:
2022-02-10
Published:
2022-03-14
Contact:
TANG Weiping
E-mail:1905061@sust.edu.cn;Tangwp@sina.cn
CLC Number:
ZHAO Yuanyuan, CHEN Haifeng, LIU Yunyun, ZHANG Hong, WU Yongmin, ZHANG Jingze, TANG Weiping. Research progress on preparation and modification of manganese based lithium ion sieve[J]. Inorganic Chemicals Industry, 2022, 54(2): 21-29.
[1] | MARTIN G, RENTSCH L, HÖCK M, et al. Lithium market research-global supply,future demand and price development[J]. Energy Storage Materials, 2017,6:171-179. |
[2] | XU P, HONG J, QIAN X M, et al. Materials for lithium recovery from salt lake brine[J]. Journal of Materials Science , 2021,56(1):16-63. |
[3] | 韩佳欢, 乜贞, 伍倩, 等. 中国锂资源供需现状分析[J]. 无机盐工业, 2021,53(12):61-66. |
[4] | LI X H, MO Y H, QING W H, et al. Membrane-based technologies for lithium recovery from water lithium resources:A review[J]. Jo-urnal of Membrane Science, 2019,591.Doi:10.1016/j.memsci.2019.117317. |
[5] | LINNEEN N, BHAVE R, WOERNER D. Purification of industrial grade lithium chloride for the recovery of high purity battery grade lithium carbonate[J]. Separation & Purification Technology, 2019,214:168-173. |
[6] | USGS.National minerals information center:Lithium statistics and information[EB/OL]. [2021-05-19]. https://www.usgs.gov/centers/ters/nmic/lithium-statistics-and-information. |
[7] | LEE D H, RYU T, SHIN J, et al. Equilibrium and kinetic studies of an electro-assisted lithium recovery system using lithium manganese oxide adsorbent material[J]. Carbon Letters, 2018,28(1):87-95. |
[8] | HAN G F, GU D L, LIN G, et al. Recovery of lithium from a synthetic solution using spodumene leach residue[J]. Hydrometallurgy, 2018,177:109-115. |
[9] | HONG H J, RYU T, PARK I S, et al. Highly porous and surface-ex-panded spinel hydrogen manganese oxide(HMO)/Al2O3 composite for effective lithium(Li) recovery from seawater[J]. Chemical Engi-neering Journal, 2018,337:455-461. |
[10] | YE Q, LI G, DENG B, et al. Solvent extraction behavior of metal ions and selective separation Sc 3+ in phosphoric acid medium using P2O4 [J]. Separation and Purification Technology, 2019,209:175-181. |
[11] | GUO X Y, HU S F, WANG C X, et al. Highly efficient separation of magnesium and lithium and high-valued utilization of magnesi-um from salt lake brine by a reaction-coupled separation technolo-gy[J]. Industrial & Engineering Chemistry Research, 2018,57(19):6618-6626. |
[12] | GUO Z Y, JI Z Y, CHEN Q B, et al. Prefractionation of LiCl from concentrated seawater/salt lake brines by electrodialysis with mo-novalent selective ion exchange membranes[J]. Journal of Cleaner Production, 2018,193:338-350. |
[13] | LIU X H, ZHONG M L, CHEN X Y, et al. Separating lithium and magnesium in brine by aluminum-based materials[J]. Hydromet-allurgy, 2018,176:73-77. |
[14] | TIAN L, MA W, HAN M. Adsorption behavior of Li + onto nano-li-thium ion sieve from hybrid magnesium/lithium manganese oxi-de [J]. Chemical Engineering Journal, 2010,156(1):134-140. |
