螺壳生物质基纳米碳酸钙的制备及其形貌研究

doi:10.19964/j.issn.1006-4990.2024-0659

Abstract

Abstract:

By employing discarded spire snail shells from the Beibu Gulf in Guangxi as raw materials，multi-morphology nano-calcium carbonate（nano-CaCO₃） was successfully synthesized via an ultrasonic-assisted bubble carbonization method.Glycine（Gly） and sodium dodecyl sulfate（SDS） were used as crystal morphology inducers.The synthesized products were characterized using SEM，XRD，FT-IR，Raman spectroscopy，and TG.The results demonstrated that Gly primarily resulted in cubic CaCO₃ particles，while SDS predominantly induced spherical CaCO₃.When both Gly and SDS were combined，the CaCO₃ morphology was mainly spindle-shaped.This study investigated the effects of individual Gly/SDS carbonization systems and the composite carbonization system on the crystal size，morphology，and thermal stability of nano-CaCO₃，proposing a reaction mechanism for Gly/SDS.The analysis indicated that the CaCO₃ in the shells exhibited a wurtzite crystal structure with a purity of 95.46%.Spherical nano-CaCO₃ prepared at a mass concentration of 3.0 mg/mL had the smallest average particle size of 60.80 nm.Both the individual Gly/SDS carbonization system and the composite system produced calcite-type CaCO₃ crystals.The thermal stability of CaCO₃ synthesized under Gly regulation was superior to that of other morphologies.

Key words: nano-calcium carbonate, glycine, sodium dodecyl sulfate, carbonization method, biomass

CLC Number:

TQ132.32

TANG Ziling, LIANG Meina, TANG Hongjie, PENG Yuxuan, JIANG Zhuocheng, WANG Dunqiu, LI Juhao. Study on preparation and morphology of nano-calcium carbonate based on snail shell biomass[J]. Inorganic Chemicals Industry, 2025, 57(12): 83-91.

Figures/Tables 12

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w（CaCO₃）/%	w（MgO）/%	微量元素含量/（mg·kg^-1）
w（CaCO₃）/%	w（MgO）/%	K	Sr	Al	As	Pb	Cd	Zn
95.46	0.40	169.78	1.28×10⁵	69.59	0.01	1.01	ND	1.68

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Study on preparation and morphology of nano-calcium carbonate based on snail shell biomass

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