改性蒙脱土基催化剂研究进展

doi:10.19964/j.issn.1006-4990.2022-0430

Abstract

Abstract:

Montmorillonite is a kind of aluminosilicate mineral.As a potentially promising material for catalysts，it has attracted attention from lots of researchers.Different modification methods can bring different excellent properties to montmorillonite and provide specific catalytic functions.Common modification methods include ion exchange modification，acid modification，pillared modification and construction of porous heterostructure.All modified montmorillonites can serve as catalysts by themselves，or serve as support for loading other active catalytic species.From the perspective of different modification methods，the characteristics of modified montmorillonite-based catalysts were introduced，their research status was summarized，and their future optimization directions were prospected.

Key words: montmorillonite, modification, catalysts

CLC Number:

TQ426.6

FENG Xiaoqian, ZHAO Yilin, ZHAO Yonghua, ZHANG Qijian, WANG Huan, MENG Qingrun. Recent progress of modified montmorillonited-based catalysts[J]. Inorganic Chemicals Industry, 2023, 55(5): 24-30.

Figures/Tables 4

References 42

1	MURRAY H H.Applied clay mineralogy：occurrences，processing and application of kaolins，bentonites，palygorskite-sepiolite，and common clays[M].American Cancer Society，2006.
2	TYAGI B， CHUDASAMA C D， JASRA R V.Determination of structural modification in acid activated montmorillonite clay by FT-IR spectroscopy[J].Spectrochimica Acta Part A：Molecular and Biomolecular Spectroscopy，2006，64（2）：273-278.
3	栗西亮.Ni/膨润土催化剂制备及对硝基苯加氢合成苯胺的催化性能研究[D].南宁：广西大学，2016.
	LI Xiliang.The preparation of Ni/bentonite catalyst and its catalytic property research to the hydrogenation of nitrobenzene to aniline[D].Nanning：Guangxi University，2016.
4	陈凌霞，王琪，孙海杰，等.膨润土负载钌催化剂制备及其催化氨硼烷水解产氢研究[J].无机盐工业，2021，53（6）：199-204.
	CHEN Lingxia， WANG Qi， SUN Haijie，et al.Study on preparation of bentonite supported Ru catalysts and their performance for hydrogen generation from catalytic hydrolysis of ammonia borane[J].Inorganic Chemicals Industry，2021，53（6）：199-204.
5	王燕华，刘自力，王浅朱，等.非晶态镍-硼合金柱撑膨润土催化剂的制备及其加氢性能的研究[J].无机盐工业，2021，53（8）：106-111.
	WANG Yanhua， LIU Zili， WANG Qianzhu，et al.Study on preparation and hydrogenation performance of amorphous Ni-B alloy pillared bentonite catalyst[J].Inorganic Chemicals Industry，2021，53（8）：106-111.
6	BRUNENGO M T， SANTOS C， YESTE M，et al.Utilization of a PILC-Al obtained from Uruguayan clay as support of mesoporous MnO _x -catalysts on the combustion of toluene[J].Applied Clay Science，2021，201：105935.
7	王品，王海娟，牛国庆，等.不同钠盐改性蒙脱土的制备及表征[J].当代化工，2020，49（5）：773-776.
	WANG Pin， WANG Haijuan， NIU Guoqing，et al.Preparation and characterization of different sodium salt modified montmorilloni-te[J].Contemporary Chemical Industry，2020，49（5）：773-776.
8	JANKOVIC L.Metal cation-exchanged montmorillonite catalyzed protection of aromatic aldehydes with Ac₂O[J].Journal of Catalysis，2003，218（1）：227-233.
9	ZARKESH F， FARZANEH F， GHANDI A M.Metal ions exchanged montmorillonite as catalyst for alkylation of benzene with 1-dodecene[J].Reaction Kinetics and Catalysis Letters，2006，89（2）：247-252.
10	LIU Jie， WANG Xueqian， YANG Beibei，et al.Highly efficient conversion of glucose into methyl levulinate catalyzed by tin-exchanged montmorillonite[J].Renewable Energy，2018，120：231- 240.
11	WANG Guangwei， HAO Qingqing， LIU Zhaotie，et al.Fischer-Tropsch synthesis over Co/montmorillonite-insights into the role of interlayer exchangeable cations[J].Applied Catalysis A：General，2011，405（1/2）：45-54.