[15] | RYU T, SHIN J, RYU J, et al. Preparation and characterization of a cylinder-type adsorbent for the recovery of lithium from seawat-er[J]. Materials Transactions, 2013,54(6):1029-1033. |
[16] | CHUNG K Y, SHU D, KIM K B. Determination of the potential ran-ge responsible for the replacement of surface film on LiMn2O4[J]. Electrochimica Acta, 2004,49(6):887-898. |
[17] | 纪志永, 许长春, 袁俊生, 等. 尖晶石型锂离子筛研究进展[J]. 化工进展, 2005,24(12):1336-1341. |
[18] | XIAO W J, XIN C, LI S B, et al. Insight into fast Li diffusion in Li-excess spinel lithium manganese oxide[J]. Journal of Materials Chemistry A, 2018,6(21):9893-9898. |
[19] | HUNTER J C. Preparation of a new crystal form of manganese dio-xide:λ-MnO2[J]. Journal of Solid State Chemistry, 1981,39(2):142-147. |
[20] | OOI K, MIYAI Y, KATOH S, et al. Lithium-ion insertion/extraction reaction with λ-MnO2 in the aqueous phase[J]. Chemistry Letters, 1980(6):989-992. |
[21] | SATO K, POOJARY D M, CLEARFIELD A, et al. The surface st-ructure of the proton-exchanged lithium manganese oxide spinels and their lithium-ion sieve properties[J]. Journal of Solid State Chemistry, 1997,131(1):84-93. |
[22] | FENG Q, MIYAI Y, KANOH H, et al. Li + extraction/insertion with spinel-type lithium manganese oxides:Characterization of redox-type and ion-exchange-type sites [J]. Langmuir, 1992,8(7):1861-1867. |
[23] | LIU G, ZHAO Z W, GHAHREMAN A. Novel approaches for lithium extraction from salt-lake brines:A review[J]. Hydrometallurgy, 2019,187:81-100. |
[24] | WENG D, DUAN H Y, HOU Y C, et al. Introduction of manganese based lithium-ion sieve-a review[J]. Progress in Natural Science:Materials International, 2020,30(2):5-18. |
[25] | WANG L, ZHANG Y, SUN W, et al. Membrane technologies for Li +/Mg 2+ separation from salt-lake brines and seawater:A compre-hensive review [J]. Journal of Industrial and Engineering Chemi-stry, 2019,81:7-23. |
[26] | FENG Q, KANOH H, MIYAI Y, et al. Hydrothermal synjournal of lithium and sodium manganese oxides and their metal ion extrac-tion/insertion reactions[J]. Chemistry of Materials, 1995,7(6):1226-1232. |
[27] | ZHANG Q H, LI S P, SUN S Y, et al. LiMn2O4 spinel direct synthe-sis and lithium ion selective adsorption[J]. Chemical Engineering Science, 2010,65(1):169-173. |
[28] | ÖZGÜR C. Preparation and characterization of LiMn2O4 ion-sieve with high Li + adsorption rate by ultrasonic spray pyrolysis [J]. Solid State Ionics, 2010,181:1425-1428. |
[29] | SUN S Y, SONG X F, ZHANG Q H, et al. Lithium extraction/inser-tion process on cubic Li-Mn-O precursors with different Li/Mn ratio and morphology[J]. Adsorption, 2011,17(5):881-887. |
[30] | JI Z Y, ZHAO M Y, ZHAO Y Y, et al. Lithium extraction process on spinel-type LiMn2O4 and characterization based on the hydroly-sis of sodium persulfate[J]. Solid State Ionics, 2017,301:116-124. |
[31] | THACKERAY M M. Spinel electrodes from the Li-Mn-O system for rechargeable lithium battery applications[J]. Journal of the El-ectrochemical Society, 1992,139(2):363-366. |
[32] | TAKADA T, HAYAKAWA H, AKIBA E. Preparation and crystal structure refinement of Li4Mn5O12 by the rietveld method[J]. Jour-nal of Solid State Chemistry, 1995,115(2):420-426. |
[33] | TANAKA Y, ZHANG Q W, SAITO F. Synjournal of spinel Li4Mn5O12 with an aid of mechanochemical treatment[J]. Powder Technology, 2003,132(1):74-80. |
[34] | XIAO J L, NIE X Y, SUN S Y, et al. Lithium ion adsorption-desop-tion properties on spinel Li4Mn5O12 and pH-dependent ion-exchange model[J]. Advanced Powder Technology, 2015,26(2):589-594. |
[35] | LIU D F, SUN S Y, YU J G, et al. Li4Mn5O12 desorption process with acetic acid and Mn dissolution mechanism[J]. Journal of Chemical Engineering of Japan, 2019,52(3):274-279. |
[36] | GAO A L, HOU X J, SUN Z H, et al. Lithium-desorption mechanism in LiMn2O4,Li1.33Mn1.67O4,and Li1.6Mn1.6O4 according to precisely controlled acid treatment and density functional theory calculations[J]. Journal of Materials Chemistry A, 2019,7(36):20878-20890. |
[37] | CHITRAKAR R, KANOH H, MIYAI Y, et al. ChemInform abstract:A new type of manganese oxide(MnO2·0.5H2O) derived from Li1.6Mn1.6O4 and its lithium ion-sieve properties[J]. Chemistry of Materials, 2000,12:3151-3157. |
[38] | CHITRAKAR R, KANOH H, MIYAI Y, et al. Recovery of lithium from seawater using manganese oxide adsorbent(H1.6Mn1.6O4) de-rived from Li1.6Mn1.6O4[J]. Industrial & Engineering Chemistry Research, 2001,40(9):2054-2058. |
[39] | SHI X C, ZHOU D F, ZHANG Z B, et al. Synjournal and properties of Li1.6Mn1.6O4 and its adsorption application[J]. Hydrometallurgy, 2011,110(1/2/3/4):99-106. |
[40] | 符雨尧, 杨喜云, 黄海强, 等. 工艺参数对o-LiMnO2相纯度及Li1.6Mn1.6O4合成的影响及作用(英文)[J]. 无机化学学报, 2020,36(3):154-164. |
[41] | LI X L, TAO B F, JIA Q Y, et al. Preparation and adsorption per- formance of muliti-morphology H1.6Mn1.6O4 for lithium extraction[J]. Chinese Journal of Chemical Engineering, 2020,34:68-76. |
[42] | CHEN L F, XU X, SONG J J, et al. Microwave assisted hydrother- mal synjournal of MnO2·0.5H2O ion-sieve for lithium ion selective adsorption[J]. Separation Science and Technology, 2016,51(5):874-882. |
[43] | QIAN F R, ZHAO B, GUO M, et al. Trace doping by fluoride and sulfur to enhance adsorption capacity of manganese oxides for lithium recovery[J]. Materials & Design, 2020,194.Doi:10.1016/j.matdes.2020.108867. |
[44] | 王亮, 张欣, 马来波, 等. 锰氧化物锂离子筛阳离子掺杂改性研究进展[J]. 盐科学与化工, 2018,47(4):8-11. |
[45] | CHEN M M, WU R Y, JU S G, et al. Improved performance of Al-doped LiMn2O4 ion-sieves for Li + adsorption [J]. Microporous and Mesoporous Materials, 2018,261:29-34. |
[46] | 许乃才, 黎四霞, 曹佳佳, 等. 锰氧化物锂离子筛的掺杂改性及吸附性能研究[J]. 无机盐工业, 2020,52(4):37-41. |
[47] | ZHANG G T, ZHANG J Z, ZHOU Y, et al. Synjournal of aluminum-doped ion-sieve manganese oxides powders with enhanced adsorp-tion performance[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2019,583.Doi:10.1016/j.colsurfa.2019.123950. |
[48] | 纪志永, 孙步云, 袁俊生, 等. 锰基锂离子筛前体及其掺杂和表面修饰进展[J]. 材料导报, 2016,30(13):17-22. |