12	LI Tingting， ZHANG Junfeng， XIE Xianmei，et al.Montmorillo-nite-supported Ni nanoparticles for efficient hydrogen production from ethanol steam reforming[J].Fuel，2015，143：55-62.
13	殷雪梅，谢鲜梅，吴旭，等.有机蒙脱土负载镍催化剂上乙醇重整制氢[J].燃料化学学报，2016，44（6）：689-697.
	YIN Xuemei， XIE Xianmei， WU Xu，et al.Catalytic performance of nickel immobilized on organically modified montmorillonite in the steam reforming of ethanol for hydrogen production[J].Journal of Fuel Chemistry and Technology，2016，44（6）：689-697.
14	ZHAO Heng， ZHOU Chunhui， WU Linmei，et al.Catalytic dehydration of glycerol to acrolein over sulfuric acid-activated montmorillonite catalysts[J].Applied Clay Science，2013，74：154- 162.
15	ÖNAL M， SARIKAYA Y.Preparation and characterization of acid-activated bentonite powders[J].Powder Technology，2007， 172（1）：14-18.
16	张俊波.高分散Ni基蒙脱土催化剂制备及CO/CO₂甲烷化反应性能研究[D].呼和浩特：内蒙古大学，2021.
	ZHANG Junbo.Preparation of highly dispersed Ni-baced montmorillonite catalyst and study on its performance of CO/CO₂ methanation[D].Hohhot：Inner Mongolia University，2021.
17	BHATTI U H， KAZMI W W， MUHAMMAD H A，et al.Practical and inexpensive acid-activated montmorillonite catalysts for energy-efficient CO₂ capture[J].Green Chemistry，2020，22（19）：6328-6333.
18	YU Weihua， WANG Pengpeng， ZHOU Chunhui，et al.Acid-activated and WO _x -loaded montmorillonite catalysts and their catalytic behaviors in glycerol dehydration[J].Chinese Journal of Catalysis，2017，38（6）：1087-1100.
19	SHAH A K， PARK S， KHAN H A，et al.Citronellal cyclisation over heteropoly acid supported on modified montmorillonite catalyst：Effects of acidity and pore structure on catalytic activity[J].Research on Chemical Intermediates，2018，44（4）：2405-2423.
20	HUANG Guiqiu， SONG Yonghong， LIU Chang，et al.Acid activated montmorillonite for gas-phase catalytic dehydration of mo-noethanolamine[J].Applied Clay Science，2019，168：116-124.
21	BERGAYA F， LAGALY G.Handbook of clay science[M].2nd edition.Amsterdam：Elsevier，2013.
22	TENNAKOON D T B， JONES W， THOMAS J M.Structural aspects of metal-oxide-pillared sheet silicates.An investigation by magic-angle-spinning nuclear magnetic resonance，fourier-transform infrared spectroscopy and powder X-ray diffractometry[J].Journal of the Chemical Society，Faraday Transactions 1：Physical Chemistry in Condensed Phases，1986，82（10）：3081.
23	REJEB R， BOUDALI L K， DELAHAY G，et al.Effect of molybdenum on the behavior of sulfated and non-sulfated titanium pillared clay in the selective catalytic reduction of NO by ammo- nia[J].Topics in Catalysis，2017，60（3）：230-237.
24	Biyang TUO， HAN Lang， LONG Sen，et al.Preparation of zirconium pillared montmorillonite composites[J].IOP Conference Series：Earth and Environmental Science，2018，186：012035.
25	KHANKHASAEVA S T， BADMAEVA S V.Removal of p-aminobenzenesulfanilamide from water solutions by catalytic pho-to-oxidation over Fe-pillared clay[J].Water Research，2020，185：116212.
26	LAHOUES-CHAKOUR N， BARAMA S， BARAMA A，et al.Catalytic behavior of nickel loaded on acid-activated and pillared clay in total gas-phase oxidation of ethanol[J].Journal of Nano- particle Research，2018，20（11）：294.
27	王琪莹，刘自力，邹汉波，等.焙烧温度对层柱粘土催化剂Cu/Ti-PILCs催化丙烯还原NO反应的影响[J].环境工程学报，2015，9（11）：5527-5530.
	WANG Qiying， LIU Zili， ZOU Hanbo，et al.Influence of calcination temperature on Cu/Ti-PILCs for catalytic reduction of NO by propylene[J].Chinese Journal of Environmental Engineering，2015，9（11）：5527-5530.