[49] | CHITRAKAR R, MAKITA Y, OOI K, et al. Magnesium-doped man-ganese oxide with lithium ion-sieve property:Lithium adsorption from salt lake brine[J]. Bulletin of the Chemical Society of Japan, 2013,86(7):850-855. |
[50] | 钱方仁, 郭敏, 赵炳, 等. Mg 2+掺杂对H1.6Mn1.6O4锂离子筛吸附性能的影响 [J]. 盐湖研究, 2020,28(2):1-14. |
[51] | CAO G F, YANG X Y, YIN Z L, et al. Synjournal,adsorption proper-ties and stability of Cr-doped lithium ion sieve in salt lake brine[J]. Bulletin of the Chemical Society of Japan, 2019,92(7):1205-1210. |
[52] | LI J S, YANG X Y, FU Y Y, et al. Recovery of Fe,Mn,Ni and Co in sulfuric acid leaching liquor of spent lithium ion batteries for synjournal of lithium ion-sieve and NixCoyMn1-x-y(OH)2[J]. Hydro-metallurgy, 2019,190.Doi:10.1016/j.hydromet.2019.105190. |
[53] | CHITRAKAR R, MAKITA Y, OOI K, et al. Synjournal of iron-doped manganese oxides with an ion-sieve property:Lithium adsorption from Bolivian brine[J]. Industrial & Engineering Chemistry Re-search, 2014,53(9):3682-3688. |
[54] | WANG S L, ZHENG S L, WANG Z M, et al. Superior lithium ad-sorption and required magnetic separation behavior of iron-doped lithium ion-sieves[J]. Chemical Engineering Journal, 2018,332:160-168. |
[55] | ZHAO Q, GAO J M, GUO Y X, et al. Facile synjournal of magneti-cally recyclable Fe-doped lithium ion sieve and its Li adsorption performance[J]. Chemistry Letters, 2018,47:1308-1310. |
[56] | QIAN F R, ZHAO B, GUO M, et al. Enhancing the Li + adsorption and anti-dissolution properties of Li1.6Mn1.6O4 with Fe,Co doped [J]. Hydrometallurgy, 2020,193.Doi:10.1016/j.hydromet.2020.105291. |
[57] | FENG Q, KANOH H, MIYAI Y, et al. Li + extraction/insertion reac-tions with LiZn0.5Mn1.5O4 spinel in the aqueous phase [J]. Chemistry of Materials, 1995,7(2):379-384. |
[58] | QIAN F R, ZHAO B, GUO M, et al. Surface trace doping of Na en-hancing structure stability and adsorption properties of Li1.6Mn1.6O4 for Li + recovery [J]. Separation and Purification Technology, 2020,256.Doi:10.1016/j.seppur.2020.117583. |
[59] | QIAN F R, ZHAO B, GUO M, et al. K-gradient doping to stabilize spinel structure of Li1.6Mn1.6O4 for Li + recovery [J]. Dalton Transac-tions, 2020,49:10939-10948. |
[60] | OHASHI F, TAI Y. Lithium adsorption from natural brine using surface-modified manganese oxide adsorbents[J]. Materials Lette-rs, 2019,251:214-217. |
[61] | 王豪, 杨喜云, 尹周澜, 等. 包覆ZrO2锂离子筛的制备及其在盐湖卤水中的吸附性能[J]. 无机化学学报, 2017,33(10):1775-1781. |
[62] | 杨喜云, 曹改芳, 胡长军, 等. 锂离子筛的TiO2包覆改性研究[J]. 材料导报:纳米与新材料专辑, 2017,31(1):435-438. |
[63] | NISHIHAMA S, ONISHI K, YOSHIZUKA K. Selective recovery process of lithium from seawater using integrated ion exchange methods[J]. Solvent Extraction and Ion Exchange, 2011,29(3):421-431. |
[64] | XIAO G P, XIAO J L, SUN S Y, et al. Adsorption and desorption behavior of lithium ion in spherical PVC-MnO2 ion sieve[J]. Indu-strial & Engineering Chemistry Research, 2012,51:10921-10929. |