28	WANG Ke， YAN Xinlong， KOMARNENI S.CO₂ adsorption by several types of pillared montmorillonite clays[J].Applied Petrochemical Research，2018，8（3）：173-177.
29	BAHRANOWSKI K， WŁODARCZYK W， WISŁA-WALSH E，et al.[Ti，Zr]-pillared montmorillonite-A new quality with respect to Ti-and Zr-pillared clays[J].Microporous and Mesoporous Materials，2015，202：155-164.
30	XU Dong， WU Wenhao， WANG Penglu，et al.Boosting the alkali/heavy metal poisoning resistance for NO removal by using iron-titanium pillared montmorillonite catalysts[J].Journal of Hazardous Materials，2020，399：122947.
31	GONZÁLEZ-RODRÍGUEZ B， TRUJILLANO R， RIVES V，et al.Structural，textural and acidic properties of Cu-，Fe- and Cr-doped Ti-pillared montmorillonites[J].Applied Clay Science，2015，118：124-130.
32	VELLAYAN K， GONZÁLEZ B， TRUJILLANO R，et al.Pd supported on Cu-doped Ti-pillared montmorillonite as catalyst for the Ullmann coupling reaction[J].Applied Clay Science，2018，160：126-131.
33	JOSEPH A， VELLAYAN K， GONZÁLEZ B，et al.Effective degradation of methylene blue in aqueous solution using Pd-supported Cu-doped Ti-pillared montmorillonite catalyst[J].Applied Clay Science，2019，168：7-10.
34	GALARNEAU A， BARODAWALLA A， PINNAVAIA T J.Porous clay heterostructures formed by gallery-templated synthesis[J].Nature，1995，374（6522）：529-531.
35	HAO Qingqing， LIU Zhongwen， ZHANG Bingsen，et al.Porous montmorillonite heterostructures directed by a single alkyl ammonium template for controlling the product distribution of Fischer-Tropsch synthesis over cobalt[J].Chemistry of Materials，2012，24（6）：972-974.
36	CECILIA J A， GARCÍA-SANCHO C， VILARRASA-GARCÍA E，et al.Synthesis，characterization，uses and applications of porous clays heterostructures：A review[J].Chemical Record，2018，18（7/8）：1085-1104.
37	CHMIELARZ L， GIL B， KUŚTROWSKI P，et al.Montmorillonite-based porous clay heterostructures（PCHs） intercalated with sili-ca-titania pillars-synthesis and characterization[J].Journal of Solid State Chemistry，2009，182（5）：1094-1104.
38	CHMIELARZ L， KOWALCZYK A， SKOCZEK M，et al.Porous clay heterostructures intercalated with multicomponent pillars as catalysts for dehydration of alcohols[J].Applied Clay Science，2018，160：116-125.
39	CHMIELARZ L， PIWOWARSKA Z， KUSTROWSKI P，et al.Comparison study of titania pillared interlayered clays and porous clay heterostructures modified with copper and iron as catalysts of the DeNO _x process[J].Applied Clay Science，2011，53（2）：164-173.
40	PRADHAN A C， VARADWAJ G B， PARIDA K M.Facile fabrication of mesoporous iron modified Al₂O₃ nanoparticles pillared montmorillonite nanocomposite：A smart photo-Fenton catalyst for quick removal of organic dyes[J].Dalton Transactions，2013，42（42）：15139-15149.
41	YUAN Minhao， DENG Wenyi， Dong Shilin，et al.Montmorillonite based porous clay heterostructures modified with Fe as catalysts for selective catalytic reduction of NO with propylene[J].Chemical Engineering Journal，2018，353：839-848.
42	KASHIF M， HALEPOTO A， MEMON A，et al.Gallium oxide impregnated on porous clay heterostructures material for selective catalytic reduction of nitrogen oxide with C₃H₆ [J].Journal of Environmental Chemical Engineering，2020，8（4）：103943.

蒙脱土类型	表面酸性	孔结构	比表面积和孔容	热稳定性	制备方法
离子交换蒙脱土	较弱	微孔为主	较小	400~500 ℃	简单
酸改性蒙脱土	强	微孔、介孔	大	根据酸量不等	简单
柱撑改性蒙脱土	可控	微孔为主	较大	＞600 ℃	较复杂
PCH型蒙脱土	可控	微孔、介孔	很大	＞600 ℃	复杂

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Recent progress of modified montmorillonited-based catalysts

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