[65] | NISOLA G M, LIMJUCOA L A, VIVAS E L, et al. Macroporous fl- exible polyvinyl alcohol lithium adsorbent foam composite prepared via surfactant blending and cryodesiccation[J]. Chemical Engin-eering Journal, 2015,280:536-548. |
[66] | PARK M J, NISOLA G M, VIVAS E L, et al. Mixed matrix nanofiber as a flow-through membrane adsorber for continuous Li + recovery from seawater [J]. Journal of Membrane Science, 2016,510:141-154. |
[67] | JIA Q Y, WANG J, GUO R L. Preparation and characterization of porous HMO/PAN composite adsorbent and its adsorption-desorp-tion properties in brine[J]. Journal of Porous Materials, 2019,26(3):705-716. |
[68] | CHUNG W J, TORREJOS R E C, PARK M J, et al. Continuous lithium mining from aqueous resources by an adsorbent filter with a 3D polymeric nanofiber network infused with ion sieves[J]. Che- mical Engineering Journal, 2017,309:49-62. |
[69] | ZHU G R, WANG P, QI P F, et al. Adsorption and desorption pro-perties of Li + on PVC-H1.6Mn1.6O4 lithium ion-sieve membrane [J]. Chemical Engineering Journal, 2014,235:340-348. |
[70] | QI G C, HAI C X, ZHOU Y. Synjournal of PVDF-H1.6Mn1.6O4 lithi- um ion-sieve membrane for lithium extraction[J]. Journal of Syn-thetic Crystals, 2019,48(3):418-427. |
[71] | QIU Z W, WANG M Y, CHEN Y, et al. Li4Mn5O12 doped cellulose acetate membrane with low Mn loss and high stability for enhancing lithium extraction from seawater[J]. Desalination, 2021,506.Doi:10.1016/j.desal.2021.115003. |
[72] | SUN D S, ZHU Y Z, MENG M J, et al. Fabrication of highly selec-tive ion imprinted macroporous membranes with crown ether for targeted separation of lithium ion[J]. Separation and Purification Technology, 2017,175:19-26. |
[73] | LAI X R, YUAN Y J, CHEN Z Q, et al. Adsorption-desorption pro-perties of granular EP/HMO composite and its application in lithi-um recovery from brine[J]. Industrial & Engineering Chemistry Re-search, 2020,59(16):7913-7925. |
[74] | ZHAO X Y, JIAO Y X, XUE P J, et al. Efficient lithium extraction from brine using a three-dimensional nanostructured hybrid inor-ganic-gel framework electrode[J]. ACS Sustainable Chemistry & Engineering, 2020,8(12):4827-4837. |
[75] | MA L W, CHEN B Z, CHEN Y, et al. Preparation,characterization and adsorptive properties of foam-type lithium adsorbent[J]. Mi-croporous & Mesoporous Materials, 2011,142(1):147-153. |
[76] | HAN Y, KIM H, PARK J. Millimeter-sized spherical ion-sieve foams with hierarchical pore structure for recovery of lithium from seawater[J]. Chemical Engineering Journal, 2012,210:482-489. |
[77] | MU Y X, ZHANG C Y, ZHANG W, et al. Electrochemical lithium recovery from brine with high Mg 2+/Li + ratio using mesoporous λ-MnO2/LiMn2O4 modified 3D graphite felt electrodes [J]. Desalination, 2021,511.Doi:10.1016/j.desal.2021.115112. |
[78] | LIMJUCO L A, NISOLA G M, LAWAGON C P, et al. H2TiO3 com-posite adsorbent foam for efficient and continuous recovery of Li + from liquid resources [J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2016,504:267-279. |
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